• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2016.11a
• /
• pp.198-198
• /
• 2016

An ideal orthopedic implant should provide an excellent bone-implant connection, less implant loosening and minimum adverse reactions. Commercial pure titanium (CP-Ti) and Ti alloys have been widely utilized for biomedical applications such as orthopedic and dental implants. However, being bioinert, the integration of such implant in bone was not in good condition to achieve improved osseointegraiton, there have been many efforts to modify the composition and topography of implant surface. These processes are generally classified as physical, chemical, and electrochemical methods. Plasma electrolytic oxidation (PEO) as an electrochemical route has been recently utilized to produce this kind of composite coatings. Mg ion plays a key role in bone metabolism, since it influences osteoblast and osteoclast activity. From previous studies, it has been found that Mg ions improve the bone formation on Ti alloys. PEO is a promising technology to produce porous and firmly adherent inorganic Mg containing $TiO_2$($Mg-TiO_2$ ) coatings on Ti surface, and the amount of Mg introduced into the coatings can be optimized by altering the electrolyte composition. In this study, a series of $Mg-TiO_2$ coatings are produced on Ti-6Al-4V ELI dental implant using PEO, with the substitution degree, respectively, at 0, 5, 10 and 20%. Based on the preliminary analysis of the coating structure, composition and morphology, a bone like apatite formation model is used to evaluate the in vitro biological responses at the bone-implant interface. The enhancement of the bone like apatite forming ability arises from $Mg-TiO_2$ surface, which has formed the reduction of the Mg ions. The promising results successfully demonstrate the immense potential of $Mg-TiO_2$ coatings in dental and biomaterials applications.

• Restorative Dentistry and Endodontics
• /
• v.15 no.1
• /
• pp.201-216
• /
• 1990

A variety of surface pre-treatments have been advocated to prepare the dentin prior to placement of a bonding agent. The purpose of this study was to evaluate the effect of various dentin conditioners upon the degree of resin impregnation to the dentinal tubules and the shear bond strength of a new dentinal bonding agent (Scotchbond 2) used in conjunction with a visible light cured composite (Silux). The healthy eighty human molars extracted due to periodontal or orthodontic reasons were used and randomly divided into five groups. All the grinded dentin surfaces were conditioned with 3% $H_2O_2$, Cavity Cleanser (Columbus/Bayer), Dentin Conditioner (GC Inter. Corp.), Scotchprep (3M Co.) according to the manufacturer's directions. The specimens were then demineralized in 10% HCl for 20 sec. and 24 hrs. in order to observe the resin tags in Hitachi X-450 scanning electron microscope at 25KV. Also, shear strengths were obtained using an Instron Testing Machine with a cross head speed of 1 mm/min. The following results were obtained ; 1. In group treating with Dentin Conditioner and Scotchprep, the resin strings were formed on most of the surfaces and penetrated more than $50{\mu}m$ into the tubules. 2. The inner surface of resin treated with Cavity Cleanser, indicating the resin strings formed partly and penetrated about in depth of $30{\mu}m$. 3. In control and experimental group treated with 3% $H_2O_2$, the resin tags were not formed, if any, penetrated shortly. 4. Shear bond strengths in groups treating with Dentin Conditioner and Scotchprep were statistically significant increase than with 3% $H_2O_2$. (P<0.01). 5. The Scotchprep treatment group was significantly higher in shear strength than groups treated with no conditioning and Cavity Cleanser.(P<0.01) 6. Shear bond strengths evaluated were gradually increase in proportion to the tag length of resin impregnation.

• Elastomers and Composites
• /
• v.38 no.2
• /
• pp.139-146
• /
• 2003

In this work, the influence of ozone treatment on surface properties of carbon black is investigated in terms of X-ray photoelectron spectroscopy (XPS) and contact angles. And their mechanical interfacial properties of the carbon black/acrylonitrile butadiene rubber (NBR) compounds are studied by the crosslink density and composite tearing energy ($G_{IIIC}$). As a result, it is found that the increasing of the ozone concentration leads to an increase of the introduction rate of oxygen-containing functional groups onto carbon black surfaces and to an increase of the surface free energy, resulting in improving both crosslink density and tearing energy ($G_{IIIC}$) of the compounds. The results can be explained by the fact that the oxygen-containing functional groups of carbon black surfaces make an increase of the degree of adhesion at interfaces between carbon blacks and rubber matrix.

• Journal of Adhesion and Interface
• /
• v.6 no.4
• /
• pp.1-6
• /
• 2005

In this work, the effect of chemical treatments on surface properties of SiC was investigated in crack resistance properties of SiC/epoxy composites. The surface properties of SiC were determined by acid/base values and FT-IR measurements. Also the crack resistance properties of the composites were studied in critical strain energy release rate mode II ($G_{IIC}$) measurements. As a result, the acidically treated SiC had higher acid value than that of untreated SiC or basically treated SiC. The crack resistance properties of the composites had been improved in the specimens treated by acidic solution. These results were could be attributed to the acide-base intermolecular interaction between SiC and epoxy resin, resulting in increase of the degree of adhesion at interfaces.

