• Journal of the Korean Society for Heat Treatment
• /
• v.17 no.2
• /
• pp.87-93
• /
• 2004

Nitrocarburizing was carried out with various $CH_4$ gas composition with 4 torr gas pressure at $570^{\circ}C$ for 3 hours and post oxidation was carried out with 100% $O_2$ gas atmosphere with 4 torr at different temperatures for various time. In the case of plasma nitrocarburizing, It is that the ratio of ${\varepsilon}-Fe_{2-3}$(N, C) and ${\gamma}^{\prime}-Fe_4$(C, N), which comprise the compound layer phase, depend on concentrations of $N_2$ gas and $CH_4$ such that when the concentration of $N_2$ and $CH_4$ increased, the ratio of ${\gamma}^{\prime}-Fe_4$(C, N) decreased, but the ratio of ${\varepsilon}-Fe_{2-3}$(N, C) increased. The thickness of compound layer consistently increased as gas concentration increased regardless of $N_2$ and $CH_4$ expect when the concentration of $CH_4$ was 3.5 volume%, it decreased insignificantly. When oxidizing for 15min in the temperature range of $460{\sim}570{^\circ}C$, the study found small amount of $Fe_3O_4$ at the temperature of $460{^\circ}C$ and also found that amounts of $Fe_2O_3$. and $Fe_3O_4$ on the surface and amount of ${\gamma}^{\prime}-Fe_4$(C, N) in the compound layer increased as the increased over $460^{\circ}C$, but the thickness of the compound layer decreased. Corrosion resistance was influenced by oxidation times and temperature.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2017.05a
• /
• pp.234-235
• /
• 2017

The bonding of the asphalt-based waterproof sheet is carried out in such a manner that the sheet and the sheet are adhered together and the lower adhesive layer of one sheet is adhered to the upper film layer of the other sheet, and the asphalt layer and the PE or HDPE film layer are bonded. When the joints are formed in the form of junctions between heterogeneous materials and exposed to the concrete joint movements and other deteriorating factors, the integrity of the joints can deteriorate and problems such as lifting and peeling off of the joints can occur. Therefore, this study was carried out to prevent unstable joint adhesion of the asphalt compound and film layer and to prevent defects in the adhesion between self - adhesive waterproof sheets. The self-adhesive waterproof sheet of this study can maximize bond stability by inducing bond between asphalt compounds during sheet-to-sheet bonding, thereby improving bonding strength.

• Journal of the Korean institute of surface engineering
• /
• v.29 no.5
• /
• pp.443-448
• /
• 1996

In order to plasma-sulfnitride by combining ion-nitriding of a steel and sputtering of MoS$_2$, chromium-molybdenum steel was plasma-sulfritrided using hollow cathode discharge with parallel electrodes which are a main of the steel and a subsidiary cathode of $MoS_2$. The treatment was carried out at 823K for 10.8ks under 665Pa in a 30% $N_2$-70% $H_2$ gas atmosphere. Plasma-sulfnitriding layers formed of the steel were characterized with EDX, XRD, micrographic structure observation and hardness measurement. A compound layer of 8-15$\mu\textrm{m}$ and nitrogen diffusion layer of about 400$\mu\textrm{m}$ were formed on the surface of plasma-sulfnitrided steel. The compound layer consisted of FeS containing Mo and iron nitrides. The nitrides of $\varepsilon$-$Fe_2_3N$ and $\gamma$'-$Fe_4N$ formed under the FeS. The thickness of compound layer and surface hardness were different with the gaps between main and subsidiary cathodes even in the same sulfnitriding temperature. The surface hardnesses after plasma-sulfnitriding were distributed from 640 to 830Hv. The surface hardness was higher in the plasma-sulfnitriding than the usual sulfnitriding in molten salt. This may be due to Mo in sulfnitriding layer.

• Journal of the Korean Society for Heat Treatment
• /
• v.14 no.2
• /
• pp.81-88
• /
• 2001

The effects of post-oxidation and sulfnitriding treatments on the phase transformation in the nitrided case of tool steels have been studied. Dense and compact $Fe_3O_4$ layer was formed at the outer surface of nitride compound layer by post-oxidation treatment and multi layer of iron sulfide(FeS) was formed in the compound layer by sulfnitriding treatment. The surface hardness decreased because of formation of the soft oxide or sulfide at the nitride surface. Diffusion layer of nitride case was not affected by post-oxidation treatment or sulfnitriding treatment of nitrided alloy tool steels.

• Applied Microscopy
• /
• v.24 no.4
• /
• pp.98-106
• /
• 1994

The corneal formation of compound eye of Pieris rapae L., which was mostly made during pupal stage, was morphologically investigated with light microscope, scanning electron microscope and transmission electron microscope. The regeneration of the microvilli were found on the surface membranes of corneagen cells and retinular pigment cells of preommatidium after apolysis pupal cuticle. The microvilli were finally differentiated to corneal nipples of the ommatidium. The corneal cuticle was generated on the superficial layer of the preommatidium from corneagen cells and retinular pigment cells. The corneal process was also formed under the cuticular layer from the corneagen cells. The pore canal was appeared within the cuticular layer and connected with the retinular pigment cell as if the root of interommatidial hair was connected. The interommatidial hair was projected randomly among the ommatidial facets and cornal nipple was arrayed regular on the ommatidial facets. The cornea was convex lens and the refracting power by its convex shape was 4 diopter.

