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Pre-treatment of textile wastewaters containing Chrysophenine using hybrid membranes

  • lehi, Arash Yunessnia (Institute of Nanoscience and Nanotechnology, University of Kashan) ;
  • Mousavirad, Seyed Jalaleddin (Department of Computer Engineering, Faculty of Computer & Electrical Engineering, University of Kashan) ;
  • Akbari, Ahmad (Institute of Nanoscience and Nanotechnology, University of Kashan)
  • Received : 2015.11.12
  • Accepted : 2016.11.15
  • Published : 2017.01.25

Abstract

Dyeing wastewaters are the most problematic wastewater in textile industries and also, growing amounts of waste fibers in carpet industries have concerned environmental specialists. Among different treatment methods, membrane filtration processes as energy-efficient and compatible way, were utilized for several individual problems. In this research, novel hybrid membranes were prepared by waste fibers of mechanical carpets as useful resource of membrane matrix and industrial graphite powder as filler to eliminate Chrysophenine GX from dyeing wastewater. These membranes were expected to be utilized for first stage of hybrid membrane filtration process including (adsorption-ultrafiltration) and nanofiltration in Kashan Textile Company. For scaling of membrane filtration process, fouling mechanism of these membranes were recognized and explained by the use of genetic algorithm, as well. The graphite increased rejection and diminished permeate flux at low concentration but in high concentration, the performance was significantly worsened. Among all hybrid membranes, 18% wt. waste fibers-1% wt. graphite membrane had the best performance and minimum fouling. The maximum pore size of this optimum membrane was ranged from 16.10 to 18.72 nm.

Keywords

References

  1. Abedi, S. and Nekouei, F. (2011), "Removal of direct yellow 12 from water samples by cloud point extraction using triton X-100 as nonionic surfactant", E-J. Chem., 8(4), 1588-1595. https://doi.org/10.1155/2011/207640
  2. Adoor, S.G., Sairam, M., Manjeshwar, L.S., Raju, K.V.S.N. and Aminabhavi, T.M. (2006), "Sodium montmorillonite clay loaded novel mixed matrix membranes of poly(vinyl alcohol) for pervaporation dehydration of aqueous mixtures of isopropanol and 1,4-dioxane", J. Membrane Sci., 285(1-2), 182-195. https://doi.org/10.1016/j.memsci.2006.08.022
  3. Akbari, A., Desclaux, S., Remigy, J.C. and Aptel, P. (2002b), "Treatment of textile dye effluents using a new photografted nanofiltration membrane", Desalination, 149(1-3), 101-107. https://doi.org/10.1016/S0011-9164(02)00739-7
  4. Akbari, A., Desclaux, S., Rouch, J.C. and Remigy, J.C. (2007), "Application of nanofiltration hollow fibre membranes, developed by photografting, to treatment of anionic dye solutions", J. Membrane Sci., 297(1-2), 243-252. https://doi.org/10.1016/j.memsci.2007.03.050
  5. Akbari, A., Desclaux, S., Rouch, J.C., Aptel, P. and Remigy, J.C. (2006), "New UV-photografted nanofiltration membranes for the treatment of colored textile dye effluents", J. Membrane Sci., 286(1-2), 342-350. https://doi.org/10.1016/j.memsci.2006.10.024
  6. Akbari, A., Remigy, J.C. and Aptel, P. (2002a), "Treatment of textile dye effluent using a polyamide-based nanofiltration membrane", Chem. Eng. Process.: Process Intensif., 41(7), 601-609. https://doi.org/10.1016/S0255-2701(01)00181-7
