• 제목/요약/키워드: Compositional Structure

검색결과 129건 처리시간 0.032초

Pervaporation Process for Water/Ethanol Mixture through IPN Membranes

  • Jeon, Eun-Jin;Kim, Sung-Chul
    • 한국막학회:학술대회논문집
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    • 한국막학회 1993년도 춘계 총회 및 학술발표회
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    • pp.52-53
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    • 1993
  • The pervaporation behavior of EtOH/Water mixture through IPN membranes was predicted in this study. The pervaporation characteristics of single polymer membrane were modeled according to the "six-coefficients model" proposed by Brun. In the case of the IPN membrane, two models were proposed according to the phase structure of the IPN. For a uniphase membrane with no phase separation, the compositional average of the single polymer membrane was used. in the case of the phase separated IPN's two cases existed. The first was the island and sea model: in which one phase was continuous and the other was dispersed. The second was the co-continuous model where two continuous phases existed. For these cases, the permeation rate and the separation factor of the IPN membrane were calculated using the experimental sorption data and the cornponent polymer properties. Comparison with the experimental data indicated that these models could be used to predict the performances of IPN membranes depending on the morphology of the IPN.

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Structural Control Aiming for High-performance SiC Polycrystalline Fiber

  • Ishikawa, Toshihiro;Oda, Hiroshi
    • 한국세라믹학회지
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    • 제53권6호
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    • pp.615-621
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    • 2016
  • SiC-polycrystalline fiber (Tyranno SA, Ube Industries, Ltd.) shows very high heat-resistance and excellent mechanical properties up to very high temperatures. However, further increase in the strength is required. Up to now, we have already clarified the relationship between the strength and the defect-size of the SiC-polycrystalline fiber. The defects are formed during the conversion process from the raw material (amorphous Si-Al-C-O fiber) into SiC-polycrystalline fiber. In this conversion process, a degradation of the Si-Al-C-O fiber and a subsequent sintering of the degraded fiber proceed as well, accompanied by a release of CO gas and compositional changes, to obtain the dense SiC-polycrystalline fiber. Since these changes proceed in each filament, the strict control should be needed to minimize residual defects on the surface and in the inside of each filament for achieving the higher strength. In this paper, the controlling factors of the fiber strength and the fine structure will appear.

New oxide crystals as substrates for GaN-based blue light emitting devices

  • T. Fukuda;K. Shimamura;H. Tabata;H.Takeda;N. Futagawa;A. Yoshikawa;Vladimir V. Kochurikhin
    • 한국결정성장학회지
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    • 제9권5호
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    • pp.470-474
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    • 1999
  • We have successfully grown <111>-oriented $(La,Sr)(Al,Ta)O_{3}\;(LSAT)$ mixed-perovskite single crystals and <0001>-oriented ${Ca_{8}La_{2}(PO_{4})}_{6}O_2$ (CLPA) single crystals with the apatite structure by the Czochralski method. The compositional and lattice parameter uniformity of the crystals are discussed in relation to the growth conditions. Since LSAT and CLPA single crystals have excellent lattice matching with GaN, they are promising as new substrates for the growth of high quality GaN epitaxial layers.

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CLN-PZT 세라믹스(55/45(Zr/Ti) 영역)의 유전적, 전기 광학적 특성 연구 (A study on the dielectric, electrooptic properties of CLN-PZT ceramics (55/45/ (Zr/Ti) region))

  • 류제춘;홍재일;유주현;정익채;박창엽
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1988년도 추계학술대회 논문집
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    • pp.86-90
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    • 1988
  • In this paper, the compositional and sintering time dependences of dielectric, electrooptic properties for X/55/45([Ca$.$La$.$Nb]/Zr/Ti)CLN-PZT ceramics, where X is ranged from 3.0 to 11.0 mol %, have been investigated. As CLN mol% is increased, density, curie-temperature and dielectric constant are decreased, and also grain size and transmittance are increased, With the increment of CLN mol %. longitudinal mode electromechanical coupling coefficient is decreased and P-E hysterisis loop became slim-loop slowly. The crystal structure of CLN-PZt ceramics is changed from rhombohedral to tetragonal and pseudo-cubic according to the increment of CLN mol%.

