• Title/Summary/Keyword: Concentration Correction Factor

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Ultrafiltration Characteristics of Poly(vinyl Alcohol) Solution and Theoretical Investigations (Poly(vinyl Alcohol) 용액의 한외여과 특성과 이론적 고찰)

  • 이상화;이영철
    • Membrane Journal
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    • v.6 no.4
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    • pp.203-212
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    • 1996
  • The operating parameters influencing on limiting flux was investigated in the ultrafiltration of PVA, and a new model, which is based on the Amiar model using the concept of heat transfer coefficient, was devised to overcome the limitation of gel-layer model. Using polysulfone plate-unit membrane (MWCO=20,000) and hollow-fiber membrane (MWCO= 30,000), ultrafiltration characteristics of PVA was examined with the variation of operating parameters such as cross flow velocity, transmembrane pressure, temperature, and PVA concentration. According to experimental results, the ultrafiltration of PVA through polysulfone membrane is mainly controlled by well-known phenomena of concentration polarization caused by gel-layer formation. On the contrary, in hollow fiber membrane was observed upward limiting flux which can not be explained by gel-layer model. New model was applied to predict the upward limiting flux behavior with partial satisfaction. The application of new model including viscosity correction factor, however, revealed that PVA ultrafiltration is closely related to the viscosity of permeating fluid.

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Estimation of PM2.5 Correction Factor for Optical Particle Counter in Ambient Air (대기환경에서 광산란 미세먼지 측정기의 PM2.5 보정계수 산정)

  • Kim, Jong Bum;Kim, Danbi;Noh, Sujin;Yoon, Kwan Hoon;Park, Duckshin;Lee, Jeong Joo;Kim, Jeongho
    • Particle and aerosol research
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    • v.16 no.2
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    • pp.49-59
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    • 2020
  • Various devices have been developed to the measurement of particulate matter pollutants, and Optical Particle Counter (OPC) that can be easily and quickly measured is widely used lately. The measured value by OPC is converted to weight concentration using the correction factor (CF). The calculation of CF is very important to improve the reliability and accuracy of OPC. In this study, the CF calculation study of light scattering laser photometer (model 8533, TSI) was carried out to measure in the atmospheric environment using 2 gravimetric devices and 3 light scattering laser photometer devices. Regression analysis and Tukey tests were used to significance the test of measurement devices. Measurements were carried out twice. There was a comparative analysis of measurement data between light scattering laser photometer and gravimetric devices in 1st measurement, and then the Evaluation of PM2.5 concentration corrected by CF performed in 2nd measurement. As a result of the significance analysis between light scattering laser photometer and gravimetric devices, the correlation between the same method was high, but the correlation between different methods was low. CF was calculated as 0.4258 based on the measurement results, and it is a similar level to previous studies at home and abroad. It is expected that these results can be used as basic data in the future study for air quality measurement research using light scattering laser photometer. Also, in order to improve the accuracy of the measurement techniques and the development of technology in the atmospheric environment, CF calculation research should be conducted continuously.

Empirical Estimation and Diurnal Patterns of Surface PM2.5 Concentration in Seoul Using GOCI AOD (GOCI AOD를 이용한 서울 지역 지상 PM2.5 농도의 경험적 추정 및 일 변동성 분석)

  • Kim, Sang-Min;Yoon, Jongmin;Moon, Kyung-Jung;Kim, Deok-Rae;Koo, Ja-Ho;Choi, Myungje;Kim, Kwang Nyun;Lee, Yun Gon
    • Korean Journal of Remote Sensing
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    • v.34 no.3
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    • pp.451-463
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    • 2018
  • The empirical/statistical models to estimate the ground Particulate Matter ($PM_{2.5}$) concentration from Geostationary Ocean Color Imager (GOCI) Aerosol Optical Depth (AOD) product were developed and analyzed for the period of 2015 in Seoul, South Korea. In the model construction of AOD-$PM_{2.5}$, two vertical correction methods using the planetary boundary layer height and the vertical ratio of aerosol, and humidity correction method using the hygroscopic growth factor were applied to respective models. The vertical correction for AOD and humidity correction for $PM_{2.5}$ concentration played an important role in improving accuracy of overall estimation. The multiple linear regression (MLR) models with additional meteorological factors (wind speed, visibility, and air temperature) affecting AOD and $PM_{2.5}$ relationships were constructed for the whole year and each season. As a result, determination coefficients of MLR models were significantly increased, compared to those of empirical models. In this study, we analyzed the seasonal, monthly and diurnal characteristics of AOD-$PM_{2.5}$model. when the MLR model is seasonally constructed, underestimation tendency in high $PM_{2.5}$ cases for the whole year were improved. The monthly and diurnal patterns of observed $PM_{2.5}$ and estimated $PM_{2.5}$ were similar. The results of this study, which estimates surface $PM_{2.5}$ concentration using geostationary satellite AOD, are expected to be applicable to the future GK-2A and GK-2B.

