• 제목/요약/키워드: Concentration coefficient

검색결과 2,048건 처리시간 0.033초

Ultrasonic Velocity and Absorption Measurements in an Aqueous Solution of Poly(sodium 4-styrenesulfonate)

  • Rae Jong-Rim
    • Macromolecular Research
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    • 제12권6호
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    • pp.559-563
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    • 2004
  • Both the ultrasonic velocity at 3 MHz and the absorption coefficient in the frequency range from 0.2 to 2 MHz were measured for aqueous solutions of poly(sodium 4-styrenesulfonate) over the concentration range from 5 to $25\%$ (by weight). The pulse echo overlap method was employed to measure the ultrasonic velocity over the temperature range from 10 to $90^{\circ}C;$ the high-Q ultrasonic resonator method was used for the measurement of the absorption coefficient at $20^{\circ}C.$ The velocities exhibited their maximum values at ca. 55, 59, 63, 67, and $71^{\circ}C.$ for the 25, 20, 15, 10, and $5\%$ solutions, respectively. The velocity increased with respect to the poly(sodium 4-styrene-sulfonate) concentration at a given temperature. A study of the concentration dependence of the both the relaxation frequency and amplitude indicated that the relaxation at ca. 200 kHz is related to structural fluctuations of the polymer molecules, such as the segmental motions of the polymer chains and that the relaxation at ca. 1 MHz resulted from the proton transfer reactions of the oxygen sites of $SO_3.$ Both the absorption and the shear viscosity increase upon increasing the polymer concentration, but they decrease upon increasing the temperature.

移動汚染源에 대한 大氣擴散模型의 感應度 分析에 관한 硏究 (HIWAY2, PAL, CALINE3 模型을 對象으로) (A Study on the Sensitivity Analysis of Line Source Air Quality Models)

  • 김선태;김병태;김정욱
    • 한국대기환경학회지
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    • 제5권1호
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    • pp.1-10
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    • 1989
  • The sensitivity analysis is a method to quantify to what extent the output of a model changes with the values of input parameters. This will lead to increase model accuracy through measurement validation. Three line source air quality models, HIWAY 2, PAL, and CALINE 3 were selected for this study. The input parameters analysed included wind speed, wind direction, stability, emission rate, mixing height, receptor distance, initial dispersion coefficient, surface roughness, and averaging time. It turned out that PAL model generally showed higher concentration than other two models, and that between CALINE 3 and HIWAY 2, CALINE 3 showed higher concentration than HIWAY 2 model near the line sources, but beyond a certain downwind distances HIWAY 2 model showed higher concentration. The modesl were very sensitive to wind speed especially in the range of 0 $\sim$ 1 m/s and to wind direction near the parallel wind to streets. In case of emission rate, the output concentration was directly proportional to these input parameters. And the sensitivity of the input parameters such as stability, mixing height, initial dispersion coefficient, surface roughness, and averaging time were not very significant.

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Development of Lactose-hydrolyzed Milk with Low Sweetness Using Nanofiltration

  • Choi, S.H.;Lee, S.-B.;Won, H.-R.
    • Asian-Australasian Journal of Animal Sciences
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    • 제20권6호
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    • pp.989-993
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    • 2007
  • A lactose-hydrolyzed milk with low sweetness was developed using nanofiltration. Raw milk was treated with 0.03% ${\beta}$-galactosidase at $4^{\circ}C$ for 24 h to hydrolyze lactose partially. The resultant lactose-hydrolyzed milk containing 0.43% lactose was then concentrated using a nanofiltration membrane to reach concentration factor of 2.13. The concentration factors and coefficients of retention of milk components in nanofiltration were determined. The concentration factor of milk fat was 2.20 which was the highest of the milk components. The coefficient of retention of calcium and riboflavin was 0.96 and 0.76, respectively. However, the coefficient of retention of glucose, galactose, and sodium was 0.21, 0.15, and 0.22, respectively. Raw milk was treated with 0.1% ${\beta}$-galactosidase at $4^{\circ}C$ for 40 h to hydrolyze lactose fully and then concentrated to reach a concentration factor of 1.6 by using nanofiltration. The concentrated milk was reconstituted with water. The lactose-hydrolyzed milk had sweetness similar to milk. The compositional ratios of crude protein, calcium, sodium, and riboflavin of lactose-hydrolyzed nanofiltrated milk to those of raw milk were 99%, 97%, 77%, and 80%, respectively. This study showed that nanofiltration of lactose-hydrolyzed milk to remove galactose and glucose did not cause significant loss of calcium. The lactose-hydrolyzed nanofiltrated milk contained 0.06% lactose and had sweetness similar to milk.