  7. Allegre, C., Moulin, P., Maisseu, M. and Charbit, F. (2006), "Treatment and reuse of reactive dyeing effluents", J. Membrane Sci., 269(1-2), 15-34. https://doi.org/10.1016/j.memsci.2005.06.014
  8. Amarnath, C.A., Hong, C.E., Kim, N.H., Ku, B.C. and Lee, J.H. (2011), "Aniline- and N,Ndimethylformamide-assisted processing route for graphite nanoplates: intercalation and exfoliation pathway", Mater. Lett., 65(9), 1371-1374. https://doi.org/10.1016/j.matlet.2011.02.005
  9. Aouni, A., Fersi, C., Cuartas-Uribe, B., Bes-Pia, A., Alcaina-Miranda, M.I. and Dhahbi, M. (2012), "Reactive dyes rejection and textile effluent treatment study using ultrafiltration and nanofiltration processes", Desalination, 297, 87-96. https://doi.org/10.1016/j.desal.2012.04.022
  10. Asatekin, A., Olivetti, E.A. and Mayes, A.M. (2009), "Fouling resistant, high flux nanofiltration membranes from polyacrylonitrile-graft-poly(ethylene oxide)", J. Membrane Sci., 332(1-2), 6-12. https://doi.org/10.1016/j.memsci.2009.01.029
  11. Ballinas, L., Torras, C., Fierro, V. and Garcia-Valls, R. (2004), "Factors influencing activated carbonpolymeric composite membrane structure and performance", J. Phys. Chem. Solid., 65(2-3), 633-637. https://doi.org/10.1016/j.jpcs.2003.10.043
  12. Boom, R.M., Wienk, I.M., van den Boomgaard, T. and Smolders, C.A. (1992), "Microstructures in phase inversion membranes. Part 2. The role of a polymeric additive", J. Membrane Sci., 73(2-3), 277-292. https://doi.org/10.1016/0376-7388(92)80135-7
  13. Carvalho, A.L., Maugeri, F., Silva, V., Hernandez, A., Palacio, L. and Pradanos, P. (2011), "AFM analysis of the surface of nanoporous membranes: application to the nanofiltration of potassium clavulanate", J. Mater. Sci., 46(10), 3356-3369. https://doi.org/10.1007/s10853-010-5224-7
  14. El Nemr, A., Abdelwahab, O., Khaled, A. and El Sikaily, A. (2006), "Biosorption of direct yellow 12 from aqueous solution using green alga Ulva lactuca", Chem. Ecol., 22(4), 253-266. https://doi.org/10.1080/02757540600812875
  15. Fane, A.G. and Fell, C.J.D. (1987), "A review of fouling and fouling control in ultrafiltration", Desalination, 62, 117-136. https://doi.org/10.1016/0011-9164(87)87013-3
  16. Fathizadeh, M., Aroujalian, A. and Raisi, A. (2011), "Effect of added NaX nano-zeolite into polyamide as a top thin layer of membrane on water flux and salt rejection in a reverse osmosis process", J. Membrane Sci., 375(1-2), 88-95. https://doi.org/10.1016/j.memsci.2011.03.017
  17. Fersi, C. and Dhahbi, M. (2008), "Treatment of textile plant effluent by ultrafiltration and/or nanofiltration for water reuse", Desalination, 222(1-3), 263-271. https://doi.org/10.1016/j.desal.2007.01.171
  18. Field, R.W. and Wu, J.J. (2011), "Modelling of permeability loss in membrane filtration: Re-examination of fundamental fouling equations and their link to critical flux", Desalination, 283, 68-74. https://doi.org/10.1016/j.desal.2011.04.035
  19. Gao, W., Liang, H., Ma, J., Han, M., Chen, Z.L., Han, Z.S. and Li, G.B. (2011), "Membrane fouling control in ultrafiltration technology for drinking water production: A review", Desalination, 272(1-3), 1-8. https://doi.org/10.1016/j.desal.2011.01.051
  20. Gethard, K., Sae-Khow, O. and Mitra, S. (2010), "Water desalination using carbon-nanotube-enhanced membrane distillation", ACS Appl. Mater. Interf., 3(2), 110-114. https://doi.org/10.1021/am100981s
  21. Ghaedi, M., Sadeghian, B., Kokhdan, S.N., Pebdani, A.A., Sahraei, R., Daneshfar, A. and Mihandoost, A. (2013), "Study of removal of direct yellow 12 by cadmium oxide nanowires loaded on activated carbon", Mater. Sci. Eng. C, 33(4), 2258-2265. https://doi.org/10.1016/j.msec.2013.01.052
