• Title/Summary/Keyword: Composite Degree

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Proton Conductivity and Methanol Permeability of Sulfonated Polysulfone/PPSQ Composite Polymer Electrolyte Membrane (설폰화된 폴리설폰/PPSQ 유-무기 복합 전해질막의 수소이온 전도도 및 메탄올 투과 특성)

  • Kwon Jeongdon;Lee Changjin;Kang Yongku
    • Journal of the Korean Electrochemical Society
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    • v.7 no.2
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    • pp.89-93
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    • 2004
  • Sulfonated polysulfone (SPSF) with poly(phenylmethyl silsesquioxane, PPSQ) composite polymer electrolyte membranes were prepared and their proton conductivity, water uptake and methanol permeability of membranes were characterized. By controlling the ratio of $(CH_3)_3SCI\;and\;CISO_3H$ and reaction time, SPSF with $37\~75\%$ degree of sulfonation were synthesized. The increase of sulfonate groups in the base polymer resulted in the increase of the water uptake in the membranes as well as methanol permeability. Composite membranes were prepared by casting of DMF solution of SPSF and PPSQ. The proton conductivity of the composite membrane at room temperature was $2.8\times10^{-3}\~4.9\times10^{-2}S/cm.$ The increase of PPSQ contents in composite membranes resulted in a decrease in water uptake and methanol permeability. Composite membranes containing $5\%$ PPSQ did not make a significant effect on the proton conductivity nO methanol permeability compared with that of pristine SPSF, but a significant decrease of water uptake was observed.

Shear Strength Characteristics of Recycled-Aggregate Porous Concrete Pile for Soft Ground Improvement (순환골재를 활용한 연약지반개량용 다공질 콘크리트 말뚝의 전단특성)

  • Yoon, Gil-Lim;Yoon, Yeo-Won;Kang, O-Ram;You, Seung-Kyong;Lee, Kyu-Hwan
    • Journal of the Korean Geotechnical Society
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    • v.24 no.12
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    • pp.75-84
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    • 2008
  • Recycled-aggregate porous concrete pile (RAPP) which forms a composite ground is one of new ground improvement techniques. In this paper, triaxial compression tests are carried out to investigate the shear strength characteristics of RAPP-Clay composite samples. The main purpose of the tests was to investigate the effects of area replacement ratio ($15%{\sim}100%$) on behaviors of RAPP-Clay samples during shearing. Also, triaxial compression tests using Sand-Clay composite samples were performed to compare with the behaviors of RAPP-Clay samples. The test results showed that the friction angle and cohesion of the RAPP-Clay composite were $18{\sim}34$ degree and $557.0{\sim}588.0\;kPa$, respectively, whereas those of sand-clay composite samples were 26~35 degree of friction angel and $4.0{\sim}18.0\;kPa$.

Numerical and experimental study of large deflection of symmetrically laminated composite plates in compression

  • Chai, Gin Boay;Hoon, Kay Hiang
    • Structural Engineering and Mechanics
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    • v.2 no.4
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    • pp.359-367
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    • 1994
  • The stability behaviour of symmetrically laminated rectangular composite plates with loaded ends clamped and unloaded edges simply-supported, and subjected to uniform in-plane compression is investigated. A numerical and experimental investigation is presented in this contribution. The stacking sequence of the laminated glass/epoxy composite plates is symmetric about the middle surface and consists of 8-ply [0, 90, +45, -45]s lamination. Numerical predictions were obtained through the use of the finite element method. The above plates were modelled with 8-noded isoparametric layered shell elements. The effect of the input parameters such as the degree and forms of prescribed initial imperfection and the incremental step size required for incremental loading, on the convergence of the solution is thoroughly examined. Experimental results are presented for 10 test panels. All test panels were made from glass/epoxy unidirectional prepregs and have aspect ratio of 5.088. The laminate thicknesses were found to vary from 1.054 mm to 1.066 mm. Comparison of experimental data with predicted results show good correlation and give confidence in the finite element model.

