• 한국토양비료학회지
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• 제24권2호
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• pp.102-108
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• 1991

나지상태(裸地狀態)에서 관수량(灌水量)에 따른 양분(養分)의 수직이동(垂直移動) 양상(樣相)을 구명하기 위하여 본량사양토(本良砂壤土)(Typic Udifluvents)의 작토층(作土層)을 공시토양(供試土壤)으로 하여 microplot(지름 20cm, 길이 85cm)시험(試驗)을 수행하였다. 시비량(施肥量)를 기준으로 하여 각(各) 성분(成分)이 (각(各) 토층(土層)으로 이동(移動)된 양(量))/(시비량(施肥量))${\times}$(시비지점에서 각(各) 토층(土層) 중심점까지의 거리)의 화(和)를 평균(平均) 이동(移動)거리라 했을때, 평균이동(平均移動)거리는 관수량(灌水量)과 수직적(直線的)인 관계가 있었다. 1 pore volume(piston front 10cm)물의 이동(移動)에 대한 각(各) 성분(成分)의 평균(平均) 이동(移動)거리는(cm)는 Cl, 7.52>무기태(無機態) N, 6.03>K, 3.50>Mg, 2.69>Ca, 1.19>유효인산(有效燐酸), 0.29순이었다. 여러 성분중(成分中) Cl이 가장 활발하게 하향이동(下向移動)되어 물의 piston front 이동(移動)거리의 75%가 되었고, 인산(燐酸)은 거의 이동(移動)되지 않아 물의 piston front 이동(移動)거리의 3%에 불과하였다. 양분이동(養分移動)의 결과 토양 pH는 관수량(灌水量)이 많아질수록 표층(表層)에서 낮아지고 심층(深層)에서 높아지는 경향인데 토양(土壤)깊이별 pH변화는 치환성(置換性) Ca과 Mg보다는 $NH_4-N$의 함량변화와 같은 경향을 보였다.

• 한국지하수토양환경학회지:지하수토양환경
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• 제26권1호
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• pp.17-23
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• 2021

In order to investigate change of shear strength of coastal muddy sediment by mixing pretreated oyster shells with different pyrolysis temperatures and particle sizes, a vane shear test was carried out. The shear strength of the sediment with oyster shells pyrolyzed at 800℃ was twice higher than that of the control, with a maximum shear strength of ca. 0.2 kPa. The Ca2+ concentration in the pore water was the highest at sediment with oyster shells pyrolyzed at 800℃ with a concentration of ca. 790 mg/L. From the above results, it is concluded that the application of the oyster shells pyrolyzed at 800℃ can affect the increase in shear strength of coastal sediments through the aggregation of clay particles and pozzolanic reactions with sediments.

• Membrane and Water Treatment
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• 제8권1호
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• pp.89-112
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• 2017

Dyeing wastewaters are the most problematic wastewater in textile industries and also, growing amounts of waste fibers in carpet industries have concerned environmental specialists. Among different treatment methods, membrane filtration processes as energy-efficient and compatible way, were utilized for several individual problems. In this research, novel hybrid membranes were prepared by waste fibers of mechanical carpets as useful resource of membrane matrix and industrial graphite powder as filler to eliminate Chrysophenine GX from dyeing wastewater. These membranes were expected to be utilized for first stage of hybrid membrane filtration process including (adsorption-ultrafiltration) and nanofiltration in Kashan Textile Company. For scaling of membrane filtration process, fouling mechanism of these membranes were recognized and explained by the use of genetic algorithm, as well. The graphite increased rejection and diminished permeate flux at low concentration but in high concentration, the performance was significantly worsened. Among all hybrid membranes, 18% wt. waste fibers-1% wt. graphite membrane had the best performance and minimum fouling. The maximum pore size of this optimum membrane was ranged from 16.10 to 18.72 nm.

