• Title/Summary/Keyword: Concentration model

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A Case Study of Characterization of AOC Formation

  • Kim, Ji-Hoon;Hwang, Hyeon-Uk;Kim, Young-Ju
    • Journal of Environmental Science International
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    • v.19 no.3
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    • pp.261-267
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    • 2010
  • The variation of assimilable organic carbon(AOC) concentration at each condition of ozonation was investigated using a model water and drinking water resource. AOC concentration of model raw water and drinking water resource tended to increase at low ozone dose. The maximum AOC concentration was detected when the residual ozone begin to be measured. Also, the AOC concentration increase at pH 8 compared to both pH 6 and 7 while that for pH 9 decreased rapidly. The removal characteristics of trihalomethane formation potential(THMFP) by ozonation was also investigated. Unlike the trend of AOC, the THMFP concentration never increased by ozonation but decreased even at low ozone dosage. From these results, the ozone dosage would be effective to simultaneously decrease both AOC and THMFP.

Combined Effect of Lidocaine Hydrochloride with Some Surfactants ( I ) (유화제(乳化劑)와 Lidocaine.HCl의 병용효과에 관(關)한 연구(硏究)( I ))

  • Kim, Yong-Hyoun;Yeum, Chul-Ho;Choi, Jun-Shik
    • Journal of Pharmaceutical Investigation
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    • v.12 no.2
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    • pp.31-36
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    • 1982
  • The effect of some surfactants, such as tween 40, tween 80, span 80, and triethanolamine, on the absorption of lidocaine was studied using goldfish as a model of absorption kinetics. This model was believed that reciprocal overturn time and death time were the occurrence of biological effect versus drug absorption. The results were as follows; The threshold concentration of lidocaine was significantly reduced by the surfactants. Overturn time and death time of goldfish in the lidocaine solution were reduced by such surfactants as tween 40, tween 80, span 80 and triethanolamine, and more reduced with increasing concentration of surfactants except tween 40 and tween 80. The plots of reciprocal death time versus lidocaine concentration were linear relationship with a positive concentration intercept such as minimum effective concentration (0.2-0.8%). As results it is believed that these surfactants may form complexes with lidocaine or affect the goldfish membrane to make more permeable to lidocaine, which is adsorbed more rapidly.

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Development of Three-Dimensional Cohesive Sediment Transport Model and Diffusion of Suspended Sediment at Suyoung Bay (3차원 점성토(粘性土) 운송(運送) 모델의 개발(開發)과 수영만(水營灣)의 부유물질 확산)

  • Kim, Cha Kyum;Lee, Jong Sup
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.13 no.1
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    • pp.179-192
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    • 1993
  • Three-dimensional cohesive sediment transport model, COSETM-3, is develpoed using a finite difference method. The model results are compared with the physical experimental results for the relative concentration with time at the mid-depth of the recirculating flume and are found to be in good agreement. This model is applied to Suyoung Bay in Pusan of Korea to verify the field applicability of the model and to investigate on the SS (suspended solids) diffusion phenomena at the bay. Behaviors of discharging SS from Suyoung River at normal river flow and flood river flow are predicted. The numerical results appear to be reasonable and qualitative agreement with field data. The influence of settling velocity on the concentration distribution of SS is also investigated. In case of not considering settling velocity, SS concentration at surface layer is higher than that at lower layer, but in case of considering settling velocity, SS concentration at lower layer is higher than that at surface layer. The fluctuation of SS concentration at surface layer is large due to the strong mixing, but the fluctuation of the concentration at lower layer is small due to the weak mixing. SS diffusion patterns at flood river flow are similar to those at normal river flow, while the concentration at that flow is so much higher than that at this flow. SS concentration increases with time until the peak discharge occurs, but the concentration decreases with time with decreasing river flow after the peak discharge.

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The Characteristic and Control of Contaminant Transport through the Subsurface of Nanjido Landfill (난지도 매립장 지반을 통한 오염이동 특성과 제어)

  • 장연수;이광열
    • Journal of the Korean Society of Groundwater Environment
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    • v.1 no.1
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    • pp.1-5
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    • 1994
  • The contaminant migration through the subsurface of Nanjido landfill is studied using a 2-D finite element model of contaminant transport. The leachate mounding caused by the installation of partial slurry wall around the pheriperal area of the Landfill is analysed using the finite difference model of groundwater flow. Model parameters were validated using in-situ concentration data and the behavior of the transport next 30 years is predicted. The sensitivities of chloride concentration by the change of model parameters, e.g. leachate mounding in the Landfill and the dispersivity are analysed. The results of the analyses show that the maximum chloride concentration level near Han River caused by the leachate of Nanjido Landfill would be 1488mg/1 and comes 17 years after the landfill closure. Increase of the leachate concentration is caused by the increase of both the leachate mounding and the dispersivity. However, the rate of concentration increase becomes higher with the rise of leachate mounding level, while it tends to converge a certain concentration with the increase of the dispersivity.