  22. Ghaedi, M., Sadeghian, B., Pebdani, A.A., Sahraei, R., Daneshfar, A. and Duran, C. (2012), "Kinetics, thermodynamics and equilibrium evaluation of direct yellow 12 removal by adsorption onto silver nanoparticles loaded activated carbon", Chem. Eng. J., 187, 133-141. https://doi.org/10.1016/j.cej.2012.01.111
  23. Goosen, M.F.A., Sablani, S.S., Al-Hinai, H., Al-Obeidani, S., Al-Belushi, R. and Jackson, D. (2005), "Fouling of Reverse Osmosis and Ultrafiltration Membranes: A Critical Review", Sep. Sci. Technol., 39(10), 2261-2297. https://doi.org/10.1081/SS-120039343
  24. Huang, H., Qu, X., Dong, H., Zhang, L. and Chen, H. (2013), "Role of NaA zeolites in the interfacial polymerization process towards a polyamide nanocomposite reverse osmosis membrane", RSC Adv., 3(22), 8203-8207. https://doi.org/10.1039/c3ra40960k
  25. Hwang, K.J. and Lin, T.T. (2002), "Effect of morphology of polymeric membrane on the performance of cross-flow microfiltration", J. Membrane Sci., 199(1-2), 41-52. https://doi.org/10.1016/S0376-7388(01)00675-5
  26. Hwang, L.L., Chen, J.C. and Wey, M.Y. (2013), "The properties and filtration efficiency of activated carbon polymer composite membranes for the removal of humic acid", Desalination, 313, 166-175. https://doi.org/10.1016/j.desal.2012.12.019
  27. Jung, B., Yoon, J.K., Kim, B. and Rhee, H.W. (2004), "Effect of molecular weight of polymeric additives on formation, permeation properties and hypochlorite treatment of asymmetric polyacrylonitrile membranes", J. Membrane Sci., 243(1-2), 45-57. https://doi.org/10.1016/j.memsci.2004.06.011
  28. Khaled, A., El Nemr, A., El-Sikaily, A. and Abdelwahab, O. (2009), "Treatment of artificial textile dye effluent containing Direct Yellow 12 by orange peel carbon", Desalination, 238(1-3), 210-232. https://doi.org/10.1016/j.desal.2008.02.014
  29. Khataee, A.R. and Zarei, M. (2011), "Photoelectrocatalytic decolorization of diazo dye by zinc oxide nanophotocatalyst and carbon nanotube based cathode: Determination of the degradation products", Desalination, 278(1-3), 117-125. https://doi.org/10.1016/j.desal.2011.05.004
  30. Khulbe, K.C., Feng, C.Y. and Matsuura, T. (2008), Synthetic Polymeric Membranes: Characterization by Atomic Force Microscopy, Springer-Verlag, Heidelberg.
  31. Kilduff, J.E., Mattaraj, S., Sensibaugh, J., Pieracci, J.P., Yuan, Y. and Belfort, G. (2002), "Modeling flux decline during nanofiltration of NOM with poly(arylsulfone) membranes modified using UV-assisted graft polymerization", Environ. Eng. Sci., 19(6), 477-495. https://doi.org/10.1089/109287502320963454
  32. Kim, H.J., Choi, K., Baek, Y., Kim, D.-G., Shim, J., Yoon, J. and Lee, J.C. (2014), "High-performance reverse osmosis CNT/Polyamide nanocomposite membrane by controlled interfacial interactions", ACS Appl. Mater. Interf., 6(4), 2819-2829. https://doi.org/10.1021/am405398f
  33. Kim, J. and DiGiano, F.A. (2009), "Fouling models for low-pressure membrane systems", Sep. Purif. Technol., 68(3), 293-304. https://doi.org/10.1016/j.seppur.2009.05.018
  34. Kim, J. and Van der Bruggen, B. (2010), "The use of nanoparticles in polymeric and ceramic membrane structures: Review of manufacturing procedures and performance improvement for water treatment", Environ. Pollut., 158(7), 2335-2349. https://doi.org/10.1016/j.envpol.2010.03.024
