• 소성∙가공
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• 제25권1호
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• pp.36-42
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• 2016

Fiber metal laminates (FMLs) are well known for improved fatigue strength, better impact resistance, superior damage tolerance and slow crack growth rate compared to traditional metallic materials. However, defects and loss of strength of a composite material can occur due to the vertical load from the punch during the joining with a dissimilar material using a conventional clinching method. In the current study, tapered-hole clinching was an alternative process used to join Al 5052 and FMLs. The tapered hole was formed in the FML before the joining. For the better understanding of static and dynamic characteristics, a clinched joining followed by a tensile-shear test was numerically simulated using the finite element analysis. The design parameters were also evaluated for the geometry of the tapered hole by the Taguchi method in order to improve and compare the lateral joining strength of the clinched joint. The influence of the neck thickness and the undercut were evaluated and the contribution of each design parameter was determined. Then, actual experiments for the joining and tensile-shear test were conducted to verify the results of the numerical simulations. In conclusion, the appropriate combination of the design parameters can improve the joining strength and the cross-sections of the tapered-hole clinched joint formed in the actual experiments were in good agreement with the results of the numerical simulations.

• Steel and Composite Structures
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• 제19권5호
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• pp.1167-1184
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• 2015

Despite considerable life casualty and financial loss resulting from past earthquakes, many existing steel buildings are still seismically vulnerable as they have no lateral resistance or at least need some sort of retrofitting. Passive control methods with decreasing seismic demand and increasing ductility reduce rate of vulnerability of structures against earthquakes. One of the most effective and practical passive control methods is to use a shear panel system working as a ductile fuse in the structure. The shear Panel System, SPS, is located vertically between apex of two chevron braces and the flange of the floor beam. Seismic energy is highly dissipated through shear yielding of shear panel web while other elements of the structure remain almost elastic. In this paper, lateral behavior and related benefits of this system with narrow-flange link beams is experimentally investigated in chevron braced simple steel frames. For this purpose, five specimens with IPE (narrow-flange I section) shear panels were examined. All of the specimens showed high ductility and dissipated almost all input energy imposed to the structure. For example, maximum SPS shear distortion of 0.128-0.156 rad, overall ductility of 5.3-7.2, response modification factor of 7.1-11.2, and finally maximum equivalent viscous damping ratio of 35.5-40.2% in the last loading cycle corresponding to an average damping ratio of 26.7-30.6% were obtained. It was also shown that the beam, columns and braces remained elastic as expected. Considering this fact, by just changing the probably damaged shear panel pieces after earthquake, the structure can still be continuously used as another benefit of this proposed retrofitting system without the need to change the floor beam.

• 한국전기전자재료학회논문지
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• 제32권6호
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• pp.501-506
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• 2019

To overcome the limitations of the conventional Ni anode-supported SOFCs, various types of ceramic anodes have been studied. However, these ceramic anodes are difficult to commercialize because of their low cell performances and difficulty in manufacturing anode-support typed SOFCs. Therefore, in this study, to use these ceramic anodes and take advantage of anode-supported SOFC, which can minimize ohmic loss from the thin electrolyte, we fabricated cathode support-typed SOFC. The cathode-support of LSCF-YSZ was prepared by the acid treatment of conventional Ni-YSZ (Yttria-stabilized Zirconia) anode-support, followed by the infiltration of LSCF to YSZ scaffold. The composite of $La(Sr)Ti(Ni)O_3$ and $Ce(Mn,Fe)O_2$ was used as the ceramic anode. The fabricated cathode-supported button cell showed a relatively low power density of $0.207Wcm^{-2}$ at $850^{\circ}C$; however, it is expected to show better performance through the optimization of the infiltration rate and thickness of LSCF-YSZ cathode-support layer.

• Advances in environmental research
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• 제5권1호
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• pp.1-18
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• 2016

Magnetic nano-based sorbents have been synthesized for the recovery of two rare earth elements (REE: Nd(III) and Yb(III)). The magnetic nano-based particles are synthesized by a one-pot hydrothermal procedure involving co-precipitation under thermal conditions of Fe(III) and Fe(II) salts in the presence of chitosan. The composite magnetic/chitosan material is crosslinked with epichlorohydrin and modified by grafting alanine and serine amine-acids. These materials are tested for the binding of Nd(III) (light REE) and Yb(III) (heavy REE) through the study of pH effect, sorption isotherms, uptake kinetics, metal desorption and sorbent recycling. Sorption isotherms are well fitted by the Langmuir equation: the maximum sorption capacities range between 9 and 18 mg REE $g^{-1}$ (at pH 5). The sorption mechanism is endothermic (positive value of ${\Delta}H^{\circ}$) and contributes to increase the randomness of the system (positive value of ${\Delta}S^{\circ}$). The fast uptake kinetics can be described by the pseudo-second order rate equation: the equilibrium is reached within 4 hours of contact. The sub-micron size of sorbent particles strongly reduces the contribution of resistance to intraparticle diffusion in the control of uptake kinetics. Metal desorption using acidified thiourea solutions allows maintaining sorption efficiency for at least four successive cycles with limited loss in sorption capacity.