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Bioglass내의 수식체가 유리의 물성 및 아파타이트 형성에 미치는 영향 (Effect of Modifiers in Bioglass on the Glass Properties and the Formation of Apatite)

  • 길철영;이호필
    • 한국세라믹학회지
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    • 제29권8호
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    • pp.623-629
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    • 1992
  • The possible use of bioglass as implant materials is due to its biocompatibility to human body. Even if many animal studies for the bioglasses have been performed, their compositional dependences of structures and physical properties are not fully understood. In the present work, physical property measurements such as density and thermal expansion coefficient were carried out for the bioglasses, with substitution of CaO for Na2O in bioglass composition (46.1%SiO2, 24.4%Na2O, 26.9%CaO, 2.6%P2O5:mol%). Hydroxyapatite formation on the glass surface was also examined after reacted in Tris-buffer solution. As CaO was substituted for Na2O, the bond strength between nonbridging oxygen and modifier became stronger to make glass structure rigid, and resulted in increase in density and decrease in thermal expansion coefficient. When the bioglasses were reacted in Tris-buffer solution, hydroxyapatite was formed on the bioglass surface for all prepared glasses in 2 hours, independently on CaO content, and the thickness of hydroxyapatite layer was decreased a little, while the thickness of SiO2 rich layer was decreased sharply with CaO content.

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Phase Identification of Nano-Phase Materials using Convergent Beam Electron Diffraction (CBED) Technique

  • Kim, Gyeung-Ho;Ahn, Jae-Pyoung
    • Applied Microscopy
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    • 제36권spc1호
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    • pp.47-56
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    • 2006
  • Improvements are made to existing primitive cell volume measurement method to provide a real-time analysis capability for the phase analysis of nanocrystalline materials. Simplification is introduced in the primitive cell volume calculation leading to fast and reliable method for nano-phase identification and is applied to the phase analysis of Mo-Si-N nanocoating layer. In addition, comparison is made between real-time and film measurements for their accuracy of calculated primitive cell volume values and factors governing the accuracy of the method are determined. About 5% accuracy in primitive cell determination is obtained from camera length calibration and this technique is used to investigate the cell volume variation in WC-TiC core-shell microstructure. In addition to chemical compositional variation in core-shell type structure, primitive cell volume variation reveals additional information on lattice coherency strain across the interface.

죠르죠 그라씨 건축형태 구성원리에 관한 연구 (A Study on the architectural composition of Giorgio Grassi)

  • 곽기표
    • 한국실내디자인학회논문집
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    • 제32호
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    • pp.13-20
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    • 2002
  • This study is purposed to find fundamental characteristics in Grassi's architecture which has architectural principles in architecture itself and in the general frame of the historical facts of architecture. His architectural theories can be explained for rationality, historicity, universality. The method of architectural composition can be divided into urban morphological characteristic and compositional characteristic of architecture. The characteristics of the former are the reconstruction of the urban structure by the readjustment of an urban axis which is based on historical continuity of the city, the open court which is a passage transformed from colonnade that is the historical vernacular type and the respect for the city-line which goes with historical context. The characteristics of the latter are the use transformed of nine square which gives consideration to centrality and typology at the same time and the hierarchic division of the principal space and the subordinate space for the functional typical purpose. This analysis shows that Grassi's architecture is on the base of historical continuity and urban reality and for him architectural work is mental work which conflict with the real world for the reconstruction of the city.

