• Title/Summary/Keyword: Complex layer

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Memristive Devices Based on RGO Nano-sheet Nanocomposites with an Embedded GQD Layer (저결함 그래핀 양자점 구조를 갖는 RGO 나노 복합체 기반의 저항성 메모리 특성)

  • Kim, Yongwoo;Hwang, Sung Won
    • Journal of the Semiconductor & Display Technology
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    • v.20 no.1
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    • pp.54-58
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    • 2021
  • The RGO with controllable oxygen functional groups is a novel material as the active layer of resistive switching memory through a reduction process. We designed a nanoscale conductive channel induced by local oxygen ion diffusion in an Au / RGO+GQD / Al resistive switching memory structure. A strong electric field was locally generated around the Al metal channel generated in BIL, and the local formation of a direct conductive low-dimensional channel in the complex RGO graphene quantum dot region was confirmed. The resistive memory design of the complex RGO graphene quantum dot structure can be applied as an effective structure for charge transport, and it has been shown that the resistive switching mechanism based on the movement of oxygen and metal ions is a fundamental alternative to understanding and application of next-generation intelligent semiconductor systems.

Neighborhood coreness algorithm for identifying a set of influential spreaders in complex networks

  • YANG, Xiong;HUANG, De-Cai;ZHANG, Zi-Ke
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.11 no.6
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    • pp.2979-2995
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    • 2017
  • In recent years, there has been an increasing number of studies focused on identifying a set of spreaders to maximize the influence of spreading in complex networks. Although the k-core decomposition can effectively identify the single most influential spreader, selecting a group of nodes that has the largest k-core value as the seeds cannot increase the performance of the influence maximization because the propagation sphere of this group of nodes is overlapped. To overcome this limitation, we propose a neighborhood coreness cover and discount heuristic algorithm named "NCCDH" to identify a set of influential and decentralized seeds. Using this method, a node in the high-order shell with the largest neighborhood coreness and an uncovered status will be selected as the seed in each turn. In addition, the neighbors within the same shell layer of this seed will be covered, and the neighborhood coreness of the neighbors outside the shell layer will be discounted in the subsequent round. The experimental results show that with increases in the spreading probability, the NCCDH outperforms other algorithms in terms of the affected scale and spreading speed under the Susceptible-Infected-Recovered (SIR) and Susceptible-Infected (SI) models. Furthermore, this approach has a superior running time.

Characteristics of Ozone Advection in Vertical Observation Analysis Around Complex Coastal Area (연직관측자료를 통한 복잡 연안지역의 오존 이류특성)

  • Lee, Hwa-Woon;Park, Soon-Young;Lee, Soon-Hwan;Leem, Heon-Ho
    • Journal of Korean Society for Atmospheric Environment
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    • v.25 no.1
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    • pp.57-74
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    • 2009
  • In order to clarify the vertical ozone distribution in planetary boundary layer of coastal area with complex terrain, an observation campaign was carried out around Gwangyang Bay with dense pollutant emission sources during two days from June, 4 2007. For this observation are Radiosonde, SODAR(SOnic Detection And Ranging) and Tethered ozone sonde were employed. The surface meteorological and photochemical observation data provided by AWS (Automatic Weather System) and AQMS (Air Quality Monitoring System) were also applied for analysis. Synoptic condition is strongly associated with lower level ozone distribution in complex terrain coastal area. Since mesoscale circulation induced by difference of characteristics of land and sea and orographic forcing is predominant under calm synoptic condition, vertical distribution of ozone is complicate and vertical ozone concentration greatly fluctuated. However in second day when synoptic influence become strong, ozone concentration in lower levels is vertically uniform regardless of observation level. This results in vertical observation indicates that vertical ozone distribution is often determined by synoptic condition and also affects surface ozone concentration.

Chemical Reactivity of N-Iodopyridinium Dichlorodate as a Lubricant Additive (潤滑添加劑로서의 N-Iodopyridinium Dichlorodate의 화학반응성)

  • Moon Tak Jin;Kwon Oh Seung
    • Journal of the Korean Chemical Society
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    • v.19 no.1
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    • pp.43-49
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    • 1975
  • Small amounts of iodine compound in mineral oils are usually effective in reducing friction of metallic surfaces. Such improvement in frictional behaviour of wear characteristics was explained by the formation of a diiodide layer lattice structure at the metallic contact surfaces. The lubrication mechanism, however, by which organoiodine compounds functions is not based on the formation of such lattice structure iodide. It was tested and shown, by a static surface chemical reactivity test, wear and EP tests, and a hot wire method, that compound such as N-iodopyridinium dichlorodate, a double charge transfer complex, reacted with metals as an interhalogen compound and that the resultant thin film product reduced appreciable the friction of metallic surfaces, more than compounds such as methyl iodide, diiodomethane, and iodoform. These results suggest that the action of iodine, included in organoiodine compounds, is not that of a classical layer structure iodide, and an entirely new mechanism may be derived from a further studies on charge transfer complex compounds of organoiodine compounds.