  35. Koyuncu, I., Topacik, D. and Wiesner, M.R. (2004), "Factors influencing flux decline during nanofiltration of solutions containing dyes and salts", Water Res., 38(2), 432-440. https://doi.org/10.1016/j.watres.2003.10.001
  36. Kuo, K.P. and Cheryan, M. (1983), "Ultrafiltration of acid whey in a spiral-wound unit: effect of operating parameters on membrane fouling", J. Food Sci., 48(4), 1113-1118. https://doi.org/10.1111/j.1365-2621.1983.tb09172.x
  37. Kurt, E., Koseoglu-Imer, D.Y., Dizge, N., Chellam, S. and Koyuncu, I. (2012), "Pilot-scale evaluation of nanofiltration and reverse osmosis for process reuse of segregated textile dyewash wastewater", Desalination, 302, 24-32. https://doi.org/10.1016/j.desal.2012.05.019
  38. Lee, J.W., Choi, S.P., Thiruvenkatachari, R., Shim, W.G. and Moon, H. (2006), "Submerged microfiltration membrane coupled with alum coagulation/powdered activated carbon adsorption for complete decolorization of reactive dyes", Water Res., 40(3), 435-444. https://doi.org/10.1016/j.watres.2005.11.034
  39. Li, J.B., Zhu, J.W. and Zheng, M.S. (2007), "Morphologies and properties of poly(phthalazinone ether sulfone ketone) matrix ultrafiltration membranes with entrapped $TiO_2$ nanoparticles", J. Appl. Polym. Sci., 103(6), 3623-3629. https://doi.org/10.1002/app.25428
  40. Li, J.F., Xu, Z.L., Yang, H., Yu, L.Y. and Liu, M. (2009), "Effect of $TiO_2$ nanoparticles on the surface morphology and performance of microporous PES membrane", Appl. Surf. Sci., 255(9), 4725-4732. https://doi.org/10.1016/j.apsusc.2008.07.139
  41. Lohokare, H., Bhole, Y., Taralkar, S. and Kharul, U. (2011), "Poly(acrylonitrile) based ultrafiltration membranes: Optimization of preparation parameters", Desalination, 282, 46-53. https://doi.org/10.1016/j.desal.2011.04.009
  42. Lu, L., Sun, H., Peng, F. and Jiang, Z. (2006), "Novel graphite-filled PVA/CS hybrid membrane for pervaporation of benzene/cyclohexane mixtures", J. Membrane Sci., 281(1-2), 245-252. https://doi.org/10.1016/j.memsci.2006.03.041
  43. Mirzababaei, M., Miraftab, M., Mohamed, M. and McMahon, P. (2013), "Impact of carpet waste fibre addition on swelling properties of compacted clays", Geotech. Geol. Eng., 31(1), 173-182. https://doi.org/10.1007/s10706-012-9578-2
  44. Nataraj, S.K., Hosamani, K.M. and Aminabhavi, T.M. (2009), "Nanofiltration and reverse osmosis thin film composite membrane module for the removal of dye and salts from the simulated mixtures", Desalination, 249(1), 12-17. https://doi.org/10.1016/j.desal.2009.06.008
  45. Oh, N.W., Jegal, J. and Lee, K.H. (2001), "Preparation and characterization of nanofiltration composite membranes using polyacrylonitrile (PAN). I. preparation and modification of PAN supports", J. Appl. Polym. Sci., 80(10), 1854-1862. https://doi.org/10.1002/app.1282
  46. Okhovat, A. and Mousavi, S.M. (2012), "Modeling of arsenic, chromium and cadmium removal by nanofiltration process using genetic programming", Appl. Soft Comput., 12(2), 793-799. https://doi.org/10.1016/j.asoc.2011.10.012
  47. Peng, F., Lu, L., Hu, C., Wu, H. and Jiang, Z. (2005), "Significant increase of permeation flux and selectivity of poly(vinyl alcohol) membranes by incorporation of crystalline flake graphite", J. Membrane Sci., 259(1-2), 65-73. https://doi.org/10.1016/j.memsci.2005.03.014
  48. Peng, F., Lu, L., Sun, H., Pan, F. and Jiang, Z. (2007), "Organic-Inorganic Hybrid Membranes with Simultaneously Enhanced Flux and Selectivity", Ind. Eng. Chem. Res., 46(8), 2544-2549. https://doi.org/10.1021/ie061622h
