• Bulletin of the Korean Chemical Society
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• 제22권12호
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• pp.1366-1370
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• 2001

Thin films of the SiO2-TiO2-PDMS composite material have been prepared by the sol-gel dip coating method. Acid catalyzed solutions of tetraethoxy silane (TEOS) and polydimethyl siloxane (PDMS) mixed with titanium isopropoxide Ti(OiPr) were used as precursors. The optical and structural properties of the organically modified 70SiO2-30TiO2 composite films have been investigated with Fourier Transform Infrared Spectroscopy (FT-IR), UV-Visible Spectroscopy (UV-Vis), Differential Thermal Analysis (DTA) and prism coupling technique. The films coated on the soda-lime-silicate glass exhibit 450-750 nm thickness, 1.56-1.68 refractive index and 88-94% transmittance depending on the experimental parameters such as amount of PDMS, thermal treatment and heating rate. The optical loss of prepared composite film was measured to be about 0.34 dB/cm.

• Advances in nano research
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• 제16권2호
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• pp.127-140
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• 2024

Upon direct/indirect exposure to flame or heat, composite structures may burn or thermally buckle. This issue becomes more important in the natural fiber-based composite structures with higher flammability and lower mechanical properties. The main goal of the present study was to obtain an optimal eco-friendly composite system with low flammability and high thermal buckling resistance. The studied composite consisted of polypropylene (PP) and short abaca fiber (AF) with eggshell powder (ESP) and halloysite clay nanotubes (HNTs) additives. An optimal base composite, consisting of 30 wt.% AF and 70 wt.% PP, abbreviated as OAP, was initially introduced based on burning rate (BR) and the Young's modulus determined by horizontal burning test (HBT) and tensile test, respectively. The effects of adding ESP to the base composite were then investigated with the same experimental tests. The results indicated that though the BR significantly decreased with the increase of ESP content up to 6 wt.%, it had a very destructive influence on the stiffness of the composite. To compensate for the damaging effect of ESP, small amount of HNT was used. The performance of OAP composite with 6 wt.% ESP and 3 wt.% HNT (OAPEH) was explored by conducting HBT, cone calorimeter test (CCT) and tensile test. The experimental results indicated a 9~23 % reduction in almost all flammability parameters such as heat release rate (HRR), total heat released (THR), maximum average rate of heat emission (MARHE), total smoke released (TSR), total smoke production (TSP), and mass loss (ML) during combustion. Furthermore, the combination of 6 wt.% ESP and 3 wt.% HNT reduced the stiffness of OAP to an insignificant amount by maximum 3%. Moreover, the char residue analysis revealed the distinct differences in the formation of char between AF/PP and AF/PP/ESP/HNT composites. Afterward, dilatometry test was carried out to examine the coefficient of thermal expansion (CTE) of OAP and OAPEH samples. The obtained results showed that the CTE of OAPEH composite was about 18% less than that of OAP. Finally, a theoretical model was used based on first-order shear deformation theory (FSDT) to predict the critical bucking temperatures of the OAP and OAPEH composite plates. It was shown that in the absence of mechanical load, the critical buckling temperatures of OAPEH composite plates were higher than those of OAP composites, such that the difference between the buckling temperatures increased with the increase of thickness. On the contrary, the positive effect of CTE reduction on the buckling temperature decreased by raising the axial compressive mechanical load on the composite plates which can be assigned to the reduction of stiffness after the incorporation of ESP. The results of present study generally stated that a suitable combination of AF, PP, ESP, and HNT can result in a relatively optimal and environmentally friendly composite with proper flame and thermal buckling resistance with no significant decline in the stiffness.

• Restorative Dentistry and Endodontics
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• 제42권4호
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• pp.253-263
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• 2017

Objectives: The aim of the study was to evaluate the 5-year clinical performance of occlusal carious restorations using nanofill and microhybrid composites, in combination with 3-step etch-and-rinse adhesives, in patients who were going to commence orthodontic treatment. Materials and Methods: A total of 118 restorations for occlusal caries were conducted prior to orthodontic treatment. Occlusal restorations were performed both with Filtek Supreme XT (3M ESPE) and Filtek Z250 (3M ESPE) before beginning orthodontic treatment with fixed orthodontic bands. Restorations were clinically evaluated at baseline and at 1, 2, 3, 4, and 5-year recalls. Results: None of the microhybrid (Filtek Z250) and nanofill (Filtek Supreme XT) composite restorations was clinically unacceptable with respect to color match, marginal discoloration, wear or loss of anatomical form, recurrent caries, marginal adaptation, or surface texture. A 100% success rate was recorded for both composite materials. There were no statistically significant differences in any of the clinical evaluation criteria between Filtek Z250 and Filtek Supreme XT restorations for each evaluation period. Conclusions: The composite restorations showed promising clinical results relating to color matching, marginal discoloration, wear or loss of anatomical form, recurrent caries, marginal adaptation, and surface texture at the end of the 5-year evaluation period.