• Journal of the Korean Society for Heat Treatment
• /
• v.11 no.4
• /
• pp.258-267
• /
• 1998

For the purpose of investigating the growth characteristics and composition of nitrides, gas nitridings of the austenitic stainless steel, STR 36 heat resisting steel and martensitic stainless steel are investigated at the temperature ranges between $500^{\circ}C$ and $675^{\circ}C$ for 5hours under the $75%NH_3+5%CO_2+20%$Air gas atmosphere. When gas nitriding the austentic stainless steel and STR 36 heat resisting alloy, the abnormal growth behavior of compound layer deviating from the conventional diffusion law with increasing temperature appears, while the compound layer of martensitic stainless steel shows the normal diffusional growth behavior. From the examination of microstructure, X-ray diffraction and hardness test, it is concluded that the abnormal growth behavior of compound layer with increasing temperature induces from the formation and dissolution of CrN and ${\gamma}^{\prime}-Fe_4N$ at the nitriding temperature ranges of $600{\sim}650^{\circ}C$.

• Journal of the Korean Society for Heat Treatment
• /
• v.2 no.4
• /
• pp.27-39
• /
• 1989

The effect of gas mixing ratios during gas nitrocarburizing treatment on the formation of compound layer and the mechanical properties has been studied for hot work tool steel by using a combined heat treating technique. The thickness of compound and diffusion layers has been shown to grow as a parabolic relation with increasing the amount of ammonia at a given flow quantity of $CO_2$ gas. The compound layer consists mainly of ${\varepsilon}-Fe_3$(C, N) with small amounts of ${\gamma}^{\prime}-Fe_4N$ and ${\alpha}$-Fe. The combined heat treated hot work tool steel has shown that the thickness of compound layer increases with increasing nitrocarburizing time, but the rate of growth slows down as gas nitrocarburizing time goes more than two hours. Tensile properties have given a remarkable improvement. In particular, the wear resistance of combined heat treated hot work tool steel has exhibited an improvement of about 165% greater than that obtained from conventional quenching and multi-tempering treatments.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.17 no.4
• /
• pp.432-438
• /
• 2004

In this study, we investigated the WVTRs Properties of inorganic thin composite films(ITCFs) to be newly adopted as the passivation layer of the OLED to replace the inorganic compound material Because we thought that inorganic compound materials were limited to enhance the barrier property of thin film. So, ITCFs were fabricated by mixing the cooperated material with the base material. And then, ITCFs were deposited onto the plastic substrate using the electron beam evaporation system and the water vapor transmission rates(WVTRs) were measured using the Mocon equipment. As a result of the WVTR measurement, we could analyze the WVTR values for various ITCFs. ITCFs had a remarkably lower value than the inorganic compound film. Through the analysis of thin film, we can understand the crystal structure and mixed amount. Therefore, ITCFs can be used as the inorganic passivation layers of OLED with the inorganic compound film.

• Analytical Science and Technology
• /
• v.15 no.3
• /
• pp.317-320
• /
• 2002

The layer structure of the title compound, $[Ni(en)_2(H_2O)_2](CH_3C_6H_4SO_3)_2(H_2O)$ (en = ethylenediamine), consists of discrete cations, anions, and solvate water molecules linked by a hydrogen bonding network. The central Ni atom of the cation layer has a slightly distorted octahedral coordination geometry with the ethylenediamine ligands functioning as a N,N'-bidentate and the water ligands bonding through oxygen in a trans arrangement. The p-toluenesulfonate of the anion layer has an alternate sulfonate group directed toward opposite side of the cation layer. This layer structure is stabilized by a hydrogen bond involving the O atoms of the sulfonate, the water ligand, solvate water molecule, and the N atoms of the ethylenediamine.

• Journal of the Korean institute of surface engineering
• /
• v.31 no.5
• /
• pp.266-277
• /
• 1998

The effects of $H_2S$ gas ratio, temperature and time on the case depth, hardness, and sulfide and nitride formation on the surface of sulfnitrided SCM440 steel have been studied by micro-pulse plasma technique. The thickness of compound layer of sulfide and nitride increased with the increase of time, temperautre and $H_2S$ gas ratio. But surface hardness decreased with the increase of soft sulfide layer because the hard nitride layer formed beneath the sulfide. The thickness of sulfide layer was about 10$\mu\textrm{m}$ abpve 0.0088% of $H_2S$ gas. The highest surface hardness of the compound layer was Hv835 at $530^{\circ}C$, 1hr and 0.06% of $H_2S$ gas. X-ray diffraction indicated that the surface products were $Fe_{1_x}S$, $Fe_{2.5}N$ and $Fe_4N$. It was confirmed by EPMA that sulfide only existed in the surface.