  49. Prusty, G. and Swain, S.K. (2011), "Synthesis and characterization of conducting gas barrier polyacrylonitrile/graphite nanocomposites", Polym. Compos., 32(9), 1336-1342. https://doi.org/10.1002/pc.21155
  50. Purkait, M.K., DasGupta, S. and De, S. (2004), "Removal of dye from wastewater using micellar-enhanced ultrafiltration and recovery of surfactant", Sep. Purif. Technol., 37(1), 81-92. https://doi.org/10.1016/j.seppur.2003.08.005
  51. Rathi, A., Rajor, H.K. and Sharma, R.K. (2003), "Photodegradation of direct yellow-12 using $UV/H_2O_2/Fe^{2+}$", J. Hazard. Mater., 102(2-3), 231-241. https://doi.org/10.1016/S0304-3894(03)00213-9
  52. Reddy, A.V.R., Trivedi, J.J., Devmurari, C.V., Mohan, D.J., Singh, P., Rao, A.P., Joshi, S.V. and Ghosh, P.K. (2005), "Fouling resistant membranes in desalination and water recovery", Desalination, 183(1-3), 301-306. https://doi.org/10.1016/j.desal.2005.04.027
  53. Revathi, G., Ramalingam, S., Subramaniam, P. and Ganapathi, A. (2011), "Removal of Direct Yellow-12 Dye from water by adsorption on activated carbon prepared from Ficus Racemosa L.", E-J. Chem., 8(4), 1536-1545. https://doi.org/10.1155/2011/902421
  54. Sahoo, G.B. and Ray, C. (2006), "Predicting flux decline in crossflow membranes using artificial neural networks and genetic algorithms", J. Membrane Sci., 283(1-2), 147-157. https://doi.org/10.1016/j.memsci.2006.06.019
  55. Said, A.A., Aly, A.A., Abd El-Wahab, M.M., Soliman, S.A., Abd El-Hafez, A.A., Helmey, V. and Goda, M.N. (2013), "An efficient biosorption of direct dyes from industrial wastewaters using pretreated sugarcane bagasse", Energy Environ. Eng., 1(1), 10-16.
  56. Shahnazari, H., Ghiassian, H., Noorzad, A., Shafiee, A., Tabarsa, A.R. and Jamshidi, R. (2009), "Shear Modulus of Silty Sand Reinforced by Carpet Waste Strips", J. Seismol. Earthq. Eng., 11(3), 133-142.
  57. Shi, Z., Zhang, W., Zhang, F., Liu, X., Wang, D., Jin, J. and Jiang, L. (2013), "Ultrafast separation of emulsified oil/water mixtures by ultrathin free-standing single-walled carbon nanotube network films", Adv. Mater., 25(17), 2422-2427. https://doi.org/10.1002/adma.201204873
  58. Shinde, M.H., Kulkarni, S.S., Musale, D.A. and Joshi, S.G. (1999), "Improvement of the water purification capability of poly(acrylonitrile) ultrafiltration membranes", J. Membrane Sci., 162(1-2), 9-22. https://doi.org/10.1016/S0376-7388(99)00100-3
  59. Shojaie, S.S., Krantz, W.B. and Greenberg, A.R. (1994a), "Dense polymer film and membrane formation via the dry-cast process part I. Model development", J. Membrane Sci., 94(1), 255-280. https://doi.org/10.1016/0376-7388(93)E0228-C
  60. Shojaie, S.S., Krantz, W.B. and Greenberg, A.R. (1994b), "Dense polymer film and membrane formation via the dry-cast process part II. Model validation and morphological studies", J. Membrane Sci., 94(1), 281-298. https://doi.org/10.1016/0376-7388(93)E0229-D
  61. Smolders, C.A., Reuvers, A.J., Boom, R.M. and Wienk, I.M. (1992), "Microstructures in phase-inversion membranes. Part 1. Formation of macrovoids", J. Membrane Sci., 73(2-3), 259-275. https://doi.org/10.1016/0376-7388(92)80134-6
  62. Sohrabi, M.R. and Ghavami, M. (2010), "Comparison of direct yellow 12 dye degradation efficiency using UV/semiconductor and UV/$H_2O_2$/semiconductor systems", Desalination, 252(1-3), 157-162. https://doi.org/10.1016/j.desal.2009.10.009