한강의 부영양화에 대한 조사연구 (The Investigation of the Han River Eutrophication)

  • 신정식;정종흡;나규환
    • 환경위생공학
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    • 제14권4호
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    • pp.77-84
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    • 1999
  • Most river quality problems are generated by pollutants which are discharged into the river as a consequence of human activities. And eutrophication occurs when water is over enriched with nutrients, principally nitrate and phosphate. Both these nutrients are found in many waste products, especially sewage even when the waste is treated. Eutrophication is concerned in lakes, but it also causes problems in river. Wide growth of Phytoplankton in rivers, leads to blockage of channels, but the main concern is deoxygenation because of the increase in plant life's demand for oxygen in revers. Fish, plant and animals die due to lack of oxygen. The increase of algae floating on the tops of water looks ugly and has attracted public attention and concern in recent years. One way of controlling eutrophication is to restrict the amount of waste carrying nitrate or phosphate from entering the water in the first place. another way is to remove it from the water after it has been entered. This study was carried out to investigate on the trophic state, nutrients and Chlorophyll-a concentration in the Han River. The results were as follows:1. Concentrations of total nitrogen were 2.208~9.221(5.133)mg/$\ell$2. Concentrations of total phosphate were 0.045~0.614(0.195)mg/$\ell$3. Chlorophyll-a concentration were $0.0-25.3(9.6)mg/m^3$.4. The correlation coefficient between T-P and Chlorophyll-a concentration was r=-0.856 at Sungsan sampling site.5. The correlation coefficient was r=-0.578~-0.767, between Paldang Dam outflow and Chlorophyll-a concentration at all sampling sites.

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연속강우시 산성우의 이온농도 변화에 관한 조사연구 (A Study on Ion Concentration Change of Acid Rain by the Succeeding Raintall)

  • 박경렬;김대선
    • 한국환경보건학회지
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    • 제16권2호
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    • pp.11-20
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    • 1990
  • To investigate ionic characteristics of acid rain by the succeeding rainfall. bulk precipitation was collected every each 5mm rainfall from march to october 1990 at Dae Jeon area. pH, sulfate nitrate, chloride, ammonium ion was measured and analyzed. The result was as follows: 1. The weighted average pH of rain was 5.1$\pm$ 0.72(4.15~7.6) and rain pH less than 5.5 was appeared 51.3% 2. Average ion concentrations of sulfate, nitrate, chloride and ammonium ion was 125.12 $\mu$eq/l, 62.38 $\mu$eq/l, 31.95 $\mu$eq/l, 66.6 $\mu$eq/l and rates of each anions was 57%, 28.4%, 14.6% and rate of sulfate by nitrate was 2 times. 3. There is no correlations time interval of rainfall and Ion concentration change. 4. From initial to 15mm rainfall, each ion concentrations were decreased. and average concentration of pH, SO$^{-2}_{4}$, Cl ion concentration was increased in the succeeding rainfall 5. Only sulfate ion was correlated by the simple regression analysis with pH except NO$^{-}_{3}$, Cl$^{-}$ and NH$_{4}^{+}$ Cl$^{-}$ correlation coefficient was very high at the multiple regression analysis with pH. 6. Simple & multiple correlation coefficient among anions and NH$^{+}_{4}$ was very high especially N$^{+}_{4}$ and SO$^{2-}_{4}$ at simple regression analysis and SO$^{-2}_{4}$ and NO$_{3}^{-}$, Cl$^{-}$, NH$_{4}^{-}$ at multiple regression analysis.

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광양만내의 현장 부유입자물질 분포와 거동 (Distribution and Behaviors of In-Situ Suspended Particulate Matters of Gwangyang Bay)

  • 이병관;김석윤;조현만
    • 한국해양공학회지
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    • 제24권1호
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    • pp.99-105
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    • 2010
  • The concentration and size analysis of in-situ suspended particulate material were measured using an optical instrument, LISST-100, in the bottom layer at the three inlets of the Seomjin River Estuary, mouth of Gwangyang bay, and Gwangyang bay-side of the Namhae Bridge. In the Seomjin river estuary and mouth of Gwangyang bay-side of the Namhae Bridge, the in-situ mean grain size of the suspended material changed from a uni-modal distribution with a dominant peak at a coarse fraction to a bi-modal distribution with a secondary peak at the finer particles. Seomjin River. The interactions between suspended particulate concentration and beam attenuation coefficient of suspended particulate matters depended on the supply of finer and coarser particles in the mouth of Gwangyang Bay and Seomjin River. So, interactions reflected difference of the concentration, mean size and sorting of suspended particulate matters. The difference of interaction showed dynamic behaviors to the resuspension and deflocculation processes increased river discharge. This showed that it may be possible to use the interactions between the suspended particle concentration and beam attenuation coefficient to monitor the temporal and spatial distributions of in-situ particles.

