• 제목/요약/키워드: Complex dielectric constant

검색결과 131건 처리시간 0.026초

유기 발광 다이오드의 유전분극에 관한 연구 (A Study on the Dielectric Polarization of Organic Light-Emitting Diodes)

  • 오용철;정동회;신철기;김진사;김기준;김상진;김충혁;김태완
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.490-491
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    • 2007
  • We have investigated dielectric polarization in organic light-emitting diodes using 8-hydroxyquinoline aluminum$(Alq_3)$ as an electron transport and emissive material. We analyzed the dielectric polarization of organic light emitting diodes using impedance. Impedance characteristics was measured complex impedance Z and phase ${\theta}$ in the frequency range of 40Hz to $10^8Hz$. We obtained dielectric constant and loss tangent (tan ${\delta}$) of the device. From these analyses, we are able to interpret a dielectric dispersion and dielectric absorption contributed by an interfacial and orientational polarization.

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$C_{22}$-Quinolium(TCNQ) LB 막의 주파수에 따른 전기적 특성 (Electrical Properties of $C_{22}$-Quinolium(TCNQ) Langmuir-Blodgett Films Depending on the Frequency)

  • 이삼국;유덕선;김태완;김영관;권명수;강도열
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1994년도 하계학술대회 논문집 C
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    • pp.1289-1291
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    • 1994
  • Dielectric properties of $C_{22}$-Quinolium(TCNQ) Langmuir-Blodgett (LB) films were studied as a function of frequency(10Hz-13MHz) and annealing temperature($20{\sim}240^{\circ}C$). A complex dielectric constant ${\epsilon}^*={\epsilon}'-i{\epsilon}"$, in general, shows the frequency dependence of orientational polarization in the measured frequency range. A dielectric permittivity ${\epsilon}'$ at 10Hz is around 8.2 and decreases very slowly as the frequency increases up to 1 MHz, and then suddenly drops above this frequency, while a dielectric loss factor ${\epsilon}"$ reaches a maximum near 1 MHz. Its annealing temperature dependence at 10Hz shows that ${\epsilon}'$ and ${\epsilon}"$ increase as the temperature increases upto $180^{\circ}C$, even though there is a little drop near $120{\sim}160^{\circ}C$. Both ${\epsilon}'$ and ${\epsilon}"$ drop quickly above $180^{\circ}C$. which may be thought of a destruction of the LB films. Another fact of the annealing temperature dependence of the dielectric constant is an occurrence of the new dielectric dispersion below 100Hz. This low frequency dispersion is getting clear above $80^{\circ}C$.

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펄스 레이저 증착법으로 제작된 Bi2O3-MgO-ZnO-Nb2O5 박막의 제작 및 특성 분석 (Fabrication and Characterization of Bi2O3-MgO-ZnO-Nb2O5 Thin Films by Pulsed Laser Deposition)

  • 배기열;이동욱;;이원재;배윤미;신병철;윤순길
    • 한국전기전자재료학회논문지
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    • 제23권3호
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    • pp.211-215
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    • 2010
  • Pulsed laser deposition is a very efficient technique for fabricating thin films of complex compounds. In the present work, $Bi_2O_3$-MgO-ZnO-$Nb_2O_5$ (BMZN) pyrochlore thin films were deposited on platinized Si substrates at various temperatures by using pulsed laser deposition technique. These films have been characterized by X-ray diffractometer (XRD), atomic force microscopy (AFM) to investigate their structural, morphological properties. MIM structure was manufactured to analyze di-electrical properties of BMZN thin films. XRD results reveal the thin films deposited at less than $400^{\circ}C$ show only amorphous phase, the crystallized thin films was observed when the thin films were prepared temperature at above $500^{\circ}C$. From AFM, it was known that the thin film grown at $400^{\circ}C$ is the densest. Dielectric constant increased with increasing temperature up to $400^{\circ}C$ at 100 kHz and dramatically decreased at the higher temperature. A aspect of dissipation factor was the exact opposite of dielectric constant. BMZN thin films grown at $400^{\circ}C$ exhibited a high dielectric constant of 60.9, a low dissipation factor of 0.007 at 100 kHz.