Studies on Mechanical Interfacial Properties of Kevlar-29 Fibers Reinforced Composites (Kevlar-29 섬유강화 복합재료의 기계적 계면 특성 연구)

  • Park, Soo-Jin;Seo, Min-Kang;Ma, Tae-Jun;Lee, Jae-Rock
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.10a
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    • pp.158-162
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    • 2001
  • The effects of chemical treatment on Kevlar-29 fibers have been studied in a composite system. The surface characteristics of the Kevlar-29 fibers were characterized by pH, acid-base value and X-ray photoelectron spectroscopy (XPS). The mechanical interfacial properties of final composites were studied by interlaminar shear strength (ILSS) and critical stress intensity factor ($K_{IC}$). Also, the impact properties of the composites were investigated in the differentiating studies between initiation and propagation energies, and ductile index (DI) along with maximum farce and total energy. It was found that the chemical treatment with phosphoric acid ($H_3PO_4$) solution significantly affected the degree of adhesion at interfaces between fibers and resin matrix, resulting in improving the mechanical interfacial strength of the composites. This was probably due to the presence of chemical polar groups on Kevlar surfaces, leading to an increment of interfacial binding force in a composite system.

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Mechanical Synthesis and Rapid Consolidation of Nanostructured W-Al2O3 Composite

  • Lee, BooRak;Jeong, GeolChae;Park, GeunO;Shon, In-Jin
    • Korean Journal of Materials Research
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    • v.28 no.6
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    • pp.343-348
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    • 2018
  • Recently, the properties of nanostructured materials as advanced engineering materials have received great attention. These properties include fracture toughness and a high degree of hardness. To hinder grain growth during sintering, it is necessary to fabricate nanostructured materials. In this respect, a high-frequency induction-heated sintering method has been presented as an effective technique for making nanostructured materials at a lower temperature in a very short heating period. Nanopowders of W and $Al_2O_3$ are synthesized from $WO_3$ and Al powders during high-energy ball milling. Highly dense nanostructured $W-Al_2O_3$ composites are made within three minutes by high-frequency induction-heated sintering method and materials are evaluated in terms of hardness, fracture toughness, and microstructure. The hardness and fracture toughness of the composite are $1364kg/mm^2$ and $7.1MPa{\cdot}m^{1/2}$, respectively. Fracture toughness of nanostructured $W-Al_2O_3$ is higher than that of monolithic $Al_2O_3$. The hardness of this composite is higher than that of monolithic W.

Design of optimal fiber angles in the laminated composite fan blades (적층 복합재 팬-블레이드의 적층각도 최적화 설계)

  • Jeong, Jae-Yeon;Jo, Yeong-Su;Ha, Seong-Gyu
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.21 no.11
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    • pp.1765-1772
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    • 1997
  • The layered composites have a character to change of structure stiffness with respect to the layup angles. The deformations in the fan-blades to be initially designed by considering efficiency and noise, etc., which arise due to the pressure during the fan operation, can make the fan inefficient. Thus, so as to minimize the deformations of the blades, it is needed to increase the stiffness of the blades. An investigation has been performed to develop the three dimensional layered composite shell element with the drilling degree of freedom and the optimization module for finding optimal layup angles with sensitivity analysis. And then they have been verified. In this study, the analysis model is engine cooling fan of automobile. In order to analyzes the stiffness of the composite fan blades, finite element analysis is performed. In addition, it is linked with optimal design process, and then the optimal angles that can maximize the stiffness of the blades are found. In the optimal design process, the deformations of the blades are considered as multiobjective functions, and this results minimum bending and twisting simultaneously.

Mechanical Properties of GMT-Sheet on Press joined Molding (프레스 접합성형 GMT-Sheet의 기계적 성질)

  • Kim, H.;Choi, Y.S.;Lee, C.H;Han, G.Y.;Lee, D.G
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2000.04a
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    • pp.157-163
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    • 2000
  • The application as the parts of an automobile, using the property of GMT-Sheet, is increasing. In order to exchange the parts of an automobile for GMT-Sheet, at first, the establishment and joining problem of exact joining strength must be determined. We have studied it using composites which is not same each other fiber oriented condition so as to determine joining strength and joining condition of GMT-Sheet. In this study, the result of experiment of forming condition concerned joining problem of GMT-Sheet is this ; joining efficiency of GMT-Sheet, increases as lap joint length L increases. Increase of compression ration cause decrease of joining efficiency after of GMT-Sheet, joining. In the viewpoint of recycling, randomly oriented composite of GMT-Sheet is desirable more than unidirectional oriented composite. We have better design the structure so as not occur to stress centralization on the joining part.

