• Elastomers and Composites
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• 제37권1호
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• pp.21-30
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• 2002

개시제 ammonium persulfate(APS)와 유화제 sodium dodecyl benzene sulfonate(SDBS)를 이용하여 methyl methacrylate(MMA), styrene(St), ethyl acrylate(EA)등의 단량체를 core(내부)와 shell(외부)의 폴리머성분이 다른 core-shell 폴리머를 합성하고 각 core-shell 폴리머에 대한 구조를 연구하였다. 한 입자의 내부와 외부의 고분자 조성이 다른 composite 라텍스는 고분자 블렌딩과 공중합의 물성과는 달리 한 입자 내에서도 상반된 두 가지 물성을 동시에 나타내는 특성으로 인하여 여러 산업 분야에 응용이 가능하다. 그러나, core-shell 라텍스를 제조할 때 반응중입자가 성장하는 과정에서 입자의 응집과 중합율이 떨어지고, 라텍스의 응용시 기계적 안정성이 문제점으로 되고 있다. 따라서 shell 중합시에 새로운 입자의 생성이 적고 중합중 안정성이 우수한 라텍스를 제조하기 위해 유화제농도, 개시제농도, 중합온도가 PMMA/PSt과 PSt/PMMA의 core-shell 구조에 미치는 영향과 중합 후 입도분석기(particle size analyzer; PSA) 및 투과전자현미경(transmission electron microscope; TEM)을 이용하여 실제 입자측정과 입자형태 특성을 확인하였으며 시차주사열량계(differential scanning calorimeter, DSC)를 이용하여 유리전이온도($T_g$)의 측정, 최저성막온도(minimum film formation temperature; MFFT), NaOH 첨가에 의한 가수 분해에 따르는 pH를 측정하여 core-shell의 새로운 특성을 확인하였다.

• Steel and Composite Structures
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• 제1권3호
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• pp.341-354
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• 2001

This paper provides a state-of-the-art review on advanced analysis models for investigating the load-displacement and ultimate load behaviour of steel and composite frames subjected to static gravity and lateral loads. Various inelastic analysis models for steel and composite members are reviewed. Composite beams under positive and negative moments are analysed using a moment-curvature relationship which captures the effects of concrete cracking and steel yielding along the members length. Beam-to-column connections are modeled using rotational spring. Building core walls are modeled using thin-walled element. Finally, the nonlinear behaviour of a complete multi-storey building frame consisting of a centre core-wall and the perimeter frames for lateral-load resistance is investigated. The performance of the total building system is evaluated in term of its serviceability and ultimate limit states.

• Bulletin of the Korean Chemical Society
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• 제34권12호
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• pp.3829-3834
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• 2013

$H{\beta}$ (core)/SAPO-11 (shell) composite molecular sieve was synthesized by the hydrothermal method in order to combine the advantages of $H{\beta}$ and SAPO-11 for the methylation of naphthalene with methanol. For comparison, the mechanical mixture was prepared through the blending of $H{\beta}$ and SAPO-11. The physicochemical properties of $H{\beta}$, SAPO-11, the composite and the mechanical mixture were characterized by various characterization methods. The characterization results indicated that $H{\beta}$/SAPO-11 composite molecular sieve exhibited a core-shell structure, with the $H{\beta}$ phase as the core and the SAPO-11 phase as the shell. The pore diameter of the composite was between that of $H{\beta}$ and SAPO-11. The composite had fewer acid sites than $H{\beta}$ and mechanical mixture while more acid sites than SAPO-11. The experimental results indicated that the composite exhibited high catalytic performances for the methylation of naphthalene with methanol.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2004년도 춘계학술발표대회 논문집
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• pp.270-274
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• 2004

Aircraft composite structure with honeycomb core experiences core crush problem in manufacturing. To prevent core crush additional processes are needed such as core stabilization and prepreg material tie-down and this is the cause of increasing cost. Recent study shows that high friction prepreg prevent core crush without additional process. This paper presents the analysis of high frictional material which attracts lots of interests through physical property, mechanical property and microscopic morphology and the cause of friction.