• 한국결정성장학회지
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• 제12권1호
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• pp.56-61
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• 2002

전남 영암산 이타점토 출발원료에 계면활성제를 사용하여 고농도의 slurry를 발포시킨 후 성형하여 다공질 세라믹스를 제조하였다. slurry에서의 계면활성제 농도변화는 다공질 세라믹스의 기공변화 및 물리적 특성을 제어하는 중요한 요인이었다. 발포용 slurry의 농도는 발포제인 계면활성제 농도가 증가할수록 발포력과 포말층의 안전도는 향상되었으나, 6.0 wt% 농도 이상에서는 계면활성제 양이 많아짐으로써 초기 slurry의 점도가 높아져 발포력이 좋지 못했다. 성형시편을 $1150^{\circ}C$와 $1200^{\circ}C$ 온도에서 소성하였고, 그 결과 부피비중은 약 0.9, 흡수율은 45%, 겉보기 기공율은 50%, 수축율은 14% 그리고 압축강도는 70kg/$\textrm{cm}^2$인 다공질 세라믹스를 제조할 수 있었다.

• Membrane and Water Treatment
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• 제8권4호
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• pp.337-353
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• 2017

Membrane fouling at different solids retention times (SRT) (7, 12 and 20 days) was studied under well-controlled conditions in a laboratory-scale aerobic submerged membrane bioreactor under constant biomass concentration using a synthetic high strength wastewater. An increase in SRT was found to improve membrane performance and this correlated to changes in the total production of bound extracellular polymeric substances (EPS), and the composition and properties of bound EPS using X-ray photoelectron spectroscopy (XPS) and Fourier transform-infrared spectroscopy (FTIR) and floc sizes. A larger amount of total bound EPS was found at the lowest SRT (7 days) tested but the ratio of proteins (PN) to carbohydrates (CH) in bound EPS increased with an increase in SRT. Similarly, the quantity of soluble microbial products (SMP) decreased with an increase in SRT and the SMP PN/CH ratio increased with an increase in SRT. SMP concentrations positively correlated to the percentage of membrane pore blocking resistance. The quantity of total bound EPS and total SMP positively corresponded to the membrane fouling rate, while the PN/CH ratio in the bound EPS and SMP negatively correlated to the membrane fouling rate. The results show that both the quantity and composition of bound EPS and SMP and floc sizes are important in controlling membrane fouling.

• Computers and Concrete
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• 제16권6호
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• pp.847-864
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• 2015

This study aimed to develop models of sulfate diffusion and ettringite content profile in cement paste for the predication of the damage behavior in cement paste subject to external sulfate. In the models, multiphase reaction equilibrium between ions in pore solution and solid calcium aluminates phases and the microstructure changes in different positions of cement paste were taken into account. The distributions of expansive volume strain and expansion stress in cement paste were calculated based on the ettringite content profile model. In addition, more sulfate diffusion tests and SEM analyses were determined to verify the reliability and veracity of the models. As the results shown, there was a good correlation between the numerical simulation results and experimental evidences. The results indicated that the water to cement ratio (w/c) had a significant influence on the diffusion of sulfate ions, ettringite concentration profile and expansion properties in cement paste specimens. The cracking points caused by ettringite growth in cement paste specimens were predicted through numerical methods. According to the simulation results, the fracture of cement paste would be accelerated when the specimens were prepared with higher w/c or when they were exposed to sulfate solution with higher concentration.

• 한국지반공학회논문집
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• 제19권1호
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• pp.131-142
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• 2003

본 논문은 점성토 지반에 동전기 공법을 적용할 때 지반내에서 발생하는 현상과 그 특성을 고려하여 전기삼투 현상을 예측하고자 하였다. 이를 위하여 납으로 오염된 카올린에 대해 실내실험을 수행하여, 동전기 처리 동안 변화하는 시료의 전압, 전류, 제타포텐셜, pH분포 등의 물리 화학적 현상 간 상관성을 고려한 전기삼투 유한차분 수치 해석 프로그램을 개발하여 실험 결과와 비교하고 각 현상을 검토하였다. 그 결과, 전기삼투 흐름은 점토의 화학적 특성과 전기적 특성 변화에 매우 민감하였다. 간극수의 이온 농도가 증가하면 흐름속도는 감소하였으며, 시간에 따라 배수량은 감소하였다.

