This study was conducted to evaluate the causes and effects of cyanobacterial development and succession in a shallow eutrophic reservoir from March 2003 to February 2004. Phytoplankton succession, sedimentation rate, and sediment composition were analyzed. Algal bioassay also was conducted with the consideration of light, water temperature and nutrients. Cyanobacteria dominated throughout the year, except for spring season (March${\sim}$April) in which diatoms and flagellates dominated. Total cell density increased in July and November when P loading through inflows was high. Oscillatoria spp. and Aphanizomenon sp. were dominant in May and June, respectively, but replaced with Microcystis spp. in July. Thereafter, Microcystis spp. sustained until December, and again shifted to Oscillatoria spp. and Aphanizomenon sp. The dominance of Oscillatoria spp. in May was accompanied with high TN/TP ratio and the increase of water temperature and light intensity. While the dominance of Microcystis spp. was related with relatively low TN/TP ratio, ranging from 46 to 13 (average: 27). The sedimentation rate was highest in March (0.6 m $day^{-1}$) when diatoms dominated. During the period of cyanobacterial dominance, relatively high sedimentation rate was observed in May (0.4 m $day^{-1}$) and October (0.36m $day^{-1}$). C/N ratio of the sediment ranged $6{\sim}8$. Inorganic P concentration in the pore water was low when DO concentration was < 2 mg $O_2$$L^{-1}$ in the hypolimnion, reflecting the P release from the sediment. Cyanobacterial growth rate depended on phosphorus concentration and water temperature, and high P concentration compensated for the low temperature in the growth rate. Our results suggest that the potential of cyanobacterial development and substantiality in eutrophic reservoirs be high throughout the year, as being supplied with enough P, and emphasize the consideration of sediment man. agement for the water quality improvement and algal bloom control.
Physico-chemical properties of asphalt, aggregate, and asphalt-aggregate mixture that might influence stripping were summarized in Table 1, based on the fundamental theories concerning stripping. It was found that although physical properties of aggregate affected stripping, there was no strong correlation between the physical properties of aggregate, such as pore volume and surface area, and the stripping propensity of the aggregate. Chemical and electrochemical properties of aggregate surface in the presence of water were most important factors for stripping. All mineral aggregates tested in this study imparted distinctive pH values to the contacting water and possessed distinctive electrochemical properties as measured by zeta potential. It was found that aggregates which had relatively higher surface potential in water and/or which imparted relatively higher pH to the contacting water were more susceptible to stripping. The functionalities contained in antistripping additives tested were primary and secondary amines and those of organic nitrogen compounds. The functionalities were determined by examining their infrared spectra. Based on the interfacial energy concept, the contact angle of an asphalt drop on an aggregate surface immersed in water related to the stripping propensity. The contact angle and stripping propensity were markedly reduced by the presence of an antistripping additive. In general, all the additives tested improved stripping resistance to some extent, depending on their concentration in the asphalts. The optimum dosage of an additive varied with different asphalts, as well as different aggregates. All antistripping additives tested in this study lost their effectiveness and failed to function to some extent when maintained for hours in a hot asphalt.
Deep sea core samples were taken in the southwestern part of the Ulleung Basin in order to characterize the properties of shallow gases in the sediment. Amount of shallow gases in the sediments were calculated by head space techniques, and chemical and isotopic compositions of hydrocarbon gases were analyzed. Geochemical analyses were carried out on the gas bearing sediments to find out relationship between natural gas contents and organic characteristics of the sediments. Seismic characteristics of shallow gases in the sediments were also examined in this study. The amount of the hydrocarbon gases in the sediments range from 0.01% to 11.25%. Calculation of volume of gas per volume of wet sediment varies from 0.1 to 82.0 ml HC/L wet sediment. Methane consists 98% of the total hydrocarbon gases except for two samples. Based on the methane content and isotopic composition$(\delta^{13}c)$: -94.31$\textperthousand$~-55.5$\textperthousand$), the hydrocarbon gases from the sediments are generated from bacterial activities of methanogenic microbes. Contents of hydrocarbon gases are variable from site to site. Volume of shallow gases in the sediments shows no apparent trends vs. either characteristics of organic matter or particle sizes of the sediments. Gas concentration is high in the area of seismic anomalies such as blanking zone or chimney structures in the section. Physicochemically the pore water and the formation water systems are saturated with gases in these areas. Concentration of hydrocarbon gases in the sediments in these area shows favorable condition for generation of gas hydrate, as far as the other conditions are satisfied.
