• Title/Summary/Keyword: Complex modulus

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Viscosity and Dynamic Rheological Properties of Job's-tears as a Function of Moisture Content (수분함량에 따른 율무가루의 점도변화 및 동적물성 특성에 관한 연구)

  • Yoon, Won-Byung;Kim, Byung-Yong;Shin, Dong-Hoon
    • Korean Journal of Food Science and Technology
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    • v.29 no.5
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    • pp.932-938
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    • 1997
  • Changes in viscosity and dynamic theological properties of Job's-tears were measured by Bohlin dynamic tester as a function of moisture, and measurement was performed within a linear viscoelastic range. The result of the shear stress vs shear rate of Job's-tears at different moisture contents $(50{\sim}75%)$ was applied to mathematical models and Herschel-Bulkley model showed the highest correlation coefficient. Lower moisture content (55%) produced higher yield stress and consistency index, but lower flow behavior index, whereas higher moisture content showed reverse effects. Job's-tears with $50{\sim}70%$ moisture contents showed a higher storage modulus (G') than loss modulus (G') at all frequencies, showing a higher concentrated polymer characteristics. However, higher moisture content (>75%) showed crossover point between G' and G', and frequency dependency. As the moisture content was increased, the amount of viscoelastic properties such as G', G', complex viscosity decreased during heating, and initial temperature and miximum value of viscoelastic properties shifted to higher temperatures, representing the moisture-dependence of Job's-tears upon theological properties.

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Linear Low Density Polyethylene (LLDPE)/Zeolite Microporous Composite Film

  • Jagannath Biswas;Kim, Hyun;Soonja Choe;Patit P. Kundu;Park, Young-Hoon;Lee, Dai-Soo
    • Macromolecular Research
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    • v.11 no.5
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    • pp.357-367
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    • 2003
  • The linear low density polyethylene (LLDPE)/zeolite composite using novel inorganic filler, zeolite, is prepared by a conventional compounding procedure using a twin-screw extruder. The observed scanning electron microscopic (SEM) morphology shows a good dispersion and adhesion of zeolite in the LLDPE matrix. The mechanical properties in terms of the Young's modulus, the yield stress, the impact strength, and the elongation at break were enhanced with a successive increment of zeolite content up to 40 wt%. The X-ray diffraction measurement is of supportive for the improved mechanical properties and the complex melt viscosity is as well. Upon applying a certain level of strain on the composites, the dewetting, the air hole formation and its growth are characterized. The dewetting originates around the filler particles at low strain and induces elliptical micropores upon further stretching. The microporosity such as the aspect ratio, the number and the total area of the air holes is also characterized. Thus, the composites loaded 40 % zeolite and 300 % elongation may be applicable for breathable microporous films with improved modulus, impact and yield stress, elongation at break, microporosity and air hole properties.

Preparation and Characterization of Biodegradable Poly(butylene succinate)(PBS) Foams

  • Lim, Sang-Kyun;Jang, Suk-Goo;Lee, Seok-In;Lee, Kwang-Hee;Chin, In-Joo
    • Macromolecular Research
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    • v.16 no.3
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    • pp.218-223
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    • 2008
  • In order to obtain crosslinked poly(butylene succinate) (PBS) foams with a closed-cell structure, a commercial-grade PBS was first modified in the melt using two different branching agents to increase the melt viscosity. The rheological properties of the branched and crosslinked PBS were examined by varying the amount of the branching agents. The complex viscosity of the crosslinked PBS increased with increasing amount of the branching agent. However, it decreased with increasing frequency. When 2 phr of the branching agent was added to PBS, the storage modulus (G') was higher than the loss modulus (G") throughout the entire frequency range, showing that the addition of a branching agent increases the melt viscosity and elasticity of PBS effectively. Closed-cell PBS foams were prepared by mixing the chemical blowing agent with the crosslinked PBS. The effect of the foaming conditions such as temperature and time, and the amount of the crosslinking agent on the structure of the expanded PBS foams were also investigated.

Performance evaluation of underground box culverts under foundation loading

  • Bin Du;Bo Hao;Xuejing Duan;Wanjiong Wang;Mohammad Roohani
    • Geomechanics and Engineering
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    • v.38 no.4
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    • pp.397-408
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    • 2024
  • Buried box culverts are crucial elements of transportation infrastructure. However, their behavior under foundation loads is not well understood, indicating a significant gap in existing research. This study aims to bridge this gap by conducting a detailed numerical analysis using the Finite Element Method and Abaqus software. The research evaluates the behavior of buried box culverts by examining their interaction with surrounding soil and the pressures from surface foundation loads. Key variables such as embedment depth, culvert wall thickness, concrete material properties, foundation pressure, foundation width, soil elastic modulus, and friction angle are altered to understand their combined effects on structural response. The methodology employs a validated 2D numerical model under plane strain conditions. Parametric studies highlight the critical role of culvert depth (H) in influencing earth pressure and bending moments. Foundation pressure and width demonstrate complex interdependencies affecting culvert behavior. Variations in culvert materials' elastic modulus show minimal impact. It was found that the lower wall of the buried culvert experiences higher average pressure compared to the other two walls, due to the combined effects of the culvert's weight and down drag forces on the side walls. Furthermore, while the pressure distribution on the top and bottom walls is parabolic, the pressure on the side walls follows a different pattern, differing from that of the other two walls.

