• Journal of the Korea Organic Resources Recycling Association
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• v.4 no.1
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• pp.23-31
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• 1996

The heavy metal concentration in mixed and separately collected household food waste, and their compost during the composting period was analysed. The mixed and separately collected food waste had Cd content of 8 mg/kg in spring and its content of 13 mg/kg in winter respectively. Its content was higher than by-product compost limit value(5 mg Cd/kg). Cd concentration in separately collected food waste in a house was higher in January, February, April and May than by-product compost limit value (5 mg Cd/kg). When Cd concentration in the initial composting material was higher than 5 mg/kg, its concentration in the compost of household food waste during the composting period was higher than by-product compost limit value, but it was not accumulated in the compost during the composting period. Fly ash was added to separately collected household food waste to adjust its moisture content for composting. Its addition had moisture conditioning and Cd concentration reducing effect in the compost. The average one month composted fresh compost from the mixed collected household food waste was matured in a pile out of doors for 7 months with turning the pile once a month and its heavy metal concentration was examined. Accumulation of the heavy metals in the compost did not occur during the composting period, because they were washed out during the rainfall.

• Journal of Environmental Impact Assessment
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• v.21 no.5
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• pp.695-705
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• 2012

The purpose of this study is to investigate concentration level and characteristics of malodour substances generated from landfill site in C city. Also, it is tried to predict distribution of concentration level using ISCST3 model around landfill site. From the results, it can be confirmed that twelfth-class malodour substances such as ammonia, methyl mercaptan, hydrogen sulfide, dimethyl sulfate, dimethyl disulfate, toluene, acetaldehyde, styrene, propionaldehyde, butylaldehyde, n-Valeraldehyde, xylene were generated from landfill site. The levels of the malodour substances were lower than that of permeable concentration regulated by odor control law in Korea. However, the concentration of malodour substances including methyl mercaptan, hydrogen sulfide, acetaldehyde, and propionaldehyde exceeded threshold limit value(TLV). It was seemed that these substances caused the problem of offensive odor around circumstance of landfill. The concentration of malodour substances was higher in slant than in upper part of landfill. The concentrations of malodour substances measured at night time were shown higher level than those at night time because atmospheric condition was stable at night time. It showed that the concentration of malodour substances were higher in spring. The results of atmospheric diffusion model predicted that tolerance limit level of hydrogen sulfide and methyl mercaptan was detected within nearly 5km from the boundary of landfill.

• Analytical Science and Technology
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• v.8 no.4
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• pp.1079-1087
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• 1995

The quality of human life is directly related to the quality of the environment. To assess environmental quality we must first determine the MCLG(Maximum Contaminant Level Goal), MCL(Maximum Contaminant Level), environmental impact and so on. The MCLG is the concentration at which no known adverse health effects occur. The MCLG is determined by risk assessment identifying which process is hazardous assessing, dose-response, human exposure, and characteristics of risk. With consideration of analytical methods, treatment technology, cost and regulatory impact, the MCL is set as close to the MCLG as possible. In this way, determination of the concentration and national distribution of contaminants is important for assessment of environmental quality The analytical sciences pose potential problems in assessing environmental quality. Continuing improvement in the performance of analytical instruments and operating technique has been lowering the limits of detectability. Contaminant concentration below the detection limit has usually been reported as ND(Not-Detected) and this has often been misunderstood as equivalent to zero. Because of this, more the contaminant concentration in the past was below the detection limit, whereas contaminants can be quantified now even though the contaminant concentration might remain the same or may even have decreased. In addition, environmental sampling has various components due to heterogeneous matrices. These samples are used to overestimate the concentration of the contaminant due to large variability, resulting in excess readings for MCL. In this paper, the significance of the analytical sciences is emphasized in both a conceptual and a technical approach to environmental assessment.