Sensitivity Analysis of Initial Pressure and Upper Control Limit on the Pressure Decay Test for Membrane Integrity Evaluation (압력손실시험을 이용한 막 완결성 평가에서 초기압력 및 UCL 도출인자 민감도 분석)

  • Lee, Joohee;Hong, Seungkwan;Hur, Hyunchul;Lee, Kwangjae;Choi, Youngjune
    • Journal of Korean Society on Water Environment
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    • v.24 no.6
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    • pp.793-800
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    • 2008
  • Recently domestic drinking water industry has recognized membrane-based technology as a promising alternative for water treatment. To ensure successful application of membrane processes, the integrity of membrane systems should be maintained. According to US EPA guidance, the pressure decay test based on the bubble point theory is recommended to detect any membrane defection of which size is close to the smallest diameter of Cryptosporidium oocysts, $3{\mu}m$. Proper implementation of the pressure decay test is greatly affected by initial test pressure, and the interpretation of the test results is associated with upper control limit. This study is conducted to investigate various factors affecting determination of initial test prtessure and upper control limit, including membrane-based parameters such as pore shape correction factor, surface tension and contact angle, and system-based parameters, such as volumetric concentration factor and total volume of system. In this paper, three different hollow fibers were used to perform the pressure decay test. With identical initial test pressure applied, their pressure decay tendency were different from each other. This finding can be explained by the micro-structure disparity of those membranes which is verified by FESEM images of those membranes. More specifically, FESEM images revealed that three hollow fibers have asymmetry, deep finger, shallow finger pore shape, respectively. In addition, sensitivity analysis was conducted on five parameters mentioned above to elucidate their relation to determination of initial test pressure and upper control limit. In case of initial pressure calculation, the pore shape correction factor has the highest value of sensitivity. For upper control limit determination, system factors have greater impact compared to membrane-based parameters.

Determination of Neutron Absorption Fraction Factor in Manganese Sulfate Bath System (황산망간 용액조 장치의 중성자 흡수분율 보정인자 결정)

  • Lee, Kyung-Ju;Park, Kil-Oung;Hwang, Sun-Tae;Lee, Kun-Jai
    • Nuclear Engineering and Technology
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    • v.21 no.1
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    • pp.12-17
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    • 1989
  • The correction factor of neutron fraction absorbed by $^{55}$ Mn in the MnSO$_4$ bath was determined for the absolute measurement of neutron emission rate by using the solution circulation-type manganese sulfate bath system. For the determination of this correction factor, I/f, the atomic number desnsity and the effective neutron capture cross section data of Mn, S and impurity elements in the MnSO$_4$ solution were determined. For the atomic number density determination, the MnSO$_4$ solution concentration was determined by using the volumetric EDTA titration and gravimetric method. The impurity contents were analyzed by using the ICP method. For the calculation of effective neutron capture cross sections, a FORTRAN computer program EASCAL was developed in this study. in which Westcott's parameters and Axton's empirical relations are used.