• Nuclear Engineering and Technology
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• 제53권4호
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• pp.1236-1249
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• 2021

Although there are still controversial opinions and uncertainty on application of SiC_f/SiC composite cladding as next-generation cladding material for its great oxidation resistance in high temperature steam environment and other outstanding advantages, it cannot deny that SiC_f/SiC cladding is a potential accident tolerant fuel (ATF) cladding with high research priority and still in the engineering design stage for now. However, considering its disadvantages, such as low irradiated thermal conductivity, ductility that barely not exist, further evaluations of its in-pile behaviors are still necessary. Based on the self-developed code we recently updated, relevant thermohydraulic and mechanical models in FROBA-ATF were applied to simulate the cladding behaviors under normal and accident conditions in this paper. Even through steady-state performance analysis revealed that this kind of cladding material could greatly reduce the oxidation thickness, the thermal performance of UO₂-SiC was poor due to its low inpile thermal conductivity and creep rate. Besides, the risk of failure exists when reactor power decreased. With geometry optimization and dopant addition in pellets, the steady-state performance of UO₂-SiC was enhanced and the failure risk was reduced. The thermal and mechanical performance of the improved UO₂-SiC was further evaluated under Loss of coolant accident (LOCA) and Reactivity Initiated Accident (RIA) conditions. Transient results showed that the optimized ATF had better thermal performance, lower cladding hoop stress, and could provide more coping time under accident conditions.

• The Plant Pathology Journal
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• 제37권3호
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• pp.215-231
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• 2021

Brown leaf spot disease caused by Nigrospora guilinensis on Phellodendron chinense occurs in a large area in Dayi County, Chengdu City, Sichuan Province, China each year. This outbreak has severely reduced the production of Chinese medicinal plants P. chinense and caused substantial economic losses. The bacterial isolate JKB05 was isolated from the healthy leaves of P. chinense, exhibited antagonistic effects against N. guilinensis and was identified as Bacillus megaterium. The following fermentation medium and conditions improved the inhibitory effect of B. megaterium JKB05 on N. guilinensis: 2% glucose, 0.1% soybean powder, 0.1% KCl, and 0.05% MgSO₄; initial concentration 6 × 10⁶ cfu/ml, and a 42-h optimal fermentation time. A composite of 0.1% nano-SiO₂ JKB05 improved the thermal stability, acid-base stability and ultraviolet resistance by 16%, 12%, and 38.9%, respectively, and nano-SiO₂ was added to the fermentation process. The best formula for the wettable powder was 35% kaolin, 4% polyethylene glycol, 8% Tween, and 2% humic acid. The following quality test results for the wettable powder were obtained: wetting time 87.0 s, suspension rate 80.33%, frequency of microbial contamination 0.08%, pH 7.2, fineness 95.8%, drying loss 1.47%, and storage stability ≥83.5%. A pot experiment revealed that the ability of JKB05 to prevent fungal infections on P. chinense increased considerably and achieved levels of control as high as 94%. The use of nanomaterials significantly improved the ability of biocontrol bacteria to control this disease.

• Journal of Ginseng Research
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• 제48권4호
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• pp.366-372
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• 2024

Background: The biological activity and pharmacological effects of rare ginsenosides have been proven to be superior to those of the major ginsenosides, but they are rarely found in ginseng. Methods: Ginsenoside Rb1 was chemically transformed with the involvement of methanol molecules by a synthesized heterogeneous catalyst 12-HPW@MeSi, which was obtained by the immobilization of 12-phosphotungstic acid on a mesoporous silica framework. High-performance liquid chromatography coupled with mass spectrometry was used to identify the transformation products. Results: A total of 18 transformation products were obtained and identified. Methanol was found to be involved in the formation of 8 products formed by the addition of methanol molecules to the C-24 (25), C-20 (21) or C-20 (22) double bonds of the aglycone. The transformation pathways of ginsenoside Rb1 involved deglycosylation, addition, elimination, cycloaddition, and epimerization reactions. These pathways could be elucidated in terms of the stability of the generated carbenium ion. In addition, 12-HPW@MeSi was able to maintain a 60.5% conversion rate of Rb1 after 5 cycles. Conclusion: Tandem and high-resolution mass spectrometry analysis allowed rapid and accurate identification of the transformation products through the characteristic fragment ions and neutral loss. Rare ginsenosides with methoxyl groups grafted at the C-25 and C-20 positions were obtained for the first time by chemical transformation using the composite catalyst 12-HPW@MeSi, which also enabled cyclic heterogeneous transformation and facile centrifugal separation of ginsenosides. This work provides an efficient and recyclable strategy for the preparation of rare ginsenosides with the involvement of organic molecules.