  63. Soleimani, R., Shoushtari, N.A., Mirza, B. and Salahi, A. (2013), "Experimental investigation, modeling and optimization of membrane separation using artificial neural network and multi-objective optimization using genetic algorithm", Chem. Eng. Res. Des., 91(5), 883-903. https://doi.org/10.1016/j.cherd.2012.08.004
  64. Stawikowska, J. and Livingston, A.G. (2013), "Assessment of atomic force microscopy for characterisation of nanofiltration membranes", J. Membrane Sci., 425-426, 58-70. https://doi.org/10.1016/j.memsci.2012.08.006
  65. Tasdemir, M., Kocak, D., Usta, I., Akalin, M. and Merdan, N. (2007), "Properties of Polypropylene Composite Produced with Silk and Cotton Fiber Waste as Reinforcement", Int. J. Polym. Mater., 56, 1155-1165. https://doi.org/10.1080/00914030701323752
  66. Torras, C., Ferrando, F., Paltakari, J. and Garcia-Valls, R. (2006), "Performance, morphology and tensile characterization of activated carbon composite membranes for the synthesis of enzyme membrane reactors", J. Membrane Sci., 282(1-2), 149-161. https://doi.org/10.1016/j.memsci.2006.05.018
  67. Van der Bruggen, B., Cornelis, G., Vandecasteele, C. and Devreese, I. (2005), "Fouling of nanofiltration and ultrafiltration membranes applied for wastewater regeneration in the textile industry", Desalination, 175(1), 111-119. https://doi.org/10.1016/j.desal.2004.09.025
  68. Van der Bruggen, B., Curcio, E. and Drioli, E. (2004), "Process intensification in the textile industry: the role of membrane technology", J. Environ. Manage., 73(3), 267-274. https://doi.org/10.1016/j.jenvman.2004.07.007
  69. Van der Zee, F.P., Lettinga, G. and Field, J.A. (2001), "Azo dye decolourisation by anaerobic granular sludge", Chemosphere, 44(5), 1169-1176. https://doi.org/10.1016/S0045-6535(00)00270-8
  70. Yakovlev, A.V., Finaenov, A.I., Yakovleva, E.V. and Finaenova, E.V. (2004), "Use of thermally expanded graphite in water-purification and water-treatment systems", Russ. J. Appl. Chem., 77(11), 1815-1817. https://doi.org/10.1007/s11167-005-0166-6
  71. Yang, H., Li, H., Zhai, J., Sun, L. and Yu, H. (2014), "Simple Synthesis of Graphene Oxide Using Ultrasonic Cleaner from Expanded Graphite", Ind. Eng. Chem. Res., 53(46), 17878-17883. https://doi.org/10.1021/ie503586v
  72. Yang, S. and Liu, Z. (2003), "Preparation and characterization of polyacrylonitrile ultrafiltration membranes", J. Membrane Sci., 222(1-2), 87-98. https://doi.org/10.1016/S0376-7388(03)00220-5
  73. Yoshikawa, M., Shimada, H., Tsubouchi, K. and Kondo, Y. (2000), "Specialty polymeric membranes: 12. Pervaporation of benzene-cyclohexane mixtures through carbon graphite-nylon 6 composite membranes", J. Membrane Sci., 177(1-2), 49-53. https://doi.org/10.1016/S0376-7388(00)00463-4
  74. Yunessnia lehi, A., Akbari, A. and Bojaran, M. (2013), "Preparation of nanoporous poly(vinylidene fluoride) membrane and consideration of its performance", Iran. J. Chem. Chem. Eng., 32(2), 15-29.
  75. Zhao, S., Wang, Z., Wei, X., Tian, X., Wang, J., Yang, S. and Wang, S. (2011), "Comparison study of the effect of PVP and PANI nanofibers additives on membrane formation mechanism, structure and performance", J. Membrane Sci., 385-386, 110-122. https://doi.org/10.1016/j.memsci.2011.09.029
  76. Zhu, L.P., Xu, L., Zhu, B.K., Feng, Y.X. and Xu, Y.Y. (2007), "Preparation and characterization of improved fouling-resistant PPESK ultrafiltration membranes with amphiphilic PPESK-graft-PEG copolymers as additives", J. Membrane Sci., 294(1-2), 196-206. https://doi.org/10.1016/j.memsci.2007.02.038

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