• Title/Summary/Keyword: Composition wave

Search Result 216, Processing Time 0.02 seconds

Tungsten-Titanium Powder Compaction by Impulsive Loading (I) (W-Ti 분말 압축 (I))

  • Dal Sun Kim;S.Nemat-Nasser
    • Explosives and Blasting
    • /
    • v.19 no.1
    • /
    • pp.101-110
    • /
    • 2001
  • Depleted uranium (DU) outperforms tungsten heavy alloys (WHA) by about 10%. Because of environmental and hence, political concerns, there is a need to improve WHA performance, in order to replace the DU penetrators. A technique of metal powder compaction by the detonation of an explosive has been applied to tungsten-titanium(W-Ti) powder materials that otherwise may be difficult to fabricate conventionally or have dissimilar, nonequilibrium, or unique me1astab1e substructures. However, the engineering properties of compacted materials are not widely reported and are little known especially for the "unique" composition of W-Ti alloy. To develop high-performance tungsten composites with superior ballistic attributes, it is necessary to understand, carefully document controlled experimental results, and develop basic computational models for potential composites with controlled microstructures. A detailed understanding and engineering application of W-Ti alloy can lead to the development of new structural design for engineering components and materials.

  • PDF

Enhancement of Pulsed-Laser Ablation by Phase Explosion of Liquid (액체의 상폭발 과정에 의한 펄스 레이저 용발률의 증진)

  • Kim, Dong-Sik;Lee, Ho
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.25 no.11
    • /
    • pp.1483-1491
    • /
    • 2001
  • Enhancement of pulsed-laser ablation by an artificially deposited liquid film is presented. Measurements of ablation rate, ablation threshold, and surface topography arc performed. Correlation between material ablation and photoacoustic effect is examined by the optical beam deflection method. The dependence of ablation rate on liquid-film thickness and chemical composition is also examined. The results indicate that photomechanical effect in the phase explosion of liquid is responsible for the enhanced ablation. The low critical temperature of liquid induces explosive vaporization with localized photoacoustic excitation in the superheat limit and increases the ablation efficiency. Experiments were carried out utilizing a Q-swiched Nd:YAG laser at near-threshold laser fluences with negligible plasma effect (up to ∼100 MW/cm$^2$).

α -Cyclodextrin Modified Screen Printed Graphite Electrodes for Detection of Phenols

  • Kim, Hwa-jeong;Jang, Seung-Cheol;Shim, Yoon-Bo
    • Bulletin of the Korean Chemical Society
    • /
    • v.23 no.3
    • /
    • pp.427-431
    • /
    • 2002
  • A screen printed graphite electrode has been developed for a simple and sensitive determination of phenolic compounds in an aqueous solution. The electrode developed uses a simple and effective screen printing technique with ${\alpha}-Cyclodextrin({\alpha}-CD)$ modified graphite ink. Phenols were captured on the surface of the ${\alpha}-CD$ modified electrode through complex formation. The phenol/ ${\alpha}-CD$ complex was deposited and quantified electrochemically using cyclic voltammetry (CV), differential pulse voltammetry (DPV) and square wave voltammetry (SWV). The optimization of the experimental parameters was performed in regard to electrode composition, pH, temperature, sample preconcentration time. Interferences from other organic compounds were investigated. The detection limit for phenols was 500 ${\pm}7$ nM for DPV, with the linear range of 0.5 ${\mu}M$ -25.0 ${\mu}M$ and 30 ${\pm}2$ nM for SWV, with the linear range of 30 nM - $50{\mu}M$, respectively.

The Evaluation of Tracking and Erosion Resistance of Silicone Rubber for Outdoor Use by the Inclined-Plane Method (경사평면법에 의한 옥외용 실리콘고우의 내트래킹성 및 내침식성 평가)

  • Kim, J.H.;Song, W.C.;Park, Y.G.;Kim, H.G.;Kim, I.S.;Han, S.W.;Cho, H.G.
    • Proceedings of the KIEE Conference
    • /
    • 1997.07d
    • /
    • pp.1500-1502
    • /
    • 1997
  • We investigated the tracking and erosion resistance of the silicone rubber by Inclined-Plane Method. And, with the variation of the accelerated conditions such as the applied voltage and composition of contaminant, the change of the tracking characteristics according to such conditions was evaluated. The leakage current significantly increases with the increasing voltage, but the weight loss remains almost the same. The voltage above 5.0 kV isn't recommended because tracking breakdown occurs as fast as it does without erosion, and the typical discharge waveform was the form of rectifying wave.

  • PDF

Temperature Dependence of Magnetization of Amorphous TM_70 Cr_5 Si_10 B_15 (TM=Fe, Co, Ni) Alloys

  • Kim, Kyeong-Sup;Yu, Seong-Cho;Lim, Woo-Young;Myuong, Wha-Nam
    • Journal of Magnetics
    • /
    • v.2 no.4
    • /
    • pp.135-137
    • /
    • 1997
  • We report the salient features of the magnetic properties of amorphous TM70Cr5Si10B15(TM=Fe, Co, Ni) alloys. The temperature dependence of magnetization for amorphous ribbons were measured by a SQUID and a VSM from 5 K to 700 K under an external field of 10 kOe. Except TM70Cr5Si10B15 that shows a paramagnetic behaviour, both Fe and Co based amorphous alloys show a typical ferromagnetic thermo-magnetization curves. For these two ferromagnetic alloys, the saturation magnetization in the temperature range from 5 K to about 0.4 Tc can be descrived by the Bloch relation, Ms (T)=Ms(0) [1-BT3/2-CT5/2]. The spin wave stiffness constants and the range of exchange interaction were analyzed from the magnetization behaviour. The variation of the magnetic properties are discussed and compared with the composition of the alloys.