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Phosphorus Budget of a River Reservoir, Paldang (하천형 호수인 팔당호의 인 수지)

  • Kong, Dongsoo
    • Journal of Korean Society on Water Environment
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    • v.34 no.3
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    • pp.270-284
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    • 2018
  • Paldang is a river reservoir located in the Midwest of Korea, with a water volume of $244{\cdot}10^6m^3$ and a water surface area of $36.5km^2$. It has eutrophied since the construction of a dam at the end of 1973, and the phosphorus concentration has decreased since 2001. Average hydraulic residence time of the Paldang reservoir is about 10 days during the spring season and 5.6 days as an annual level. The hydraulics and water quality of the reservoir can differ greatly, both temporally and spatially. For the spring period (March to May) in 2001 ~ 2017, the reservoir mean total phosphorus concentration calculated from the budget model based on a plug-flow system (PF) and a continuous stirred-tank reaction system (CSTR) was 13 % higher and 10 % lower than the observed concentration, respectively. A composite flow system (CF) was devised by assuming that the transition zone was plug flow, and that the lacustrine zone was completely mixed. The mean concentration calculated from the model based on CF was not skewed from the observed concentration, and showed just 6 % error. The retention coefficient of the phosphorus derived from the CF was 0.30, which was less than those of the natural lakes abroad or river reservoirs in Korea. The apparent settling velocity of total phosphorus was estimated to be $93m\;yr^{-1}$, which was 6 ~ 9 times higher than those of foreign natural lakes. Assuming CF, the critical load line for the total phosphorus concentration showed a hyperbolic relation to the hydraulic load in the Paldang reservoir. This is different from the previously known straight critical load line. The trophic state of the Paldang reservoir has recently been estimated to be mesotrophic based on the critical-load curve of the phosphorus budget model developed in this study. Although there is no theoretical error in the newly developed budget model, it is necessary to verify the validity of the portion below the inflection point of the critical-load curve afterwards.

Optimization of Submerged Culture Conditions for the Production of Ginseng Root Using Response Surface Method (반응표면분석법을 이용한 인삼 Root 액체배양조건의 최적화)

  • 오훈일;장은정;이시경;박동기
    • Journal of Ginseng Research
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    • v.24 no.2
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    • pp.58-63
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    • 2000
  • To develop the production of ginseng root using plant tissue culture technology, submerged culture conditions were optimized by means of the fractional factorial design with 4 factors and 3 levels by a RSM computer program. The ginseng (Panax ginseng C. A. Meyer) roots induced by plant growth regulators were cultured on SH medium and the effects of various pH of medium, sucrose concentration, nitrogen concentration and phosphate concentration on fresh weight of the ginseng root were investigated. The fresh weight of ginseng root increased with a decrease in nitrogen concentration and fresh weight of ginseng root varied from 1.00 to 2.33g under various conditions. The optimum pH of medium and sucrose concentration determined by a partial differentiation of the model equation, nitrogen and phosphate concentration were pH 5.6, sucrose 3.8%, nitrogen 50 mg/L and phosphate 80.7 mg/L, respectively. Under these conditions, the predicted growth of ginseng root was estimated to be 2.36g.

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Effect of Environmental Factors on the Determination of the Ecotoxicological Threshold Concentration of Cu in Soil Pore Water through Biotic Ligand Model and Species Sensitivity Distribution (Biotic ligand model과 종 민감도 분포를 이용한 토양 공극수 내 Cu의 생태독성학적 허용농도 결정에 미치는 환경인자의 영향)

  • Yu, Gihyeon;An, Jinsung;Jeong, Buyun;Nam, Kyoungphile
    • Journal of Soil and Groundwater Environment
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    • v.22 no.1
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    • pp.49-58
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    • 2017
  • Biotic ligand model (BLM) and species sensitivity distribution (SSD) were used to determine the site-specific Cu threshold concentration (5% hazardous concentration; HC5) in soil pore water. Model parameters for Cu-BLM were collected for six plants, one collembola, and two earthworms from published literatures. Half maximal effective concentration ($EC_{50}\{Cu^{2+}\}$), expressed as $Cu^{2+}$ activity, was calculated based on activities of major cations and the collected Cu-BLM parameters. The $EC_{50}\{Cu^{2+}\}$ varied from 2 nM to $251{\mu}M$ according to the variation in environmental factors of soil pore water (pH, major cation/anion concentrations) and the type of species. Hazardous activity for 5% (HA5) and HC5 calculated from SSD varied from 0.076 to $0.4{\mu}g/L$ and 0.4 to $83.4{\mu}g/L$, respectively. HA5 and HC5 significantly decreased with the increase in pH in the region with pH less than 7 due to the decrease in competition with $H^+$ and $Cu^{2+}$. In the region with pH more than 7, HC5 increased with the increase in pH due to the formation of complexes of Cu with inorganic ligands. In the presence of dissolved organic carbon (DOC), Cu and DOC form a complex, which decreases $Cu^{2+}$ activity in soil pore water, resulting in up to 292-fold increase in HC5 from 0.48 to $140{\mu}g/L$.