• Journal of Environmental Health Sciences
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• v.24 no.3
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• pp.99-106
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• 1998

This study was performed to investigate the bioconcentration of dichlorvos, methidathion and phosalone in zebrafish (brachydanio rerio), red sword tail(Xiphophorus hellieri). The fishes were exposed to 0.05 ppm, 0.01 ppm, 0.50 ppm, one-hundredth concentration of 96-hrs LC$_{50}$ and one-thousandth concentration of 96-hrs LC$_{50}$ and test periods were 3, 5 and 8 days. The deputation rate of each pesticide from the whole body of fish was determined over the 24-hr period after treatment. Obtained results are summerized as follows: In the case of dichlorvos, dichlorvos concentration in zebrafish extract and BCF$_{s}$ of dichlorvos were increased as increasing test concentration. In the case of same experimental concentrations, dichlorvos concentration in zebrafish extract and BCF$_{s}$ of dichlorvos were decreased as proloning test periods, especially dropped after 5days. Dichlorvos concentration in red sword tail extract were increased as increasing test concentration, lyat BCF$_{s}$ in concentration of 0.05 ppm, 0.01 ppm and one-hundredth of 96-hrs LC$_{50}$ were decreased. Methidathion and phosalone concentration in zebrafish extract in zebrafish extract were increased as increasing test concentration, but there was little difference in BCF$_{s}$. In the case of same experimental concentrations, there were little differences in BCF$_{s}$ and concentration in zebrafish extract. In the case of red sword tail, it was impossible to calculate on BCF$_{s}$ data because test concentration was under the detecting limit on GC or test fish were die. Determined deputation rate conatant were highest on dichlorvos, and followed by methidathion, and phosalone. The results of determining depuration rate of these pesticides showed that the high BCF in fish might be due to the slow depuration rate in fish, it is thought to be responsible for vapor pressure, water solubility and partition coefficient. It is suggested that one-hundredth concentration of 96-hrs LC$_{50}$ will be proper test concentration because one-thousundth of LC$_{50}$ was under the detecting limit on GC. Dichlorvos, methidathion and phosalone, organophosphorous pesticides, were examined to their BCF$_{s}$ and depuration rates by means of fish test.

• Korean Journal of Environmental Agriculture
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• v.36 no.3
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• pp.184-192
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• 2017

BACKGROUND: This study was performed to evaluate the residue dissipation of boscalid and spinetoram on crown daisy and sweet pepper affected by the morphology of the crop. The half-lives and dissipation rate constants for boscalid and spinetoram on crown daisy and sweet pepper were calculated. And then lower limit of 95% confidence interval for dissipation rate constant could be used to propose the pre-harvest residue limit. METHODS AND RESULTS: The pesticide products diluted according to the pesticide label were applied one time on crown daisy and sweet pepper at 2 field sites, respectively. Initial concentration of boscalid and spinetoram on crown daisy after application were in the range of 72.80~117.15 mg/kg and 2.82~4.67 mg/kg, respectively. And Initial concentration of boscalid and spinetoram on sweet pepper were in the range of 1.58~1.62 mg/kg and 0.10~0.21 mg/kg, respectively. Boscalid and spinetoram for crown daisy dissipted below the maximum residue limit(MRL) at 10 and 2 days after application, respectively. All residues concentration of boscalid and spinetoram for sweet pepper below the MRL at 0 day after application. The half-lives based on dissipation rate constant for boscalid and spinetoram on crown daisy were 4.2~4.9 days and 3.0~2.4 days respectively. And the half-lives for boscalid and spinetoram on sweet pepper were 6.7~7.0 days and 2.8~4.0 days respectively. CONCLUSION: The difference in initial concentration of boscalid and spinetoram among crop commodities were due to different crop morphology with larger surface areas. This study was suggested that pre-harvest residue limit would be calculated from lower limit of 95% confidence interval for dissipation rate constant and would be useful to protect consumers by controlling the pesticide residues in crop.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.8
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• pp.1089-1096
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• 2003

An experiment was performed to investigate lift-off, blow-off and combustion characteristics of a lifted coaxial diffusion flame according to fuel jet and air velocity. A jet diffusion flame which is attached on the nozzle rim begins to be lifted with increase of air velocity, and finally becomes blow-off at higher air velocity. In experiment, blow-off limit increased with increase of fuel jet velocity, however lift-off occurred at lower air velocity. Flame structure and combustion characteristics were examined by schlieren photos, temperature distributions and emission concentration distributions. Flame temperature became higher at midstream and its RMS became larger at up and downstream with increase of air velocity. Local NO concentration decreased but $CO_2$concentration increased with increase of air velocity, which shows combustion reaction becomes close to be stoichiometric at higher air velocity in spite of lift-off.