To investigate the effect of calcium chloride ($CaCl_2$) using for deicing salts in winter on gas exchange and stomatal responses of 3-year-old Prunus serrulata, we treated twice (1 L) $CaCl_2$ solution (0.5%, 1.0% and 3.0%) in the root zone before leaf unfolding. Stomatal conductance ($g_s$), photosynthetic rate ($P_n$), transpiration rate ($T_r$) and water use efficiency (WUE) in the leaves of P. serrulata were decreased with increasing of $CaCl_2$ concentration. Even though stomatal conductance and photosynthetic rate were reduced by $CaCl_2$, intercellular $CO_2$ concentration ($C_i$) in $CaCl_2$ treatments has similar or higher values compared with control. These results suggest that non-stomatal limitation as well as stomatal limitation induced the reduction of photosynthetic rate together. On the other hands, treatment of $CaCl_2$ before leaf unfolding also affected leaf morphology traits. We proposed that reductions of stomatal length and leaf size and high pore density with increasing salinity is adaptative mechanism to reduce the water loss in plant.
Due to the growth in industrialization, potential hazards in subsurface environments are becoming increasingly significant. The extraction of the contaminant from the soil and movement of the water are restricted due to the low permeability and adsorption characteristics of the reclaimed soils. There are a number of approaches to in-situ remediation that are used in contaminated sites for removing contaminants. These include soil flushing, dual phase extraction, and soil vapor extraction. Among these techniques, soil flushing was the focus of the investigation in this paper. Incorporated technique with PVDs has been used for dewatering from fine-grained soils for the purpose of ground improvement by means of prefabricated vertical drain systems. The laboratory model tests were performed by using the flushing tracer solutions for silty soils and recorded the tracer concentration changes with the elapsed time and flow rates. The modeling was intended to predict the effectiveness and time dependence of the remediation process. Modeling has been performed on the extraction, considering tracer concentration and laboratory model test characteristics. The computer model used herein are SEEP/W and CTRAN/W, this 2-D finite element program allows for modeling to determine hydraulic head and pore water pressure distribution, efficiency of remediation for the subsurface environment. It is concluded that the coefficient of permeability of contaminated soil is related with vertical velocity and extracted flow rate. The vertical velocity and extracted flow rate have an effect on dispersivity and finally are played an important role in-situ soil remediation.
Proliposomal patch of clenbuterol, ${\beta}_2-agonist$ bronchodilator, was prepared and its feasibility as a novel transdermal drug delivery system was examined. Proliposomal granules containing clenbuterol was prepared by a standard method using sorbitol and lecithin with (Rx 2) or without cholesterol (Rx 1). The porous structure of sorbitol in the proliposomes was maintained allowing tree flowability of the granules. Following contact with water, the granules were converted probably to liposomes almost completely within several minutes. It indicates that proliposomes may be hydrated, when they are applied on the skin under occlusive condition in vivo, by the sweat to form liposomes. Clenbuterol release from Rx 1 and Rx 2 proliposomes to pH 7.4 isotonic phospate buffer (PBS) across cellulose membrane (mol. wt. cut-off of 12000-14000) was retarded significantly compared with that from the mixture of clenbuterol powder and blank proliposomes. Interestingly, proliposomes prepared with lecithin and cholesterol (i.e., Rx 2 proliposomes) showed much more retarded release of clenbuterol than proliposomes prepared only with lecithin (i.e.. Rx 1 proliposomes), indicating that clenbuterol release from proliposomes can be controlled by the addition of cholesterol to the proliposomes. Proliposomal patches were prepared using PVC film as an occlusive backing sheet, two sides adhesive tape (urethane, 1.45 mm thickness) as a reservoir for proliposome granules and Millipore MF-membrane (0.45 mm pore size) as a drug release-controlling membrane. Rx 1 or Rx 2 proliposomes containing 4.6 mg of clenbuterol were loaded into the reservoir of the patch. Clenbuterol release from the patches to pH 7.4 PBS was determined using USP paddle (50 rpm)-over-disc release method. Clenbuterol release from the proliposomal patches was much more retarded even than from a matrix type clenbuterol patch (Boehringer Ingelheim ltd). Being consistent with clenbuterol release from the proliposomal granules, the release from the patches was highly dependent on the presence of cholesterol in the proliposomes : Patches containing Rx 2 proliposomes showed several fold slower drug release than patches containing Rx 1 proliposomes. When the patch containing Rx 1 proliposomes was applied on to the back of a hair-removed rat, clenbuterol concentration in the rat blood was maintained during 6-72 hrs. Transdermal absorption of clenbuterol from the patch was accelerated when the patch was prehydrated with 50 ml of pH 7.4 PBS before topical application. Above results indicate that sustained transdermal delivery of clenbuterol is feasible using proliposomal patches if the cholesterol content and pore size of the release rate-controlling membrane of patches, for example, are appropriately controlled.