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Static and Dynamic Analyses of Pure Bending Problems of Composite Plates using Non-Conforming 3-Dimensional 8-Node Solid Element (3차원 8절점 비적합 고체요소에 의한 복합재판의 순수굽힘문제의 정적.동적해석)

  • Yun, Tae-Hyeok;Gwon, Yeong-Du
    • Journal of Ocean Engineering and Technology
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    • v.12 no.2 s.28
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    • pp.1-21
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    • 1998
  • In this paper, a non-conforming 3-D 8-node solid element(MQM10) has beets applied to the analyses of static and dynamic bending problems of laminated composite plates The QM10 element exhibits stiffer bending stiffness which is caused by the reduction of degree of freedom from Q11 element. As an effective way to correct the relative stiffness stiffening phenomenon the modification of Gauss sampling points for composite plates is proposed. The quantity of modification is a function of material properties. Also, another two modified equations are obtained, one is modification for stress, and the other is modification of coefficient of shear modulus in free vibration. It is noted that MQM10 element can analyse the static and free vibration problems of various 3-dimensional composite plates composed of unidirectional laminae, woven laminae or braided laminae. The results of MQM10 element are in good agreement with those of 20-node element.

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Improvement of Mechanical Properties of IPMC through Developing a Degree of Dispersion of SWCNT/Nafion Composite (SWCNT/Nafion 복합체의 분산능 향상을 통한 IPMC의 기계적 특성 향상)

  • Kwon, Hui-June;Kim, Ha-Na;Kang, Jung-Ho
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.10 no.5
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    • pp.131-136
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    • 2011
  • Many researchers are recently studying about Electroactive polymer(EAP). But it has a physical limitation, because of property of material. Carbon nanotube(CNT) is known as the promising material which has excellent electro-mechanical characteristics and is mostly defect-free. It is expected that a successful synthesis of CNT and Nafion known as a primary material for IPMC would make a great improvement on its electro-mechanic feature. This study focuses on the method of synthesis of CNT with Nafion which improves electro-mechanical characteristic. To come up with mechanical dispersion with Nafion and Isopropyl Alcohol(IPA), we dispersed Single-walled carbon nanotubes(SWCNTs). For a uniformly layer of CNT, we used a spray gun on a hot plate by a simplified method. We fabricated a disperse SWCNT/Nafion composite uniformly. Through the use of the E-beam evaporator to form an uniform electrode layer, we consummated the IPMC actuator. This result shows improving 1.5 times mechanical properties about driving force in IPMC.

Mechanical Properties of GMT-Sheet on Press joined Molding (프레스 접합성형 GMT-Sheet의 기계적 성질)

  • Kim, Hyuk;Choi, Yu-Sung;Lee, Dong-Ki;Han, Gil-Young;Kim, Yi-Gon
    • 제어로봇시스템학회:학술대회논문집
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    • 2000.10a
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    • pp.553-553
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    • 2000
  • The application as the parts of an automobile, using the property of GMT-Sheet, is increasing. In order to exchange the parts of an automobile for GMT-Sheet, at first, the establishment and joining problem of exact joining strength must be determined. We have studied it using composites which is not same each other fiber oriented condition so as to determine joining strength and joining condition of GMT-Sheet. h this study, the result of experiment of forming condition concerned joining problem of GMT-Sheet is this ; joining efficiency of of GMT-Sheet, increases as lap joint length L increases. Increase of compression ratio causes decrease of joining efficiency after of GMT-Sheet joining. In the viewpoint of recycling, randomly oriented composite of GMT-Sheet is desirable more than unidirectional oriented composite. We has better design the structure so as not to occur to stress centralizatien on the joining part.

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