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Preliminary Study on Effect of the Field Correlation Factor for Increasing of the Accuracy in a Direct Reading Instruments on Photoionization Detector for Total Volatile Organic Compounds (총휘발성유기화합물 측정 직독식장비 정확도 향상을 위한 현장보정계수 활용 연구)

  • Sungho Kim;Gwangyong Yi;Sujin Kim;Hae Dong Park
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.34 no.1
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    • pp.67-76
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    • 2024
  • Objectives: Direct reading instruments (DRIs) are widely used by industrial hygienists and other experts for preliminary survey and identifying source locations in many industrial fields. Photoionization detectors (PIDs), which are a form of hand-held portable DRIs, have been used for a variety of airborne vaporized chemicals, especially evaporated hydrocarbon solvents. The benefits of PIDs are high sensitivity between each chemical, competitive price, and portability. With the goal of increasing the accuracy of logged PID concentrations, previous studies have performed tests for the assessment of single chemical compounds, not mixtures. The purpose of this preliminary study was to measure mixtures with a PID and charcoal tube at the same time and compare the accuracy between them. Methods: A chamber test was implemented with different mixtures of hydrocarbon chemicals (acetone, isopropyl alcohol, toluene, m-xylene) and levels in the range of 14 to 864 ppm. Three PIDs and charcoal tubes were connected to the chamber and measured the chemical mixtures simultaneously. A comparison of accuracy and the PID group of concentrations with manufacture correction factor (M_CF) and field correction factor (F_CF) applied was performed. Results: The accuracy of the PID concentrations data-logged from the PID did not meet the accuracy criteria except for the mixture level B and C logged from PID No. 2, which was 18% of all tests for meeting accuracy criteria. The mean and standard deviation (SD) of concentration (ppm) of the charcoal tube followed by each mixtures' level were 10.37±0.26, 155.33±5.28, 300.80±11.65, and 774.93±22.65, respectively. When applying F_CF into the PID concentrations, the accuracy increased by nearly 82%. However, in the case of M_CF, none met the accuracy criterion. Between the PID there were differences of logged concentrations. Conclusions: In this preliminary study, the concentration of a logged PID with F_CF applied was a better way to increase accuracy compared to applying M_CF. We suggest that additional research is necessary to consider environmental factors such as temperature and humidity.

Development of Poisson cluster generation model considering the climate change effects (기후변화 영향을 고려한 포아송 클러스터 가상강우생성모형 개발 및 검증)

  • Park, Hyunjin;Han, Jaemoon;Kim, Jongho;Kim, Dongkyun
    • Proceedings of the Korea Water Resources Association Conference
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    • 2015.05a
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    • pp.189-189
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    • 2015
  • 본 연구는 기후변화의 영향을 고려한 포아송 강우생성모형의 일종인 MBLRP(Modified Bartlett-Lewis Rectangular Pulse)를 개발하고, 대한민국 주요 도시에 대해 향후 100년간 강우의 변화를 살펴보았다. 기존 MBLRP 모형에서 기후변화에 따른 강우량 변화를 고려할 수 있도록 GCM 모형의 강우 자료를 활용하였고, GCM 모형으로부터 발생하는 불확실성을 고려하기 위해 IPCC의 RCP(Representative Concentration Pathways) 시나리오를 모의한 16개의 GCM 모형을 사용하였다. 2007년부터 2099년까지의 미래기간을 3개의 시 구간으로 구분하고, 16개 GCM 앙상블을 사용하여 미래기간 동안 대한민국 16개 도시에 대해 1000개의 샘플을 BWA 방법을 이용하여 생성하였다. 제어기간(1973-2005) 대비 미래기간(2007-2099)의 변화율을 나타내는 FOC(factor of change)와 온도의 연별 변화율을 나타내는 SF(scaling factor)의 개념을 결합하여 미래기간에 대한 CF(correction factor)를 산정하였다. 이때 CF는 16개 도시의 연 단위 강우량 변화 비율을 월별로 나타내며, 제어기간의 월 강우 관측치와 CF를 몬테카를로 모의를 실시하여 미래기간의 강우 시나리오를 산정한다. 이를 통해 월 평균 강우량 통계치를 연 단위로 얻을 수 있으며, 월 평균 강우량이 월 평균 분산, 무강우확률, 자기상관계수와 가지는 선형 관계를 통해 강우 통계치를 산출한다. 이와 같은 강우 통계치는 가상강우생성모형인 MBLRP 모형에 입력 자료로 활용되어 월 강우량을 시 단위의 강우 시계열 자료로 생성해낸다. 최종적으로 MBLRP 모형으로 산정된 시 단위 강우 시계열은 기후변화 영향을 고려한 GCMs 앙상블로 생성된 강우 시나리오를 기반으로 산출되기 때문에 향후 수자원 분석에 활용 가능할 것이라 기대된다.