Microwave Absorbance of Polymer Composites Containing SiC Fibers Coated with Ni-Fe Thin Films

  • Liu, Tian;Kim, Sung-Soo;Choi, Woo-cheal;Yoon, Byungil
    • 한국분말재료학회지
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    • 제25권5호
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    • pp.375-378
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    • 2018
  • Conductive and dielectric SiC are fabricated using electroless plating of Ni-Fe films on SiC chopped fibers to obtain lightweight and high-strength microwave absorbers. The electroless plating of Ni-Fe films is achieved using a two-step process of surface sensitizing and metal plating. The complex permeability and permittivity are measured for the composite specimens with the metalized SiC chopped fibers dispersed in a silicone rubber matrix. The original non-coated SiC fibers exhibit considerable dielectric losses. The complex permeability spectrum does not change significantly with the Ni-Fe coating. Moreover, dielectric constant is sensitively increased with Ni-Fe coating, owing to the increase of the space charge polarization. The improvements in absorption capability (lower reflection loss and small matching thickness) are evident with Ni-Fe coating on SiC fibers. For the composite SiC fibers coated with Ni-Fe thin films, a -35 dB reflection loss is predicted at 7.6 GHz with a matching thickness of 4 mm.

Dielectric and Electrical Characteristics of Lead-Free Complex Electronic Material: Ba0.8Ca0.2(Ti0.8Zr0.1Ce0.1)O3

  • Sahu, Manisha;Hajra, Sugato;Choudhary, Ram Naresh Prasad
    • 한국재료학회지
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    • 제29권8호
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    • pp.469-476
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    • 2019
  • A lead-free bulk ceramic having a chemical formula $Ba_{0.8}Ca_{0.2}(Ti_{0.8}Zr_{0.1}Ce_{0.1})O_3$ (further termed as BCTZCO) is synthesized using mixed oxide route. The structural, dielectric, impedance, and conductivity properties, as well as the modulus of the synthesized sample are discussed in the present work. Analysis of X-ray diffraction data obtained at room temperature reveals the existence of some impurity phases. The natural surface morphology shows close packing of grains with few voids. Attempts have been made to study the (a) effect of microstructures containing grains, grain boundaries, and electrodes on impedance and capacitive characteristics, (b) relationship between properties and crystal structure, and (c) nature of the relaxation mechanism of the prepared samples. The relationship between the structure and physical properties is established. The frequency and temperature dependence of the dielectric properties reveal that this complex system has a high dielectric constant and low tangent loss. An analysis of impedance and related parameters illuminates the contributions of grains. The activation energy is determined for only the high temperature region in the temperature dependent AC conductivity graph. Deviation from the Debye behavior is seen in the Nyquist plot at different temperatures. The relaxation mechanism and the electrical transport properties in the sample are investigated with the help of various spectroscopic (i.e., dielectric, modulus, and impedance) techniques. This lead free sample will serve as a base for device engineering.

FR-4 composite 기판의 성부 구성비에 따른 광대역 유전상수 모델 및 전송 특성 해석 (Wideband dielectric modeling and transmission analysis of FR-4 composite substrate with different composition ratio)

  • 홍정기;김성일;이해영
    • 전자공학회논문지A
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    • 제33A권12호
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    • pp.33-38
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    • 1996
  • In this paper, we modeled the complex dielectric constant and analyzed the projpagation characteristics of a FR-4 composite substrate with different compositions. From the wideband dielectric modeling and the propagation loss analysis of FR-4 composites that consists of FR-4 resin and E-glass reinforcement,we have found that the propagation loss and velocity increase with the volume fraction of FR-4 resin above 1 GHz. These results are helpful in determining to deisgn optimum substrate composition ratio and cross-sectional geometry of high-speed and high-density transmission line.

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BZCT 세라믹의 마이크로파 특성에 관한 연구 (Microwave Dielectric Properties of BZCT Ceramics)

  • 이문기;최의선;류기원;이영희
    • 한국전기전자재료학회논문지
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    • 제15권10호
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    • pp.870-875
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    • 2002
  • Ba(Zn$_1$-xCox)TaO$_3$[BZCT] ceramics were Prepared by the conventional mixed oxide method. The ceramics were sintered at the temperature of 1450∼1550$\^{C}$ for 5 hr in air. The crystal structure of BZCT ceramics was investigated by the XRD. The microstructure of the specimens were observed by SEM. The structural properties of BZCT specimens were investigated as a function of composition and sintering temperature. All BZCT ceramics sintered over 1550$\^{C}$ were showed a polycrystalline complek perovskite structure without second phases and any unreacted materials. The density of BZCT (70/30) specimen sintered at 1550$\^{C}$ was 6.31g/㎤. In the case of the BZCT(70/30) ceramics sintered at 1550$\^{C}$ for 5 hours, dielectric constant, qualify factor and temperature coefficient of resonant frequency for microwave dielectrics application were a good value of 29, 16,468 at 10㎓ and -4.4 ppm/$\^{C}$, respectively.