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Spectrophotometric Determination of Antihistamines by Using Metal Indicators NN, EBT and Calcon as Color Developing Agents. (항 히스타민제의 흡광광도정량법)

  • 옥지원
    • YAKHAK HOEJI
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    • v.18 no.2
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    • pp.133-144
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    • 1974
  • The metal indicator, acidic azo dyes NN, EBT and Calcon are utilized to analyse quantitatively chlorpheniramine, tripelenamine and diphenhydramine forming insoluble ion pair in aqueous solution at proper pH values between the acidic azo dyes and the sample molecules, these compexes are extracted by organic polar solvents, and organic layer is determined spectrophotometrically. Generally, the absorption maxima of the complexes are shifted to longer wavelengths compare to the absorption maxima of the dyes themselves. The binding ratio of the ion pair forming complex molecules in chloroform soln, are as follows ; NN-antihistamines (chlorpheniramine, tripelennamine, diphenhydramine) are NN-1 to antihisamine-1, EBT-antihistamines are EBT-2 to antithistamines a and Calcon-antihistamines are Calcon-3 to antithistamines-1. These coomplexes in chloroform soln. are very stable, and show higher absorbance than the other organic polar solvents. The binding state of complexes were presumed intermolecular hydrogen bond by their infrared spectra. In the mixture solution of three samples, the aqueous phase is buffered at pH 1.0, and benzene is used to extract ion pair of diphenhydramine EBT complex selectively. At pH 1.0 of aqueous layer, Calon-diphenhydramine complex is also extracted selectively by benzene. However, in this case very small amount of chlorpheniramine-calcon calcon simultaneously. The binding state of diphenhydramine-EBT and diphenhydramine-calcon in benzene are smae as the complexes in chloroform. But the absorption maxima of the complexes in benzene are shifted to shorter wavelenlgths than the complexes in chloroform.

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Resource Allocation Strategy of Internet of Vehicles Using Reinforcement Learning

  • Xi, Hongqi;Sun, Huijuan
    • Journal of Information Processing Systems
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    • v.18 no.3
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    • pp.443-456
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    • 2022
  • An efficient and reasonable resource allocation strategy can greatly improve the service quality of Internet of Vehicles (IoV). However, most of the current allocation methods have overestimation problem, and it is difficult to provide high-performance IoV network services. To solve this problem, this paper proposes a network resource allocation strategy based on deep learning network model DDQN. Firstly, the method implements the refined modeling of IoV model, including communication model, user layer computing model, edge layer offloading model, mobile model, etc., similar to the actual complex IoV application scenario. Then, the DDQN network model is used to calculate and solve the mathematical model of resource allocation. By decoupling the selection of target Q value action and the calculation of target Q value, the phenomenon of overestimation is avoided. It can provide higher-quality network services and ensure superior computing and processing performance in actual complex scenarios. Finally, simulation results show that the proposed method can maintain the network delay within 65 ms and show excellent network performance in high concurrency and complex scenes with task data volume of 500 kbits.

Long term life-time of electrochromic poly (3-hexyl thiophene) films modified by surfactant-assisted graphene oxide layers. (계면활성제 기반 산화그래핀층이 도입된 전기변색 poly (3-hexyl thiophene) 박막의 장기 수명 특성)