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PM2.5 Simulations for the Seoul Metropolitan Area: (III) Application of the Modeled and Observed PM2.5 Ratio on the Contribution Estimation (수도권 초미세먼지 농도모사: (III) 관측농도 대비 모사농도 비율 적용에 따른 기여도 변화 검토)

  • Bae, Changhan;Yoo, Chul;Kim, Byeong-Uk;Kim, Hyun Cheol;Kim, Soontae
    • Journal of Korean Society for Atmospheric Environment
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    • v.33 no.5
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    • pp.445-457
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    • 2017
  • In this study, we developed an approach to better account for uncertainties in estimated contributions from fine particulate matter ($PM_{2.5}$) modeling. Our approach computes a Concentration Correction Factor (CCF) which is a ratio of observed concentrations to baseline model concentrations. We multiply modeled direct contribution estimates with CCF to obtain revised contributions. Overall, the modeling system showed reasonably good performance, correlation coefficient R of 0.82 and normalized mean bias of 2%, although the model underestimated some PM species concentrations. We also noticed that model biases vary seasonally. We compared contribution estimates of major source sectors before and after applying CCFs. We observed that different source sectors showed variable magnitudes of sensitivities to the CCF application. For example, the total primary $PM_{2.5}$ contribution was increased $2.4{\mu}g/m^3$ or 63% after the CCF application. Out of a $2.4{\mu}g/m^3$ increment, line sources and area source made up $1.3{\mu}g/m^3$ and $0.9{\mu}g/m^3$ which is 92% of the total contribution changes. We postulated two major reasons for variations in estimated contributions after the CCF application: (1) monthly variability of unadjusted contributions due to emission source characteristics and (2) physico-chemical differences in environmental conditions that emitted precursors undergo. Since emissions-to-$PM_{2.5}$ concentration conversion rate is an important piece of information to prioritize control strategy, we examined the effects of CCF application on the estimated conversion rates. We found that the application of CCFs can alter the rank of conversion efficiencies of source sectors. Finally, we discussed caveats of our current approach such as no consideration of ion neutralization which warrants further studies.

Marinelli Beaker Measurement and Self Absorption Correction and Application for Various Environmental Samples in Monte Carlo Simulation (몬테카를로 시뮬레이션에서의 다양한 환경 샘플에 대한 Marinelli 비이커 측정 및 자기 흡수 보정과 적용)

  • Jang, Eun-Sung;Gim, Yang-Soo;Lee, Sun-Young
    • Journal of radiological science and technology
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    • v.40 no.4
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    • pp.605-611
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    • 2017
  • The structure of the actual detector was computed using the code of the PENELOPE. Using the standard mixed sources (450, 1,000 ml), compare the effectiveness of each energy according to various densities and height of the PENELOPE computer simulation, and calculate the effectiveness of the various environmental specimens and apply them to various environmental specimens to determine the lower limit. The values obtained by the obtained value were obtained by applying the obtained efficiency to the actual environmental specimens and obtaining the lower limit values. The density correction factor is 1.155 g of the density correction factor of $0.4g/cm^3$ (59.54keV), 1.153 (661 keV), $1.06g/cm^3$ 1.064 (1,836.04keV), 1.03, and 1.033. It was confirmed that the radioactivity concentration of environmental samples decreased as the amount of specimen was measured increases, and the MDA value decreased as time measured increases.

Environmental fatigue correction factor model for domestic nuclear-grade low-alloy steel

  • Gao, Jun;Liu, Chang;Tan, Jibo;Zhang, Ziyu;Wu, Xinqiang;Han, En-Hou;Shen, Rui;Wang, Bingxi;Ke, Wei
    • Nuclear Engineering and Technology
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    • v.53 no.8
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    • pp.2600-2609
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    • 2021
  • Low cycle fatigue behaviors of SA508-3 low-alloy steel were investigated in room-temperature air, high-temperature air and in light water reactor (LWR) water environments. The fatigue mean curve and design curve for the low-alloy steel are developed based on the fatigue data in room-temperature and high-temperature air. The environmental fatigue model for low-alloy steel is developed by the environmental fatigue correction factor (Fen) methodology based on the fatigue data in LWR water environments with the consideration of effects of strain rate, temperature, and dissolved oxygen concentration on the fatigue life.