• Advances in materials Research
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• 제1권2호
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• pp.161-168
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• 2012

Nanoflake composite multi core-shell $SrFe_{12}O_{19}/Fe_3O_4$/PEG/Polypyrrole was synthesized by in situ polymerization method. In this paper, the fabrication of $SrFe_{12}O_{19}$ nanoflake is as first core by solgel method. Then fabricated a shell layer from magnetic nanoparticles of $Fe_3O_4$, which synthesized by coprecipitation technique, onto the $SrFe_{12}O_{19}$ nanoflake. Polyethylene glycol (PEG) as a polymer layer and as second shell was coated onto the before core-shell. Than core-shell $SrFe_{12}O_{19}/Fe_3O_4$/PEG was used as template for the preparation of $SrFe_{12}O_{19}/Fe_3O_4$/PEG/Polypyrrole composite. Final composite has a conductive property among $4.23{\times}10^{-2}Scm^{-1}$ and magnetic property about $M_s$=2.99 emu/g. Also final composite in soluble at organic solvent such as DMF and DMSO and has a flake structure. Conductivity and magnetic property respectively determine by four-probe instrument and vibrant sample magnetometer (VSM), morphology and article size determined by FE-SEM, TEM and XRD.

• Steel and Composite Structures
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• 제2권5호
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• pp.355-378
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• 2002

Use of composite steel construction with precast hollow core slabs is now popular in the UK, but the present knowledge in shear capacity of the headed shear studs for this type of composite construction is very limited. Currently, all the information is based on the results obtained from experimental push-off tests. A finite element model to simulate the behaviour of headed stud shear connection in composite beam with precast hollow core slabs is described. The model is based on finite element method and takes into account the linear and non-linear behaviour of all the materials. The model has been validated against the test results, for which the accuracy of the model used is demonstrated. Parametric studies showing the effect of the change in transverse gap size, transverse reinforcement diameter and in-situ concrete strength on the shear connection capacity are presented.

• Bulletin of the Korean Chemical Society
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• 제35권11호
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• pp.3303-3306
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• 2014

A facile and effective approach has been developed to prepare hybrid hollow microspheres, via consecutive processes of pickering mini-emulsion polymerization for core-shell formation, and calcination of the sacrificial core. The resulting hollow composite particles have mono-layered shells. The morphology and size characteristics of synthesized composite particles were investigated, using dynamic light scattering (DLS) and scanning electron microscopy (SEM) measurements.

• 한국분말재료학회지
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• 제24권4호
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• pp.279-284
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• 2017

The formation mechanism and photocatalytic properties of a multiwalled carbon nanotube (MWCNT)/$TiO_2$-based nanotube (TNTs) composite are investigated. The CNT/TNT composite is synthesized via a solution chemical route. It is confirmed that this 1-D nanotube composite has a core-shell nanotubular structure, where the TNT surrounds the CNT core. The photocatalytic activity investigated based on the methylene blue degradation test is superior to that of with pure TNT. The CNTs play two important roles in enhancing the photocatalytic activity. One is to act as a template to form the core-shell structure while titanate nanosheets are converted into nanotubes. The other is to act as an electron reservoir that facilitates charge separation and electron transfer from the TNT, thus decreasing the electron-hole recombination efficiency.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2004년도 춘계학술발표대회 논문집
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• pp.111-114
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• 2004

Using the embedded optical fiber sensor of totally-reflected extrinsic Fabry-Perot interferometer(TR-EFPI), longitudinal strains(Ex) of the core and skin layers in glass fiber reinforced plastic(GFRP) cross-ply composite laminates have been measured. Transmission optical microscopy was employed to study the damage formation around the TR-EFPI sensor. It was observed that values of ex in the interior of the skin layer and the core layer measured by embedded TR-EFPI sensor was significantly higher than that of the specimen surface measured by strain gauges. The experimental results agreed well with those from finite element analysis on the basis of uniform stress model. Large strains in the core layer led to the occurrence of transverse cracks which drastically reduced the strain at failure of optical fiber sensor embedded in the core layer.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 2002년도 봄 학술발표회 논문집
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• pp.407-414
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• 2002

The knowledge of interaction of electromagnetic waves in composite structures is important for designing the shielding structure for antenna such as radome. Recently, radomes are constructed in the form of foam core sandwich structures that have many mechanical advantages such as high strength, long fatigue life, low density and adaptability to the intended function of structure. However, the propagation of electromagnetic waves is affected by high anisotropic permeability and loss tangent of the composite skin. In this study, the analytical model to understand the propagation of electromagnetic waves in the anisotropic composites and foam core sandwich structures with composite skins was proposed. Numerical analyses of unidirectional composites and foam core sandwich structure as a function of incident angle were performed. From the results of analysis, the general tendencies of transmittance of electromagnetic wave through composites and foam core sandwich structure were obtained.