분말재료의 복소 유전율 및 투자율 측정 (Measurement of Complex Permittivity and Permeability for Powder-type Materials)

  • 박상복;이장수;정용식;천창율
    • 전기학회논문지
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    • 제56권12호
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    • pp.2196-2201
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    • 2007
  • Materials used at microwave are usually used as a dielectric with a manufacturing purpose of printed circuit boards, etc. Complex permittivity of them can be measured from attenuation constant or propagation constant of a transmission line using a microstrip line with bulk type. But as the technique recently which can manufacture to have complex permittivity and permeability demanded using nonferrous metals for powder-type grows up, we need sensors and methods which can measure characteristics of powder-type materials. So far measuring methods of permittivity and permeability with waveguide or coaxial cable are used but they have faults which have a complex measurement method and are difficult to simultaneously measure permittivity and permeability. In this paper, a simultaneous measuring method of permittivity and permeability with 2-port coaxial cable and a new proposed calculation. The proposed 2-port coaxial cable is designed to be easy to insert materials and to have a wideband. We measure permittivity and permeability of magnetic powder(Ni-Fe-Mo, Ni-Fe) which reveal its characteristic at $0.3{\sim}1.3GHz$ to identify the proposed sensor.

Dielectric Relaxation in Ethylene Glycol - Dimethyl Sulfoxide Mixtures as a Function of Composition and Temperature

  • Undre, P.B.;Khirade, P.W.;Rajenimbalkar, V.S.;Helambe, S.N.;Mehrotra, S.C.
    • 대한화학회지
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    • 제56권4호
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    • pp.416-423
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    • 2012
  • Using time domain reflectometry, the complex dielectric spectra between 10 MHz to 20 GHz has been measured in the whole composition range at 10, 20, 30 and $40^{\circ}C$ for the binary mixtures of ethylene glycol and dimethyl sulfoxide. For all the mixtures, only one dielectric loss peak was observed in this frequency range. The relaxation in these mixtures can be described by a single relaxation time using the Debye model. A systematic variation is observed in dielectric constant (${\varepsilon}_0$) and relaxation time (${\tau}$). The excess permittivity (${\varepsilon}^E$), excess inverse relaxation time $(1/{\tau})^E$, Kirkwood correlation factor (g) and thermodynamic parameters viz. enthalpy of activation (${\Delta}H$) and Gibbs free energy of activation (${\Delta}G$) have been determined, to confirm the formation of hydrogen bonded homogeneous and heterogeneous cooperative domains, the dynamics of solute - solute interaction and the hindrance to molecular rotation in the hydrogen bonded glass forming ethylene glycol - dimethyl sulphoxide system.

고주파에서의 카본 블랙/에폭시 복합재료 복소유전율 모사에 대한 연구 (A Study on the Simulation of Complex Permittivities of Carbon Black/Epoxy Composites at a High Frequency Band)

  • 김태욱;김천곤;김진봉
    • Composites Research
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    • 제18권3호
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    • pp.14-20
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    • 2005
  • 본 논문에서는 카본 블랙/에폭시 복합재료 적층판의 유전율에 대한 연구를 수행하였다. 유전율 측정은 $1\;GHz\~18\;GHz$의 주파수 영역에서 수행하였으며, 복합재료의 유전율은 카본 블랙 함유율의 주파수의 함수로 얻을 수 있었다. 유전율 및 전기 전도도의 주파수 특성은 Percolation 이론에서 제시된 경향을 만족하였다. 측정에 사용된 주파수 영역은 전기 전도도가 주파수의 함수관계를 가지는 최소 주파수인 임계주파수보다 크며, 복합재료의 유전율과 전기 전도도는 카본 블랙의 함유량과 일정한 관계를 가졌다. 본 연구에서는, 카본 블랙의 함유율에 따른 복합재료의 유전율을 모사하는 혼합법칙을 얻기 위하여 Lichteneker-Rother 방정식에 기초한 새로운 방법이 제시되었으며, 혼합법칙으로 계산된 복합재료 유전율 모사 결과는 실험적으로 얻은 유전율을 비교적 잘 모사하는 결과를 얻을 수 있었다.