Heat Transfer Characteristics of Liquid-Solid Suspension Flow in a Horizontal Pipe

  • Ku, Jae-Hyun;Cho, Hyun-Ho;Koo, Jeong-Hwan;Yoon, Suk-Goo;Lee, Jae-Keun
    • Journal of Mechanical Science and Technology
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    • 제14권10호
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    • pp.1159-1167
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    • 2000
  • Particles in liquid-solid suspension flow might enhance or suppress the rate of heat transfer and turbulence depending on their size and concentration. The heat transfer characteristics of liquid-solid suspension in turbulent flow are not well understood due to the complexibility of interaction between solid particles and turbulence of the carrier fluid. In this study, the heat transfer coefficients of liquid-solid mixtures are investigated using a double pipe heat exchanger with suspension flows in the inner pipe. Experiments are carried out using spherical fly ash particles with mass median diameter ranging from 4 to $78{\mu}m$. The volume concentration of solids in the slurry ranged from 0 to 50% and Reynolds number ranged from 4,000 to 11,000. The heat transfer coefficient of liquid-solid suspension to water flow is found to increase with decreasing particle diameter. The heat transfer coefficient increases with particle volume concentration exhibiting the highest heat transfer enhancement at the 3% solid volume concentration and then gradually decreases. A correlation for heat transfer to liquid-solid flows in a horizontal pipe is presented.

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키토산 가교처리된 면직물의 태 변화에 관한 연구 - 에피클로로히드린과 키토산 농도의 영향- (A study on the Change of Hand of Chitosan Crosslinked Cotton Fabrics - Effect of Concentration of Epichlorohydrin and Chitosan -)

  • 김민지;박정우;이신희
    • 한국의류산업학회지
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    • 제6권5호
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    • pp.660-666
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    • 2004
  • This article describes the change of hand value of chitosan crosslinked cotton fabrics. The chitosan crosslinked cotton fabrics were manufactured by mercerizing process using epichlorohydrin(ECH) as crosslinkins agent, 2% aqueous acetic acid as a solvent of chitosan and ECH, and 20% aqueous sodium hydroxide as a mercerizing agent and crosslinking catalyst. Cotton fabrics were dipped in the mixed solution of chitosan and ECH, picked up by mangle, mercerized and crosslinked in NaOH solution, and finally wash and dry. Mechanical and physical properties of the chitosan crosslinked fabric were investigated using Kawabata Evaluation System(KES) and other instruments. Tensile energy and tensile strain were decreased with the increase of the concentration of chitosan. Tensile resilience, compression resilience bending rigidity, bending hysteresis, shear stiffness, shear hysteresis, coefficient of friction, geometrical roughness, compression linearity, compressional energy, and thickness were increased with the increase of the concentration of chitosan. On the other hand, bending rigidity, bending hysteresis, coefficient of friction, geometrical roughness, compressional resilience, and thickness were increased with the increase of the concentration of crosslinking agent(epichlorohydrin).

흡수식 시스템의 용액열교환기용 판형열교환기의 열전달 및 압력강하 특성 실험 (Heat transfer and pressure drop characteristics of plate heat exchangers for absorption application)

  • 김현준;김정환;김성수;정진희;강용태
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2005년도 동계학술발표대회 논문집
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    • pp.347-352
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    • 2005
  • The objectives of this paper are to study the characteristics of heat transfer and pressure drop in plate heat exchangers for absorption applications, and to quantify the effect of mass flow rate, solution concentration, and geometric conditions such as chevron angle on the heat transfer coefficient and pressure drop in the plate heat exchangers. The working fluid is $H_2O$/LiBr solution with the LiBr concentration range of 53.2 - 62.5 % in mass. The results show that the overall heat transfer coefficient increases linearly with increasing Re. The heat transfer rate increases with increasing the chevron angle while it does not significantly depend on the LiBr concentration. The pressure drop also increases with increasing the chevron angle. The effect of the chevron angle on the pressure drop is more significant than that of the concentration.

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Continuous ion-exchange membrane electrodialysis of mother liquid discharged from a salt-manufacturing plant and transport of Cl- ions and SO42- ions

  • Tanaka, Yoshinobu;Uchino, Hazime;Murakami, Masayoshi
    • Membrane and Water Treatment
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    • 제3권1호
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    • pp.63-76
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    • 2012
  • Mother liquid discharged from a salt-manufacturing plant was electrodialyzed at 25 and $40^{\circ}C$ in a continuous process integrated with $SO_4{^{2-}}$ ion low-permeable anion-exchange membranes to remove $Na_2SO_4$ and recover NaCl in the mother liquid. Performance of electrodialysis was evaluated by measuring ion concentration in a concentrated solution, permselectivity coefficient of $SO_4{^{2-}}$ ions against $Cl^-$ ions, current efficiency, cell voltage, energy consumption to obtain one ton of NaCl and membrane pair characteristics. The permselectivity coefficient of $SO_4{^{2-}}$ ions against $Cl^-$ ions was low enough particularly at $40^{\circ}C$ and $SO_4{^{2-}}$ transport across anion-exchange membranes was prevented successfully. Applying the overall mass transport equation, $Cl^-$ ion and $SO_4{^{2-}}$ ion transport across anion-exchange membranes is evaluated. $SO_4{^{2-}}$ ion transport number is decreased due to the decrease of electro-migration of $SO_4{^{2-}}$ ions across the anion-exchange membranes. $SO_4{^{2-}}$ ion concentration in desalting cells becomes higher than that in concentration cells and $SO_4{^{2-}}$ ion diffusion is accelerated across the anion-exchange membranes from desalting cells toward concentrating cells.