  • PDF

Sulfur Redox Equilibrium in Mixed Alkali Silicate Glass Melts

  • Kim, Ki-Dong;Hwang, Jong-Hee
    • Journal of the Korean Ceramic Society
    • /
    • v.48 no.3
    • /
    • pp.205-210
    • /
    • 2011
  • The dependence of sulfur redox behavior and its diffusivity on temperature and composition was studied in mixed alkali silicate melts by means of square wave voltammetry (SWV) at different frequencies in a temperature range of $1000^{\circ}C$ to $1400^{\circ}C$. The voltammograms showed two reduction peaks at high frequency but only one peak at low frequency. Irrespective of $K_2O/(Na_2O+K_2O)$, each peak potential due to reduction of $S^{6+}$ to $S^{4+}$ and $S^{4+}$ to $S^0$ moved toward a negative direction with temperature decrease, and the peak current showed a strong dependence on frequency at a constant temperature. However, the compositional dependence of the peak potential showed an inconsistent behavior with an increase of $K_2O$. The mixed alkali effect was not observed in sulfur diffusion. This inconsistency of both peak potential and diffusion for compositional dependence may be derived from the strong volatilization of sulfur in melts.

Deformation Characteristics of Cut-Slope Composed of Colluvial Soil in Tae Baek Area (강원도 태백지역의 붕적층 절토사면의 변형특성)

  • 김경열;이대수;홍성연
    • Proceedings of the Korean Geotechical Society Conference
    • /
    • 2002.10a
    • /
    • pp.467-474
    • /
    • 2002
  • Colluvial sell has a very unique deformation property, particularly when it is subject to the cutting work entailed in a variety of construction. In this study, the cut slope tying on a colluvial layer in which the transmission tower had been installed were investigated to find out the cause of deformation. In-situ tests such as boring, surface-wave analysis (MASW) were employed to look into the physical composition of underground layers and FEM including LEM were carried out to simulate the construction steps. The result shows that the stress relaxation followed by road construction induced the deformation of the slope and damage in the foundation of the transmission tower.

  • PDF

A Study on Surface Acoustic Wave Characteristics of PMS-PZT Piezoelectric Ceramics (PMS-PZT 세라믹스의 탄성표면과 특성에 관한 연구)

  • 김준한;양원봉;최형욱;윤현상;윤석진;박창엽
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1992.05a
    • /
    • pp.73-76
    • /
    • 1992
  • In this study, piezoelectric ceramics of composition 0.08Pb(Mn$\sub$1/3/Sb$\sub$2/3/)O$_3$ were manufactured by the Hot-press method and structural, piezoelectrical properties and temperature stability were investigated with addition of 0, 02, 0.4, 0.6, 0.8, 1.0 [wt%] Cr$_2$O$_3$. Also the SAW delayline was fabricated and the propagation characteristics of SAW were considered with SAW theories.

  • PDF

Electrochemical Study of Nickel(II) Complexes with Diaza-Macrocyclic Ligands in Acetonitrile

  • Moo-Lyong Seo;Zun-Ung Bae;Tae-Myoung Park
    • Bulletin of the Korean Chemical Society
    • /
    • v.12 no.4
    • /
    • pp.368-370
    • /
    • 1991
  • The electrochemical behavior and the complex formation between N$i^{2+}$ and 1,7-diazs-15-crown-5 and 1,10-diaza-18-crown-6 in acetonitrile solution have been studied by DC polarography, differential puke polarography and cyclic voltammetry. Nickel(Ⅱ) complexes gave a single well-defined wave. The formation constants of their complexes were 1$0^{4.89} and 10^{3.86}$, respectively. Nickel(Ⅱ) ion was found to form complexes of 1-to-1 composition with 1,7-diaza-15-crown-5 and 1,10-diaza-18-crown-6. In addition, reduction steps were irreversible and the reduction current were diffusion controlled. The electrochemical reduction mechanism of Ni(Ⅱ)-macrocyclic diaza-crown complexes in acetonitrile solution is estimated.

Preparation of Paraelectric PLT Thin Films Using Reactive Magnetron Sputtering of Multicomponent Metal Target

  • Kim, H.H.;Sohn, K.S.;Casas, L.M.;Pfeffer, R.L.;Lareau, R.T.
    • Electrical & Electronic Materials
    • /
    • v.11 no.10
    • /
    • pp.53-59
    • /
    • 1998
  • Paraelectric lead landthanum titanate(PLT) thin films have been prepared by a reactive dc magnetron sputtering system using a multicomponent metal target. The surface area control of each element on the target markedly facilitates the fabrication of thin films of complex ceramic compounds. A postdeposition heat-treatment was applied to all as-deposited PLT thin films at annealing temperatures up to 75$0^{\circ}C$ for crystalization. The composition of the PLT(28) thin filmannealed at $650^{\circ}C$ was: Pb, 0.73; La, 0.28; Ti, 0.88; O, 2.9. The dielectric constant and dissipation factor of the thin film(200 nm) at low filed measurements (500 Vcm-1) are 1216 and 0.018, respectively. The charge storage density using a typical Sawyer-Tower circuit with a 500 Hz sine wave was 12.5 $\mu$Ccm-2 at the electric field of 200 kVcm-1.

  • PDF