Plant growth and development are also affected by root-zone environment. Therefore, it is important to consider the variables of the root-zone environment when establishing an irrigation strategy. The purpose of this study is to analyze the relationship between the volumetric moisture content (VWC), Bulk EC (ECb), and Pore EC (ECp) used by plant roots using FDR sensors in two types of rockwool media with different water transmission characteristics, using the method above this was used to establish a method for collecting and correcting available root-zone environmental data. For the experiment, two types of rockwool medium (RW1, RW2) with different physical characteristics were used. The moisture content (MC) and ECb were measured using an FDR sensor, ECp was measured after extracting the residual nutrient solution from the medium using a disposable syringe in the center of the medium at a volumetric moisture content (VWC) of 10-100%. Then, ECb and ECp are measured by supplying nutrient solution having different concentration (distilled water, 0.5-5.0) to two types of media (RW1, RW2) in each volume water content range (0 to 100%). The relationship between ECb and ECp in RW1 and RW2 media is best suited for cubic polynomial. The relationship between ECb and ECp according to volume moisture content (VWC) range showed a large error rate in the low volume moisture content (VWC) range of 10-60%. The correlation between the sensor measured value (ECb) and the ECp used by plant roots according to the volumetric water content (VWC) range was the most suitable for the Paraboloid equation in both media (RW1, RW2). The coefficient of determination the calibration equation for RW1 and RW2 media were 0.936, 0.947, respectively.
The cutting oil emulsion microfiltration was carried out on dead-end call and crossflow systems equipped with 0.22 $\mu$m GVHP Millipore and 0.2 m stainless steel Mott microfiltration membranes, respectivdy. The oil drop size in the emulsion was varied from 0.07 to 0.22 $\mu$m. Cake filtration(CFM) and standard pore blocking models(SPBM) were applied to predict the permeation flux. The permeation fluxes of 0.01 vol% oil emulsion followed CFM for dead-end system very well under the condition of 400 rpm and below 100 kPa. The SPBM was, however, suitable for the permeation flux at 400 rpm and above 150 kPa. The oil layer on the membrane surface was destroyed and reproduced repeatedly as operating pressure was suddenly changed from 60 to 200 kPa, and then returned to 60 kPa. Also, we estimated the critical entry pressure(CEP) which is changed from CFM to SPBM, and CEP for dead-end system was around 100 kPa. The CEP increased from around 100 to 150 kPa for the crossflow system as the oil concentration increased from 0.01 to 0.03 vol% when Reynolds number was 7080.
Journal of Korean Society of Environmental Engineers
/
v.35
no.9
/
pp.654-659
/
2013
This study was conducted to identify an optimal ratio of carbon to nitrogen (C/N ratio) for denitrification of nitrate using molasses as an external carbon source. A series of batch and column tests was conducted using an indigenous bacterium Pseudomonas sp. KY1 isolated from a nitrate-contaminated soil. For the initial nitrate-nitrogen concentration of 100 mg-N/L, batch test results indicated that C/N ratio of 3/1 was the optimal ratio with a relatively high pseudo-first-order reaction constant of $0.0263hr^{-1}$. At C/N ratio of 3/1, more than 80% of nitrate-nitrogen concentration of 100 mg-N/L was removed in 100 hrs. Results of column tests with a flow velocity of 0.3 mL/min also indicated that the C/N ratio of 3/1 was optimal for denitrification with minimizing remaining molasses concentrations. After 172 hrs of column operation (35 pore volumes) with an influent nitrate-nitrogen concentration of 100 mg-N/L, the effluent met the drinking water standard (i.e., 10 mg $NO_3$-N/L).
Journal of the Korea Organic Resources Recycling Association
/
v.11
no.2
/
pp.117-124
/
2003
The purpose of this study was to investigate the optical conditions to satisfied the salt concentration of 1% below of compost produced by using the material of foodwaste and sawdust. We changed the mixing ratios of foodwaste : sawdust from 7:3 to 3:7 and the ratios of foodwaste : rice hull from 6.5:3.5 to 4:6. We analyzed C/N, pH, temperature, water content, volatile solid, salt, heavy metals to check the degree of composting. The running conditions of composting were $80{\sim}133{\ell}/min{\cdot}m^{3}$ of air flow rate, 1:4 of time interval(on:off) and 7days of turning interval. Running times were 28days. The optical mixing ratio of foodwaste : sawdust was 6:4 when we compared many factors. Especially when the mixing ratios of foodwaste : sawdust or foodwaste : sawdust were 7:3 or 6:4, the composting was not accomplished by the reason of low C/N. The concentrations of heavy metal were sufficiently low to satisfied the satandard of organic compost. The salt concentration was 0.43%-0.46% that was the half of initial concentration. The rice hull was the good in pore rate and 통기성, and so it can used alternative material.
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