• 제목/요약/키워드: Compositional Effect

검색결과 142건 처리시간 0.026초

스트립캐스팅한 구상흑연주철 박판의 흑연화 과정에 대한 phase-field 모델링 (I);고용도가 없는 상의 모델링 (Phase Field Modeling of Graphitization in Ductile Cast Iron by Strip Casting(I);Modeling of Phases with Negligible Solubility)

  • 김성균;나형용
    • 한국주조공학회지
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    • 제20권2호
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    • pp.129-140
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    • 2000
  • This study aims at the phase-field modeling of the phase transformation in graphitization of the cast iron. As the first step, we constructed a phase-field model including the phases with negligible solubility. Under the dilute regular solution approximation, a simplified version of the phase-field model was obtained, which can be used for the phase transformation related with the stoichiometric phases. The results from the numerical calculation of the phase-field model was in good agreement with the exact analytic solution. The compositional shift due to Gibbs-Thomson effect can be reproduced within 0.5% error in the numerical calculation. The interface velocity, whereas, in numerical calculation of phase-field model appeared to be 15% larger than that from the analytic solution. This error is due to the shift of the interface position in phase-field model from the position with ${\phi}=0.5$.

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새로운 Fuzzy Logic을 이용한 선박조타계의 제어 (Design of Ship's Steering System by Introducting the Improved Fuzzy Logic)

  • 이철영;채양범
    • 한국항해학회지
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    • 제8권1호
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    • pp.15-42
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    • 1984
  • Many studies have been done in the field of fuzzy logic theory, but it's application to the ship's steering system is few until this date. This paper is to survey the effect of application of fuzzy logic control by new compositional rule of Inference to the ship's steering system. The controller is made up of a set of Linguistic Control Rules which are conditional linguistic statements connecting the inputs and output, and take the inputs derived from deviation angle and it's angular velocity. The Linguistic Control Rules are implemented on the digital computer to verify the performance of the fuzzy logic controller and simulations have been done in six cases of initial condition and disturbance type. Consequently, it was proved that the ship's steering system by introducing the F.L.C. is performed efficiently and less energy loss system compared with the conventional autopilot.

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THE MICROWAVE ABSORBING CHARACTERISTICS OF FERRITE GRID ABSORBER

  • Kwon, H.J.;Shon, H.J.;Hur, W.D.;Naito, Yoshiyuki;Takahashi, Michiharu
    • 한국자기학회지
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    • 제5권5호
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    • pp.805-809
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    • 1995
  • In order to widen the band-width of ferrite absorber, compositional effect on the complex permeability of Ni-Zn ferrite and the structure of grid absorber were studied. From the experimental results, we could determine the optimum composition composition of Ni-Zn ferrite and the structure of grid absorber. Also, we manufactured grid absorber and investigated its microwave absorbing characteristics. Calculation shows that the ferrite frid absorber suppresses reflection ${\leq}-20dB$ from 30 MHz to 700 MHz and the conventional ferrite tile absorber suppresses reflection ${\leq}20dB$ in the frequency range of 30 MHz-400 MHz. It was found that the microwave absorbing performance of the ferrite grid absorber was superior to the ferrite tile absorber.

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Preparation and properties of multiferroic bismuth iron oxides

  • Nam, Joong-Hee;Joo, Yong-Hui;Cho, Jeong-Ho;Chun, Myoung-Pyo;Kim, Byung-Ik
    • 한국결정성장학회지
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    • 제19권2호
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    • pp.66-69
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    • 2009
  • The compositional dependence of bismuth iron oxides and effect of La-substitutions in the structure of $BiFeO_3$ compounds were investigated, which compounds were synthesized by conventional ceramic processing. It is shown that some of bismuth iron oxides including $BiFeO_3$ show the narrow single phase region. The effect of La-doping in $BiFeO_3$ was presented as disappearance of many impurity phases of Bi-Fe-O compounds. The lower electrical resistivity was obtained as those compositions of Fe deficient region and La-doped $BiFeO_3$. The saturation magnetization of La-doped $BiFeO_3$ was increased with La content. The dielectric dispersion was also observed for those Bi-Fe-O compounds with Fe deficient and La-doped $BiFeO_3$ at low frequencies under 1 kHz.

Nd-Ba-Cu-O 벌크 초전도체의 초전도 특성에 미치는 Ca 첨가계의 영향 (Effect of Ca-doping on the superconducting properties of Nd-Ba-Cu-O bulks)

  • 이훈배;위성훈;유상임
    • 한국초전도ㆍ저온공학회논문지
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    • 제4권1호
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    • pp.21-25
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    • 2002
  • The effect of Ca-doping on the superconducting properties of Nd-Ba-Cu-O bulk superconductors, fabricated by the oxygen-controlled melt growth process, has been systematically investigated. Various c-axis textured bulk samples were grown using precursors with the nominal compositions of $Nd_{1.8-x}Ca_{x]Ba_{2.4}Cu_{3.4}O_{y}$ (x= 0.00, 0.02, 0.05, 0.10, 0.15) in a reduced oxygen atmosphere of 1%O$_2$ in Ar. Magnetization measurements revealed that the critical temperatures(Tc) were almost linearly depressed from 95K to 86K with increasing the Ca dopant from x : 0.0 to 0.15, respectively, and thus critical current densities(Jc) at 77K and for H//c-axis of specimens were gradually degraded with increasing x. Compositional analyses revealed that although the amounts of the Ca dopant both in $NdBa_2Cu_2O_y(Nd123) and Nd_4Ba_2Cu_2O_{10}(Nd422)$,/TEX> were increased with increasing x, only less than half of the initial Ca compositions were detected in melt-grown Ca-doped Nd-Ba-Cu-O bulk crystals. The supression of Tc is attributed to an increased Nd substitution for the Ba site in the Nd123 superconducting matrix with increasing the amount of the Ca dopant.