  • Kim, Tae-Ho;Choe, Gi-In;Kim, Hye-Ri;O, Seong-Hyeon;Gu, Ja-Seung;Na, Yun-Chae
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.147-147
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    • 2016
  • In general, organic electrochromic (EC) materials have been known to be electrochemically unstable during the ionic exchange process. One effective method to realize stable EC materials is incorporating graphene derivatives in the polymer matrix, by using the strong interaction between graphene derivatives and polymer. However, previous studies are limited graphene derivatives. In this study, we developed a polymer-graphene derivative complex with the chemical assistance of a surfactant (octadecylamine, ODA). Surfactant-assisted graphene oxide (GO-ODA) was introduced as a protective layer on the electrochromic poly (3-hexyl thiophene) (P3HT) films by the Langmuir-Schaefer method. The deposition of GO-ODA protective layer with high coverage was confirmed by atomic force microscopy. The strong interactions between GO-ODA and P3HT were examined with UV-Vis spectrophotometry and X-ray photoelectron spectroscopy. Electrochemical and electrochromic investigations revealed that the GO-ODA layer greatly improved the long-term cyclability of the P3HT film. These findings imply that the GO-ODA complex has a significant role in creating stable EC cycling, due to its strong interaction with the P3HT film.

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Rate Capability of Electric Double-Layer Capacitor (EDLC) Electrodes According to Pore Length in Spherical Porous Carbons

  • Ka, Bok-H.;Yoon, Song-Hun;Oh, Seung-M.
    • Journal of the Korean Electrochemical Society
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    • v.10 no.4
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    • pp.252-256
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    • 2007
  • A series of spherical porous carbons were prepared via resorcinol-formaldehyde (RF) sol-gel polymerization in the presence of cationic surfactant (CTAB, cetyltrimethylammonium bromide), wherein the carbon sphere size was controlled by varying the CTAB introduction time after a pre-determined period of addition reaction (termed as "pre-curing"). The sphere size gradually decreases with an increase in the pre-curing time within the range of 30-150 nm. The carbons possess two types of pores; one inside carbon spheres (intra-particle pores) and the other at the interstitial sites made by carbon spheres (inter-particle pores). Of the two, the surface exposed on the former was dominant to determine the electric double-layer capacitor (EDLC) performance of porous carbons. As the intra-particle pores were generated inside RF gel spheres by gasification, the pore diameter was similar for all these carbons, thereby the pore length turned out to be a decisive factor controlling the EDLC performance. The charge-discharge voltage profiles and complex capacitance analysis consistently illustrate that the smaller-sized RF carbons deliver a better rate capability, which must be the direct result of facilitated ion penetration into shorter pores.

Refined numerical simulation in wind resource assessment

  • Cheng, Xue-Ling;Li, Jun;Hu, Fei;Xu, Jingjing;Zhu, Rong
    • Wind and Structures
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    • v.20 no.1
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    • pp.59-74
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    • 2015
  • A coupled model system for Wind Resource Assessment (WRA) was studied. Using a mesoscale meteorological model, the Weather Research and Forecasting (WRF) model, global-scale data were downscaled to the inner nested grid scale (typically a few kilometers), and then through the coupling Computational Fluid Dynamics (CFD) mode, FLUENT. High-resolution results (50 m in the horizontal direction; 10 m in the vertical direction below 150 m) of the wind speed distribution data and ultimately refined wind farm information, were obtained. The refined WRF/FLUENT system was then applied to assess the wind resource over complex terrain in the northern Poyang Lake region. The results showed that the approach is viable for the assessment of wind energy.

Electrical Characteristics of Organic Light Emitting Diodes (OLED) using the Alkali Metal Complex as New Electron Injection Layers (알칼리 금속 전자 주입층을 사용한 유기 전기 발광 소자 (OLED)의 전기적 특성)

  • Lee, Hyun-Koo;Kim, Jun-Ho;Kim, Young-Kwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1015-1018
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    • 2004
  • We investigate the influence of the New Electron Injection Layers (EIL) on the performance of the Alkali Metal Complex vapor-deposited Organic Light Emitting Diodes(OLED). Two different Alkali Metal Complex were used; Lithium Quinolate (Liq), and Sodium Quinolate (Naq). In all cases, $Alq_3$ was the Electron Transporting Layer (ETL). We measure and compare the current density-voltage (J-V) and luminance-voltage (L-V) characteristics. We concluded that the turn-on voltage, and luminance efficiency are controlled by the type of EIL material used. We show the longer life-time OLED with Alkali Metal Complex EIL than OLED with LiF EIL. And we show the Optimized Alkali Metal Complex thickness is 3nm. Existent LiF to because is inorganic material, there is trouble to do epitaxy into thin layers but regulates the thickness in case of Alkali Metal Complex matter characteristic that is easy be. Alkali Metal Complex also appeared by sensitive thing in thickness than LiF If utilize this material, It is thought much advantages may be at common use of OLED.

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