Evaluation of Concentration Polarization at Feed in the Permeation of VOCs/$N_2$ mixtures through PDMS membrane (VOCs/질소 혼합물 증기투과시 공급액부 경계층에서의 농도분극 분석을 위한 모델식 확립)

  • 염충균;이상학;최정환;이정민
    • Membrane Journal
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    • v.11 no.2
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    • pp.74-82
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    • 2001
  • By using a phenomenological approach, model equations incorporating the resistance-in¬series concept were established to evaluate quantitatively concentration polarization in the boundary layer in feed adjacent to the membrane surface in the vapor permeation and separation of volatile organic compounds (VOCS)/$N_2$ mixture through po]y(dimethylsiloxane) (PDMS) membrane. The vapor permeations of various VOCS/$N_2$ mixtures through PDMS membrane were carried out at various feed flow rates. Chlorinated hydrocarbons, such as, methylene chloride, chlorofonn, 1,2-clichloroethane and 1,1,2-trichloroethane were used as organic vapor. By fitting the model equations to the experimental penneation data. the model parameters were detennined. respectively. Both the mass transfer coefficient of VOC across tbe boundary layer and concentration polarization modulus as a measure of the extent of concentration polarization were eitimated Quantitatively by the mooe1 equations with the determined model parameters. From the analysis on the detennined model parameters, the boundary layer resistance due to the concentration polarization of VOCs component was found to be more significant when the condensability of voe was greater. This study seeks to emphasize the importance of the boundary resistance on the vapor penneation of the vapor/gas mixtures with high permeability and high selectivity towards the minor component VOC.

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Concentration of Citrus Essence Aroma Model Solution by Pervaporation (투과증발법을 이용한 감귤 Essence Aroma 모델액의 농축)

  • Lee Yong-Taek;Park Joong-Won;Shin Dong-Ho
    • Membrane Journal
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    • v.16 no.1
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    • pp.68-76
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    • 2006
  • This is the research about the concentration of trace citrus flavor components in water by pervaporation. We have investigated the permeation characteristics depending on the material and formation of membranes using four siloxane-based polymer composite membranes. We have also chosen the optimal membrane and investigated the permeation characteristics depending on the feed temperature, concentration and flow rate. And then it has been analyzed by using resistance-in series model. In the permeation experiment of citrus essence aroma model solution through the four siloxane-based polymer composite membranes, PVDF/POMS membranes have showed the best flavor flux and enrichment factor. As a result of the permeation experiment depending on the feed temperature, concentration and flow rate, we can find that as the feed temperature and concentration increase, the flavor flux increases while the enrichment factor decreases. And the flavor flux and enrichment factor increased as the flow rate increases.

Chemical Equilibrium Modeling for Magnetite-Packed Crevice Chemistry in a Nuclear Steam Generator

  • Bahn, Chi-Bum;Rhee, In-Hyoung;Hwang, Il-Soon;Park, Byung-Gi
    • Bulletin of the Korean Chemical Society
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    • v.26 no.11
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    • pp.1783-1789
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    • 2005
  • Modeling of a steam generator crevice in a nuclear power system needs to take into account both thermalhydraulic and chemical phenomena. As a first step towards developing a reliable model, a chemical equilibrium model was developed to predict chemical speciation in a magnetite-packed crevice by adopting the “tableau” method. The model was benchmarked with the available experimental data and the maximum deviation did not exceed two orders of magnitude. The developed model was applied to predict the chemical speciation in a magnetite-packed crevice. It was predicted that caustic environment was developed by the concentration of NaOH and the dissolution of magnetite. The model indicated that the dominant aqueous species of iron in the caustic crevice was $FeO_2\;^-$. The increase of electrochemical corrosion potential observed in the experiment was rationalized by the decrease of dissolved hydrogen concentration due to a boiling process. It was predicted that under the deaerated condition magnetite was oxidized to hematite.