• 한국초전도ㆍ저온공학회논문지
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• 제11권3호
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• pp.1-5
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• 2009

It is important to predict AC loss in $Nb_3Sn$ and NbTi cable-in-conduit-conductor (CICC) reliably for the design and operation of large superconducting coils. The hysteresis loss in the superconducting filaments and coupling loss within strands and among strands in a cable or composite are dominant ac losses in superconducting magnets. The coupling loss in a superconductor can be characterized by identifying the coupling constant time $n{\tau}$. To reduce the coupling loss, all the strands (superconductor and Cu) in KSTAR (Korea Superconducting Tokamak Advance Research) are chromium plated with thickness of $l{\pm}0.5{\mu}m$. The ac losses of PF1, PF5 and PF6 coils has been measured by calorimetric method while applying trapezoidal current pulses with various ramp rate from 0.5 kA/s to 2 kA/s. The coupling time constants for $Nb_3Sn$ coils are $25{\sim}55$ ms and the values are not co-related with the coil size, the time constants for NbTi coil is 30 ms.

• 한국응용과학기술학회지
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• 제19권2호
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• pp.131-136
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• 2002

As model waterborne acrylic coatings, mono-dispersed poly(butyl acrylate-methyl methacrylate) copolymer latexes of random copolymer and core/shell type graft copolymer were prepared by seeded multi-staged emulsion polymerization with particle size of $180{\sim}200$ nm using semi-batch type process. Sodium lauryl sulfate and potassium persulfate were used as an emulsifier and an initiator, respectively. The effect of particle texture including core/shell phase ratio, glass transition temperature and crosslinking density, and film forming temperature on the film formation and final properties of film was investigated using SEM, AFM, and UV in this study. The film formation behavior of model latex was traced simultaneously by the weight loss measurement and by the change of tensile properties and UV transmittance during the entire course of film formation. It was found that the increased glass transition temperature and higher crosslinking degree of latex resulted in the delay of the onset of coalescence of particles by interdiffusion during film forming process. This can be explained qualitatively in terms of diffusion rate of polymer chains. However, the change of weight loss during film formation was insensitive to discern each film forming stages-I, II and III.

• 콘크리트학회논문집
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• 제25권4호
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• pp.429-438
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• 2013

콘크리트 장기변형이 합성단면과 부재의 경계조건에 의해 내 외부 구속된 구조물에 단계별계산법(SSM)을 적용하 기위해 축-휨 요소가 적용된 객체지향 전산구조해석 프로그램이 개발되었다. 단순 및 연속 지지된 PS 콘크리트 박스 및 합성거더, 연속 강합성거더의 조립식 바닥판, 단순 프리플렉스 합성거더에 대한 SSM의 전산구조해석 결과 구속정도가 클수록 수정계수는 감소하였다. 수정계수의 감소에 대해 선인장의 손실률에는 큰 변화가 없으나, 선압축의 손실률은 급격히 증가하였다. 연속보의 내부지점에서 선압축의 손실률은 더욱 증가하였다. 이는 선인장의 손실에 기초한 설계는 내 외부 구속 정도가 큰 구조물에 대한 선압축의 손실을 과소평가할 수 있음을 보여준다. 전산구조해석을 만족하는 크리프의 수정계수는 0.35~0.95의 값이었으며, 수정 계수는 콘크리트 장기변형의 내 외부 구속의 정도를 나타내는 지표로 사용될 수 있다. 도로교설계기준의 수정계수 0.5는 긴장력이 도입된 강합성단면의 조립식 바닥판에 대해서는 부적절하며, 2007년 도입된 AASHTO LRFD 도로교설계기준(2008)과 한계상태에 대한 도로교설계기준의 긴장력 손실에 적용된 수정계수 0.7과 0.8은 PS 콘크리트 합성거더의 연속화에 대한 손실률을 과소평가한다. 복합구조 합성단면의 수정계수는 0.4 이하의 값이 적절하다.

• Restorative Dentistry and Endodontics
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• 제25권3호
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• pp.359-370
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• 2000