• Composites Research
• /
• v.25 no.3
• /
• pp.70-75
• /
• 2012

Interfacial durability and electrical properties of CNT, ITO or xGnP coated PVDF nanocomposites were investigated for acoustic actuator applications. The xGnP coated PVDF nanocomposite exhibited better electrical conductivity than CNT and ITO case due to the unique electrical property of xGnP, and this nanocomposite also showed good sound characteristics. Interfacial adhesion durability between either neat CNT or plasma treated CNT and plasma treated PVDF were measured by static contact angle, surface energy, work of adhesion, and spreading coefficient tests. The optimum acoustic actuation performance of xGnP coated PVDF nanocomposite was measured using sound level meter with changing radius of curvature and coating conditions. As compared to CNT and ITO, the xGnP was known as more appropriate acoustic actuator due to the characteristic electrical property. It is the most appropriate condition when the radius of curvature is 15 degree. Although sound characteristics were different with various coating thicknesses, it is possible to manufacture transparent actuator with good sound quality.

• Composites Research
• /
• v.25 no.1
• /
• pp.26-30
• /
• 2012

This study was focused on the measurement of thermal expansion coefficients for GRP pipe through strain gage circuits. First of all, thermal expansion coefficients of aluminum beam were measured to examine the validity of the suggested method by using various types of strain gage circuits. Thermal expansion coefficients of GRP pipes along axial and hoop directions were measured to investigate the effect of the location of strain gages, number of repeated measurements, and strain gage types with different thermal expansion coefficients on the thermal strains and the repeatability of measured results. According to the results, thermal expansion coefficients of GRP pipes along hoop direction were lower than those along axial direction due to the constraint effect of reinforced glass fibers on thermal strains along hoop direction. As measurements were repeated, thermal expansion coefficients of GRP pipes were slightly increased, but the degree of increase became smaller. Finally, the same thermal expansion coefficients were obtained irrespective of different types of strain gages with different thermal expansion coefficients if thermal strains of strain gages were compensated by using reference compensation specimen.

• Elastomers and Composites
• /
• v.37 no.2
• /
• pp.99-106
• /
• 2002

In this work, the surface properties and mechanical interfacial properties of the carbon blacks treated by oxygen plasma were investigated. The surface properties of carbon black by oxidation process of oxygen plasma were studied in acid-base surface value, zeta potential, and X-ray photoelectron spectroscopy (XPS). And their mechanical interfacial properties of the carbon black/rubber composites were evaluated by the composite tearing energy ($G_{III}c$). As a result, it was found that the introduction rate of oxygen-containing polar functional groups, such as carboxyl, hydroxyl, lactone, and carbonyl groups, onto the carbon black surfaces was increased by increasing the plasma treatment time. It revealed that the polar rubber, such as acrylonitrile butadiene rubber (NBR), showed relatively a high degree of interaction with oxygen-containing functional groups of the carbon black surfaces, resulting in improving the tearing energy ($G_{III}c$) of the carbon black/acrlyonitrile butadiene rubber composites.

• Elastomers and Composites
• /
• v.44 no.1
• /
• pp.47-54
• /
• 2009

EPDM(Ethylene-propylene-diene-terpolymer) compound reinforced with carbon black having four different particle size, acetylene black(thermal conductivity carbon black), and silica were manufactured by internal mix and open mill. To investigate the effect of particle size of filler and filler type on far-infrared vulcanization, intermal temperature of compound, degree of curing, infrared spectroscopy, and thermal analysis were measured. The thermal conductivity of far-infrared vulcanized EPDM compound increased with increasing particle size of carbon filler, but hot air vulcanized EPDM compound is not affected by particle size. The thermal conductivity was increased in the order of carbon black < silica < acetylene black(thermal conductivity carbon black).

• Computational Structural Engineering
• /
• v.7 no.4
• /
• pp.103-111
• /
• 1994

Based on a variational principle of the consistent shear deformable discrete laminate theory derived in the companion paper Part I, a finite element procedure for the vibration analysis of laminated composite plates is presented. The present formulation takes the in-plane displacements of an arbitrary layer, the rotations of the cross section of each layer and transverse displacement of the plate as the state variables at a nodal point of finite element, resulting in total nodal degree of freedom of 2(n+l) +1 for the n-layered laminate. Thus, it allows to specify displacement boundary conditions of layer stretching and/or rotation of layer cross sections around the plate edge and/or lateral displacement. The developed procedure is applied to the free vibration problem for sandwich-type hybrid laminates composed of layers with drastically different material properties whose elasticity solutions are known. Comparison of analysis results with other FEM solutions showed that the present formulation yields better accuracy.

• Steel and Composite Structures
• /
• v.12 no.4
• /
• pp.353-379
• /
• 2012

The accuracy of the 30% and SRSS rules, commonly used to estimate the combined response of structures, and some related issues, are studied. For complex systems and earthquake loading, the principal components give the maximum seismic response. Both rules underestimate the axial load by about 10% and the COV of the underestimation is about 20%. Both rules overestimate the base shear by about 10%. The uncertainty in the estimation is much larger for axial load than for base shear, and, for axial load, it is much larger for inelastic than for elastic behavior. The effect of individual components may be highly correlated, not only for normal components, but also for totally uncorrelated components. The rules are not always inaccurate for large values of correlation coefficients of the individual effects, and small values of such coefficients are not always related to an accurate estimation of the response. Only for perfectly uncorrelated harmonic excitations and elastic analysis of SDOF systems, the individual effects of the components are uncorrelated and the rules accurately estimate the combined response. In the general case, the level of underestimation or overestimation depends on the degree of correlation of the components, the type of structural system, the response parameter, the location of the structural member and the level of structural deformation. The codes should be more specific regarding the application of these rules. If the percentage rule is used for MDOF systems and earthquake loading, at least a value of 45% should be used for the combination factor.