Static performance of a new GFRP-metal string truss bridge subjected to unsymmetrical loads

  • Zhang, Dongdong;Yuan, Jiaxin;Zhao, Qilin;Li, Feng;Gao, Yifeng;Zhu, Ruijie;Zhao, Zhiqin
    • Steel and Composite Structures
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    • v.35 no.5
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    • pp.641-657
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    • 2020
  • A unique lightweight string truss deployable bridge assembled by thin-walled fiber reinforced polymer (FRP) and metal profiles was designed for emergency applications. As a new structure, investigations into the static structural performance under the serviceability limit state are desired for examining the structural integrity of the developed bridge when subjected to unsymmetrical loadings characterized by combined torsion and bending. In this study, a full-scale experimental inspection was conducted on a fabricated bridge, and the combined flexural-torsional behavior was examined in terms of displacement and strains. The experimental structure showed favorable strength and rigidity performances to function as deployable bridge under unsymmetrical loading conditions and should be designed in accordance with the stiffness criterion, the same as that under symmetrical loads. In addition, a finite element model (FEM) with a simple modeling process, which considered the multi segments of the FRP members and realistic nodal stiffness of the complex unique hybrid nodal joints, was constructed and compared against experiments, demonstrating good agreement. A FEM-based numerical analysis was thereafter performed to explore the effect of the change in elastic modulus of different FRP elements on the static deformation of the bridge. The results confirmed that the change in elastic modulus of different types of FRP element members caused remarkable differences on the bending and torsional stiffness of the hybrid bridge. The global stiffness of such a unique bridge can be significantly enhanced by redesigning the critical lower string pull bars using designable FRP profiles with high elastic modulus.

Study on the Physical Properties of the Artificial Lightweight Aggregate Recycled from the Dyestuff Sludge Treated Chemically With Ti and Fe Salt (Ti염 및 Fe염으로 화학처리된 염색공단 슬러지를 재활용한 인공경량골재의 물리적 특성에 관한 연구)

  • Choi, Jong-Oh;Jung, Yong-Wook
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.1
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    • pp.34-42
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    • 2015
  • The paper investigates environmental hazards and characteristics of the artificial lightweight aggregate manufactured by using dyestuff sludge from dyeing industrial complex. The dyestuff sludge used in this study is chemically treated with Ti and Fe salt for the purpose of recycling. The artificial lightweight aggregate is manufactured through 3 step; 1) Selecting the optimum moisture content by evaluating plasticity from the mixing ratio of the clay and sludge, 2) shaping round type based on the optimum mixing ratio, 3) drying and Sintering process. Based on KS F 2534 "Lightweight Aggregate for Structural concrete", the particle size, fineness modulus, the density, absorption, unit volume weight, stability and environmental hazards of the manufactured lightweight aggregate are evaluated. Experimental results show that the particle size and fineness modulus is out of the range. However, it is observed that other physical properties are within criteria. In addition, it is confirmed that the problem of the particle size and fineness modulus could be solved in the manufacturing process.

Neuro-fuzzy based prediction of the durability of self-consolidating concrete to various sodium sulfate exposure regimes

  • Bassuoni, M.T.;Nehdi, M.L.
    • Computers and Concrete
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    • v.5 no.6
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    • pp.573-597
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    • 2008
  • Among artificial intelligence-based computational techniques, adaptive neuro-fuzzy inference systems (ANFIS) are particularly suitable for modelling complex systems with known input-output data sets. Such systems can be efficient in modelling non-linear, complex and ambiguous behaviour of cement-based materials undergoing single, dual or multiple damage factors of different forms (chemical, physical and structural). Due to the well-known complexity of sulfate attack on cement-based materials, the current work investigates the use of ANFIS to model the behaviour of a wide range of self-consolidating concrete (SCC) mixture designs under various high-concentration sodium sulfate exposure regimes including full immersion, wetting-drying, partial immersion, freezing-thawing, and cyclic cold-hot conditions with or without sustained flexural loading. Three ANFIS models have been developed to predict the expansion, reduction in elastic dynamic modulus, and starting time of failure of the tested SCC specimens under the various high-concentration sodium sulfate exposure regimes. A fuzzy inference system was also developed to predict the level of aggression of environmental conditions associated with very severe sodium sulfate attack based on temperature, relative humidity and degree of wetting-drying. The results show that predictions of the ANFIS and fuzzy inference systems were rational and accurate, with errors not exceeding 5%. Sensitivity analyses showed that the trends of results given by the models had good agreement with actual experimental results and with thermal, mineralogical and micro-analytical studies.