• Ocean and Polar Research
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• 제31권3호
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• pp.247-255
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• 2009

We measured phosphate benthic fluxes and conducted phosphate adsorption experiments in order to find out the effects of adsorption on phosphate benthic fluxes in the intertidal sediments of Keunso Bay during summer and winter. Organic carbon contents showed little variation with season at St. S1, but noticeable changes were observed at St. S2, which were three times higher in winter than in summer. The higher organic carbon contents in winter resulted from the bloom of benthic algae in surface sediments. Pore water phosphate concentrations were much higher in summer than in winter. The higher phosphate concentration in summer was probably due to the faster remineralization rate of organic matter in summer. At St. S1, benthic fluxes of phosphate showed a negative value in summer and a positive value in winter. However, St. S2 had a negative benthic flux both in summer and winter. The negative benthic flux was ascribed to the phosphate adsorption on iron oxides in surface sediments. The equilibrium concentrations of phosphate obtained from the adsorption experiment were three times higher at St. S1 than at St. S2. The relatively high adsorption coefficient and low equilibrium concentration indicated that phosphate was strongly adsorbed on the surface sediments of Keunso Bay. The strong adsorption affinity significantly reduced benthic fluxes of phosphate in the intertidal sediments.

• 한국미생물·생명공학회지
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• 제20권4호
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• pp.422-429
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• 1992

Maltosy-$\beta$-cyclodextrin는 $\beta$-cyclodextrin에 maltose가 $\Alpha$-1,6 glycosidic bond로 결합된 분지환상결합체로서 pullulanase의 역반응(축합반응)을 이용하여 $\beta$-cyclodextrin과 maltose로부터 합성된다. Maltosyl-$\beta$-cycloextrin의 합성수율을 증가시키기 위하여 각종 water activity depressor인 각종 polyol, sugar 그리고 polyethylene glycol(PEG)등의 첨가의 영향을 검토하였다. 가장 적절한 water activity depressor는 PEG 6000로서, 첨가량 10%(w/w)의 경우 maltosyl-$\beta$-cyclodextrin 생성량과 합성수율은 크게 증가하여 3.02g/100ml 와 55.9%(w/w)로서, 첨가하지 않았을 경우보다 약 1.3배 증가하였다. Water activity는 PEG 6000을 20%(w/w) 첨가할 때 원래의 0.966에서 0.914로 감소하였으며, maltosyl-$\beta$-cyclodextrin 합성수율은 water activity에 반비례하여 증가하였다. Pullulanase의 역반응을 이용한 maltosyl-$\beta$-cyclodextrin 합성반응의 각종 열역학적 상수를 평가하였으며, $\Delta$H는 36.788kJ/mol, $\Delta$S는 0.067kJ/moleK, 그리고 $\Delta$G는 14.433kJ/mole이였다. PEG 6000의 분리회수에 적절한 ultrafiltration membrane의 pore size는 3K dalton이었으며, 여과액과 농축액의 적정 분획비는 1.0 : 9.0였다. Maltosyl-$\beta$-cyclodextrin 합성수율의 증가는 첨가한 PEG가 water activity를 감소시켜 합성된 maltosyl-$\beta$-cyclodextrin이 재분해되는 pullulanase이 정반응인 hydrolysis reaction을 억제하여 equilbrium state에 변화를 주기 때문인 것으로 유추된다.

• 한국지하수토양환경학회지:지하수토양환경
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• 제22권5호
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• pp.30-39
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• 2017

In this study, the predictive toxicity of barley Hordeum vulgare was estimated using a modified terrestrial biotic ligand model (TBLM) to account for the toxic effects of $CuOH^+$ and $CuCO_3(aq)$ generated at pH 7 or higher, and this was compared to that from the original TBLM. At pH values higher than 7, the difference in $EA_{50}\{Cu^{2+}\}$ (half maximal effective activity of $Cu^{2+}$) between the two models increased with increasing pH. As Mg concentration increased from 8.24 to 148 mg/L in the pH range of 5.5 to 8.5, the difference in $EA_{50}\{Cu^{2+}\}$ increased, and it reached its maximum at pH 8. The difference in $EC_{50}[Cu]_T$ (half maximal effective concentration of Cu) between the two models increased as dissolved organic carbon (DOC) concentration increased when pH was above 7. Thus, for soils with alkaline pH, the toxic effect of $CuOH^+$ and $CuCO_3(aq)$ are greater at higher salt and DOC concentrations. The acceptable Cu concentration in soil porewater can be estimated by the modified TBLM through deterministic method at pH levels higher than 7, while combination of TBLM and species sensitivity distribution through the probabilistic method could be utilized at pH levels lower than 7.