• 한국습지학회지
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• 제18권2호
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• pp.132-147
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• 2016

동아시아 지역의 위성 토양수분 데이터 활용을 위해 Soil Moisture Ocean Salinity (SMOS) 위성에 탑재된 Microwave Imaging Radiometer using Aperture Synthesis (MIRAS) 센서와 Global Change Observation Mission-Water (GCOM-W1) 위성에 탑재된 Advanced Microwave Scanning Radiometer 2 (AMSR2) 센서 기반 토양수분 데이터를 자료동화 데이터인 Global Land Data Assimilation System (GLDAS)를 기준 값으로 Cumulative Distribution Function (CDF) 기법과 회귀식을 활용하여 보정하는 연구를 수행하였다. 동아시아 지역에서 발생하는 전파간섭의 영향을 고려하여 토양수분 산출에 적합하다고 판단되는 Radio Frequency Interference (RFI), Data Quality indeX (DQX) 한계값과, 합성일수를 제시하였다. 보완된 위성 토양수분 데이터를 지점 토양수분 데이터와 비교한 결과 상관계수가 평균 27%, 11% 증가하였고, Root Mean Square Deviation (RMSD, 평균제곱근 편차)는 평균 61%, 57% 감소하였다. 추가적으로, 보정된 위성데이터를 GLDAS 토양수분 데이터와 비교했을 때, 보정된 MIRAS 및 AMSR2 데이터는 한반도의 80% 및 90%의 지역에서 상관계수가 증가하였으며, 한반도 전역에서 RMSD가 감소하였다. 본 연구를 통해 향후 MIRAS 및 AMSR2 위성 데이터를 융합하여 각 위성의 토양수분 데이터를 보완 할 수 있는 가능성을 제시하였다.

• 한국주조공학회지
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• 제11권6호
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• pp.475-481
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• 1991

In this study the fabrication technology and mechanical properties of AC8A/$Al_2O_3$ Composites by squeeze casting process were investigated to develope for application as the piston materials that require good friction, wear resistance, and thermal stability. AC8A/$Al_2O_3$ composistes without a porosity and the break of preform were fabricated at the melt temperature of $740^{\circ}C$, the preform temperature of $500^{\circ}C$, and mold temperature of $400^{\circ}C$ under the applied pressure of $1200kg/cm^2$ as the results of the observation of microstructures. As the results of this study, the tensile strength of AC8A/$Al_2O_3$ composites was not increased linearly with $Al_2O_3$ volume fraction and so it seemed not to agree with the rule of mixture, which had been used often in metal matrix composite. Also the tensile strength after thermal fatigue test was little different from that before the test. Consequently it was thought that AC8A/$Al_2O_3$ composites fabricated under our experimental conditions had a good thermal stability and subsequently a good interface bonding. Wear rate(i.e., volume loss per unit sliding distance) of AC8A/$Al_2O_3$ composites was decreased with $Al_2O_3$ volume fraction and the sliding speed at both room temperature and $250^{\circ}C$ and so there was a good correlation between wear rate and hardness. Also the wear rate of AC/8A20% $Al_2O_3$ composities was obtained the value of $1.65cm^3/cm$ at sliding speed of 1.14m/sec as compared with about $3.0\;{\times}10^{-8}cm^3/cm$ hyereutectie Al-Si alloy(Al-16%Si-2%Cu-1%Fe-1%Ni), which applied presently for piston materials. The wear behavior of $Al_2O_3$ composites was observed to a type of abrasive wear by the SEM view of wear surface.

• 한국산학기술학회논문지
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• 제19권6호
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• pp.702-708
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• 2018

휘발성 유기 화합물(VOCs: volatile organic compounds)은 대기 오염 물질 중 하나로 주로 화석연료 연소, 도료를 사용하는 건축물 자재 등에서 발생한다. VOCs를 흡입하면 두통, 메스꺼움, 구토 등을 발생시켜 인체에 유해하며 심한 경우에는 기억상실을 유발하고, 백혈병의 발병율을 증가시킨다. 따라서 대기 중의 VOCs를 저감하기 위한 방법의 하나로 우리는 전기방사를 이용하여 폴리아크릴로니트릴과 플라이 애쉬 (PAN/FA: polyacrylonitrile/fly ash) 나노복합재를 성공적으로 제조하였다. 또한 이 복합재의 VOCs에 대한 흡착능력을 관찰하기 위해서 주사형 전자현미경(FE-SEM)을 통해 PAN/FA 나노 매트들의 형태학적 구조 관찰과 클로로폼, 벤젠, 톨루엔, 자일렌 (chloroform, benzene, toluene and xylene) 등 VOCs 성분에 대한 흡착력 실험을 수행한 후 정성 및 정량 (chromatography/mass spectrometry: GC/MS)적으로 분석하였다. 그 결과 40wt%의 FA가 들어있는 PAN 나노섬유가 가장 작은 섬유 지름을 가지고 있었으며, 그 크기는 약 283nm인 것을 확인할 수 있었고, 다른 복합 멤브레인들과 비교하여 VOCs에 대한 흡착력이 우수하다는 것을 실험적으로 규명하였다.