Organic Solvent Absorption Characteristics of Split-type Microfiber Fabrics

  • Lee Kwang Ju;Kim Seong Hun;Oh Kyung Wha
    • Fibers and Polymers
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    • 제5권4호
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    • pp.280-288
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    • 2004
  • Split-type nylon/polyester microfiber and polyester microfiber fabrics possess drapeability, softness, bulkiness, and smoothness, so that they can be applied in various industrial fields. In particular, these fabrics are able to absorb various organic solvents, and can be used as clean room materials. To investigate the chemical affinity between solvents and the compositional materials of these fabrics, the contact angle of thermally pressed film fabrics was measured with different solvents. The thermally pressed nylon/polyester fabric films showed a chemical attraction to formamide. The sorption properties of the microfiber fabrics were investigated using a real time testing device, and these tests showed that the sorption behavior was more influenced by the structure of the fibrous assembly than by any chemical attraction. The effect of the fabric density, specific weight, and sample structure on the sorption capacity and rate was examined for various organic solvents. The sorption capacity was influenced by the density and the specific weight of the fibrous assembly, and knitted fabric showed a higher sorption capacity than woven fabric. However, the sorption rate was less affected in lower viscosity solvents. On applying Poiseuille's Law, the lower viscosity solvents showed higher initial sorption rates, and more easily penetrated into the fibrous assembly.

인스타그램에 나타난 멀티 페르소나 패션이미지에 관한 연구 - "부캐" 사례를 중심으로 - (A study on multi-persona fashion images in Instagram - Focusing on the case of "secondary-characters" -)

  • 김종선
    • 복식문화연구
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    • 제29권4호
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    • pp.603-615
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    • 2021
  • The aim of this study was to analyze the semantic network structure of keywords and the visual composition of images extracted from Instagram in relation to the multi-persona phenomenon with in fashion imagery, which has recently been attracting attention. To this end, the concept of a 'secondary character', which forms a separate identity from a 'main character' on various social media platforms as well as on the airwaves, was considered as the spread of multi-persona and #SecondaryCharacter on Instagram was investigated. 3,801 keywords were collected after crawling the data using Python and morphological analysis was undertaken using KoNLP. The semantic network structure was then examined by conducting a CONCOR analysis using UCINET and Netdraw to determine the top 50 keywords. The results were then classified into a total of 6 clusters. In accordance with the meaning and context of the keywords included in each cluster, group names were assigned : virtual characters, relationship with the main character, hobbies, daily record, N-job person, media and marketing. Image analysis considered the technical, compositional, and social styles of the media based on Gillian Rose's visual analysis method. The results determined that Instagram uses fashion images that virtualize one's face to produce multi-persona representation s that show various occupations, describe different types of hobbies, and depict situations pertaining to various social roles.

나노 구조를 가지는 다공성 주석 산화물의 전기화학적 특성 (Electrochemical Characterization of Anodic Tin Oxides with Nano-Porous Structure)

  • 이재욱;박수진;신헌철
    • 한국재료학회지
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    • 제21권1호
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    • pp.21-27
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    • 2011
  • A nano-porous structure of tin oxide was prepared using an anodic oxidation process and the sample's electrochemical properties were evaluated for application as an anode in a rechargeable lithium battery. Microscopic images of the as-anodized sample indicated that it has a nano-porous structure with an average pore size of several tens of nanometers and a pore wall size of about 10 nanometers; the structural/compositional analyses proved that it is amorphous stannous oxide (SnO). The powder form of the as-anodized specimen was satisfactorily lithiated and delithiated as the anode in a lithium battery. Furthermore, it showed high initial reversible capacity and superior rate performance when compared to previous fabrication attempts. Its excellent electrode performance is probably due to the effective alleviation of strain arising from a cycling-induced large volume change and the short diffusion length of lithium through the nano-structured sample. To further enhance the rate performance, the attempt was made to create porous tin oxide film on copper substrate by anodizing the electrodeposited tin. Nevertheless, the full anodization of tin film on a copper substrate led to the mechanical disintegration of the anodic tin oxide, due most likely to the vigorous gas evolution and the surface oxidation of copper substrate. The adhesion of anodic tin oxide to the substrate, together with the initial reversibility and cycling stability, needs to be further improved for its application to high-power electrode materials in lithium batteries.