Dynamic Viscoelasticity and Optical Properties of Poly(carbonate-g-styrene) Copolymers in the Glass Transition Zone (Poly(carbonate-g-styrene)공중합체의 유리정이 영역에서의 동적 점탄성과 광학특성)

  • 황의정
    • The Korean Journal of Rheology
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    • v.9 no.4
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    • pp.163-173
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    • 1997
  • Polystyrene/polycarbonate 조성이 약 50/50인 3종류의 Poly(carbonate-g-styrene) 공중합체의 동적 탄성율, E*($\omega$)와 동적 스트레인-광학계수 O*($\omega$)을 유리전이 영역부근의 여러온도에서 동시에 측정하여 연구하였다. 두 개의 공중합체는 각각의 스티렌 그라프트쇄 에 5, 10 wt%의 MAH를 함유하고 있다. 이들 공중합체의 E*($\omega$)와 O*($\omega$)완화거동과 그라 프트 공중합체의 상용성과 연관하여 비교 고찰하였다. 공중합체들의 E*($\omega$)는 전형적인 무 정형 고분자의 유리전이 완하거동을 보였으며 정성적인 차이를 발견할수 없었다. 그러나 고 강도의 단일 tan$\delta$분산의 저주파수 영역에 미세분산을 나타내, 공중합체는 2상으로 분리되 어 있음이 추정되엇다. 폴리스티렌 그라프트체에 무수 말레인산 함유량이 증가함에 따라, 저 주파수 영역의 미세피크가 $\alpha$주분산에 병합되어 성분 고분자간의 상호 형동성이 증가함을 알수 있었다. 3공중합체의 유사한 기계적 특성과는 달리, 광학적 완화 스펙트럼 O*($\omega$)는 정 성적으로 명확한 차이를 보여 공중합체들의 광학완화 거동이 명확히 다름을 나타냈다. 기계 적 특성보다는 광학적 특성이 공중합체내의 성분 고분자의 미세한 완하 거동에 훨씬 민감한 응답을나타냈다. 이러한 특성적인 공중합체의 O*($\omega$)차이를 공중합체의 조성단일 고분자 PS, PC의 O*($\omega$)의 가성성을 가정하여 모사하였다 모사에서 구한 광학적 부분 기여 파라메 터를 사용하여 공중합체의 상용성을 고찰하였다.

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Unconfined Compressive Strength Characteristics and Time Dependent Behavior of Soil-Cement (소일시멘트의 일축압축강도 특성 및 시간의존 거동)

  • Kim, Jong-Ryeol;Kang, Hee-Bog;Kang, Hwa-Young;Kim, Do-Hyoung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.8 no.4
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    • pp.87-96
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    • 2004
  • As a special concrete, which is a mixture of soil, cement and water, has strength like regular concrete for pavement, soil cement has been used in various field such as pavement and soft soil improvement. The objective of this study was to investigate the characteristic of unconfined compressive strength and time dependent behavior of soil cement that is made from decomposed granite soil or coluvial and inorganic solidification liquid. The results showed that the unconfined compressive strength appears to increase as the amount of cement and curing time increase In addition, the strength seems to decrease with increase of the potion of fine particles(No 200 sieve). The result of XRD indicated that there is Vermiculite, the product of reaction, in the soil cement. The dynamic properties of material, such as shear complex compliance, shear complex modulus, and phase angle could be calculated from the hysteresis loop obtained from the Haversine Creep Tests. Finally, creep behavior was able to be predicted from these dynamic properties.

Analysis for Residual Twisting Moment in a Steel Cord during Twisting Wires (와이어의 연선공정시 스틸 코드에서의 잔류 비틀림 모멘트의 해석)

  • Lee, Gyu-Nam;Lee, Hyeong-Man;Kim, Gi-Tae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.2 s.173
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    • pp.403-410
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    • 2000
  • The effects of various factors were studied on the process of a steel cord by twisting wires. To remove residual twisting moment after the steel cord process, the twisting angles of residual elasti c twisting and overtwisting were measured and compared with finite element results. The agreement between experimental data and finite element calculations was good for the angles of residual elastic twisting and over-twisting. The stress distributions in a steel cord under complex loading conditions were also obtained by using the finite element analysis.