The purpose of this investigation was to observe the viscoelastic properties of five commercial flowable(Aeliteflo, Flow it, Revolution, Tetric flow, Compoglass flow), three conventional hybrid(Z-100, Z-250, P-60) and two condensable(Synergy compact, SureFil) resin composites. A dynamic oscillatory shear test was done to evaluate the storage shear modulus (G'), loss shear modulus(G"), loss tangent(tan ${\delta}$) and complex viscosity(${\eta}^*$) of the resin composites as a function of frequency - dynamic frequency sweep test from 0.01 to 100 rad/s at $25^{\circ}C$ - by using Advanced Rheometric Expansion System(ARES). To investigate the effect on the viscosity of resin composites of filler volume fraction, the filler weight % and volume % were measured by means of Archimedes' principle using a pyknometer. The results were as follows 1. The complex viscosity ${\eta}^*$ of flowable resins was lower than that of hybrid resins and significant differences were observed between brands. The complex viscosity ${\eta}^*$ of condensable resins was higher than that of hybrid resins. The order of complex viscosity ${\eta}^*$ at ${\omega}$=10 rad/s was as follows, Surefil, Synergy compact, P-60, Z-250, Z-100, Aeliteflo, Tetric flow, Compoglass flow, Flow it, Revolution. The relative complex viscosity of flowable resins compared to Z-100 was 0.04~0.56 but Surefil was 30.4 times higher than that of Z-100. 2. The storage shear modulus G' and the loss shear modulus G" of flowable resins were lower than those of hybrid resins but those of condensable resins were higher. The patterns of the change of loss tangent, tan ${\delta}$, of resin composites with increasing frequency were significantly different between brands. The phase angles, ${\delta}$, ranged from $30.2{\sim}78.1^{\circ}$ at ${\omega}$=10 rad/s. 3. All composite resins represent pseudoplastic nature with increasing shear rate. 4. The complex shear modulus $G^*$ and the phase angle ${\delta}$ was represented by the frequency domain phasor form, $G^*({\omega})=G^*e^{i{\delta}}=G^*{\angle}{\delta}$. The locus of frequency domain phasor plots in a complex plane was a valuable method that represent the viscoelastic properties of composite resins. 5. There was no direct linear correlationship but a weak positive relation was observed between filler volume % or weight % and the viscosity of the resin composites.

• 대한안전경영과학회:학술대회논문집
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• 대한안전경영과학회 2013년 추계학술대회
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• pp.275-290
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• 2013

The main cause of building fire fatalities occur in the combustible material heat, smoke and toxic gases are. Building interior decoration, etc., especially as much of the harmful substances generated during combustion, and, used in domestic architecture wallpaper, ceiling, and other plastics, built-in foam insulation also analyzed recognition of fire hazards approach to test the conkalrorimiteo test, choedaeyeolbangchulryul through, chongbal heat, mass loss rate, generates carbon monoxide gas hazard ratio tests, analysis and evaluation rigid foam index testing the toxicity of hazardous material generated by performing a gas clean up and assess the material test results, the minimum order to provide data to quantify the risk of fire. Ensure fire safety of building materials, composite materials in order to test the various risk factors could be considered organic to the introduction of testing and evaluation is needed urgently.

• 한국재료학회지
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• 제16권11호
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• pp.676-680
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• 2006

The biodegradable $\beta$-tricalcium phosphate ($\beta$-TCP)/poly(lactide-co-glycolide) (PLGA) composites were synthesized by in situ polymerization with microwave energy. The degradation behavior of $\beta$-TCP/PLGA composite was investigated by soaking in simulated body fluid (SBF) for 4 weeks. The molecular weight of the $\beta$-TCP/PLGA composites decreased with soaking time until week 2, whereas the loss rate of molecular weight reduced after week 2. The incubation time was needed for the degradation of the $\beta$-TCP, indicating that the $\beta$-TCP should be detached from the PLGA matrix and then degraded into SBF solution. The studies of mass loss of the composites with the soaking time revealed that the degradation behavior of PLGA would be processed with the transformation from the polymer to the oligomer followed by the degradation. Morphological changes, whisker-like, due to transformation and degradation of polymer in the composites were observed after week 2. On the basis of the results, it found that the degradation behavior of $\beta$-TCP/PLGA composites was influenced by the $\beta$-TCP content in the composites and the degradation rate of the composites could be controlled by the initial molecular weight of PLGA in the composites.

• 한국식품조리과학회지
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• 제32권3호
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• pp.279-289
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• 2016

Purpose: This study was to determine the optimal composite recipe of rice cookie with 3 concentrations of Spergularia Marina L. Griseb, sugar and grape seed oil, using central composite design (CCD). Methods: The mixing condition of rice cookie was optimized by subjecting it to sensory evaluation and mechanical and physicochemical analysis using response surface methodology (RSM). Results: The results of mechanical and physicochemical analysis showed significant values for lightness, redness, yellowness, hardness, spread factor, loss rate, leavening rate, density, pH, moisture, sweetness and saltiness (p<0.05), and the results of sensory evaluation showed significant values for color, flavor, taste, texture, appearance and overall quality (p<0.05). As a result, the optimal sensory ratio was found to be 6.40 g of Spergularia Marina L. Griseb, 63.49 g of sugar and 106.19 g of grape seed oil. Conclusion: In conclusion, Spergularia Marina L. Griseb is a good source in natural antioxidant aimed at replacing salt, and it is possible to use in cookie or other food products to substitute salt.