• Environmental Engineering Research
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• v.21 no.3
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• pp.247-255
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• 2016

Ten trace elements (Mg, Ca, V, Cr, Mn, Fe, Cu, Zn, Mo, and Cd) were determined in seven traditionally used wild medicinal plants of the Nagas in the North-East India viz Cynoglossum furcatum Wallich, Elsholtzia blanda Bentham, Lycopodium cernuum Linnaeus, Potentilla fulgens Wallich ex Hooker, Swertia macrosperma C.B. Clarke, Thalictrum foliolosum DC and Valeriana jatamansi Jones. Plant samples were dried, weighed, digested and analyzed for their mineral distribution level ranging from trace to major elements by graphite furnace-atomic absorption spectroscopy. All the medicinal herbs studied were found to contain the ten elements analyzed. The elemental concentration is given in mg/kg. Mg and Ca are present in high concentrations in both the roots and leaves of the plant samples. Among trace transition metals Fe had the highest concentration, followed by Mn, Cr, Cu, V, Zn, and Mo. Analysis showed that the toxic Cd element was at a lower concentration and is within the permissible limit of FAO/WHO, California standards and United States Pharmacopeia Limit for Nutritional Supplements.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.9 no.2
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• pp.257-263
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• 2008

We have examined explosion characteristics of bituminous coal dusts in cement manufacturing process. In order to find the thermal properties, we investigated weight loss and ignition temperature of coal materials using TGA and DSC. Also specific surface area of dust was investigated. Dust explosion experiments with Hartman's dust explosion apparatus have been conducted by varying concentration and size of coal dust for explosion probability and lower limit explosion concentration. According to the results for thermal properties, there is a little change by dust size. However, the specific surface area of dust is increased by decreasing dust size. The explosion test results show that small size and increasing concentration of dusts make dust explosion easier. And we find that the lower limit explosion concentration of bituminous coal is $0.3mg/cm^3$ and the probability is 100% on $0.9mg/cm^3$ in 170/200 mesh used in cement manufacturing process.

• Proceedings of the Safety Management and Science Conference
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• 2001.05a
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• pp.301-310
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• 2001

A study for the dangerous properties measurment of dust explosion was attended by the various dust concentration on Anthraquinone, Sodiumbenzoic acid, Corn starch, soy sauce powder, and cheese powder. As the result, maximum explosion pressure, the maximum rate of pressure rise, autoigntion temperature, and the water content of dust on lower limit explosion concentration was obtained as follows 1. The lower limit explosion concentration on soy sauce powder with the humidity of 65 to 90% increased by increasing the con tent of moisture, and the effect of dry air and moisture air decreased better in make of dry air. 2. The effect of a various dust concentration on autoigntion temperatures is investigated, If the vessel of dust explosion is small size and the easiness of autoignition was controled by air within the vessel, because it was better decreased air with increasing of dust concentration 3. The maximum explosion pressures of Anthraguinone, sodiumbenzoic acid, com starch, soy sauce powder, and cheese powder were 1.0g/$\ell$, 1.0g/$\ell$, 1.5g/$\ell$, 1.5g/$\ell$, and 1.5g/$\ell$, respectively, and the maximum rate of pressure rise were 0.5g/$\ell$, 0.5g/$\ell$, 1.0g/$\ell$, 1.0g/$\ell$, and 1.0g/$\ell$, respectively.

• Journal of the Korean Society of Safety
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• v.24 no.6
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• pp.27-31
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• 2009

An experimental study on the unsteady effect of the extinction limit was performed in ethene jet diffusion flames. To impose the unsteadiness on jet flames, the amplitude and frequency of a co-flow velocity was varied, and the two inert gases, $N_2$ and $CO_2$, were used to dilute the oxidizer for extinguishing concentration. The experimental results shows that large amplitude of velocity induces a low extinguishing concentration, which implies that flow variation affects the blow out mechanism. Also, the flow oscillation effects under high frequency attenuates the flame extinction. These results means that flow unsteadiness extends the extinction limit and finally minimum extinction concentration by inert gases. When the Stoke's 2nd Problem is introduced to explain the flow unsteadiness on extinction concentration, the solution predicts the effect of amplitude and frequency of velocity well, and hence it is concluded the effect of low frequency velocity excitation was attributed only to flow effect.