적층가공된 티타늄 합금의 전기화학적 특성에 미치는 불산의 영향 (Effect of Hydrofluoric Acid on the Electrochemical Properties of Additive Manufactured Ti and Its Alloy)

  • 김기태;조현우;장현영;김영식
    • Corrosion Science and Technology
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    • 제17권4호
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    • pp.166-175
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    • 2018
  • In this study, the electrochemical properties of CP-Ti (commercially pure titanium) and Ti-64 (Ti-6Al-4V) were evaluated and the effect of hydrofluoric acid on corrosion resistance and electrochemical properties was elucidated. Additive manufactured materials were made by DMT (Directed Metal Tooling) method. Samples were heat-treated for 1 hour at $760^{\circ}C$ and then air cooled. Surface morphologies were studied by optical microscope and SEM. Electrochemical properties were evaluated by anodic polarization method and AC-impedance measurement. The oxide film formed on the surface was analyzed using an XPS. The addition of HF led to an increase in the passive current density and critical current density and decreased the polarization resistance regardless of the alloys employed. Based on the composition of the oxide film, the compositional difference observed by the addition of HF was little, regardless of the nature of alloys. The Warburg impedance obtained by AC-impedance measurement indicates the dissolution of the constituents of CP-Ti and Ti-64 through a porous oxide film.

The Composition of the Rare Earth Based Conversion Coating Formed on AZ91D Magnesium Alloy

  • Chang, Menglei;Wu, Jianfeng;Chen, Dongchu;Ye, Shulin
    • Corrosion Science and Technology
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    • 제17권1호
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    • pp.1-5
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    • 2018
  • As structural materials, magnesium (Mg) alloys have been widely used in the fields of aviation, automobiles, optical instruments, and electronic products. There are few studies on the effect of coating conditions on the compositional variation during the formation process of the conversion coatings. Rare-earth based conversion coating on AZ91 magnesium alloy was prepared in ceric sulfate and hydrogen peroxide contained solution. The element composition and valence as well as their distribution in the coating were analyzed with energy dispersive X-ray spectroscopy (EDS), Electron probe micro-analyzer (EPMA), X-ray photoelectron spectroscopy (XPS). The effect of treating process on the element composition were also studied. It was found that the conversion coating surface consists of Mg, Al, O, Ce, and the weight content of Ce in the coating was affected by the treating solution concentration and immersion time; the Ce element was distributed in the coating non-uniformly and existed in the form of $Ce^{+3}$ and $Ce^{+4}$, while the O element existed in the form of $OH^-$, $O^{2-}$, $H_2O$. Based on microscopic analysis results, the electrochemical deposition mechanism on the micro-anode and micro-cathode in the process of the coating growth was suggested.

Effect of Sulfurization on CIGS Thin Films by RF Magnetron Sputtering Using a Cu(In1-xGax)Se2 Single Target

  • Jung, Sung Hee;Chung, Chee Won
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.675-675
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    • 2013
  • CIGS thin films have received a great attention as a promising material for solar cells due to their high absorption coefficient, appropriate bandgap, long-term stability, and low cost production. CIGS thin films have been deposited by various methods such as co-evaporation, sputtering, spray pyrolysis and electro-deposition. In this study, Cu(In,Ga)Se2(CIGS) thin films were prepared using a single quaternary target by rf magnetron sputtering. The effect of sulfurization on the structural, compositional and electrical properties of the films was examined in order to develop the deposition process. An optimal sulfurization process will be selected for the preparation of CIGS thin films with good structural, optical and electrical properties by applying various sulfurization processes. In addition, the electrical properties of CIGS thin films were investigated by post-deposition annealing process. The carrier concentration of CIG(SSe) thin films after sulfurization was increased from $10^{14}cm^{-3}$ to $10^{16}cm^{-3}$ and the resistivity was increased from 10 ${\Omega}cm$ to $10^3$ ${\Omega}cm$. It is confirmed that CIG(SSe) thin films prepared at optimal deposition condition have similar atomic ratio to the target value after sulfurization.

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Carbon and Cobalt Diffusion in Liquid Phase Sintering of WC-Co with Gradient Composition

  • Park, Dong-Kyu;Kim, Ki-Won;Jung, Woo-Hyun
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.635-636
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    • 2006
  • In this study, the diffusion behaviors of C and Co in liquid phase sintering of WC-Co system were investigated whether these two components diffused in the same direction in case of having opposite gradient each other with not being $\eta$ phase. The green compacts with controlled compositions in not being of $\eta$ phase and gradient composition which one is WC-5Co-1.2%C, the other is WC-XCo-0.2%C (where X = 5, 10, 15, 20, 25) were sintered at $1350^{\circ}C$ and $1400^{\circ}C$ and then the diffusion behaviors of C and Co were investigated by analyses of compositional change, also determined for microstructure and microhardness. Also, same testing was carried out on the specimens with dual layers sintered in upright and reverse positions to evaluate the effect of gravity on the diffusion in liquid Co. From the results of this study, we can find the fact that the direction of diffusion for C and Co in WC-Co system during liquid phase sintering was different and the effect of gravity for the liquid was insignificant. Also other physical properties were changed on the diffusion of elements.

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