• Title/Summary/Keyword: Complex Viscosity

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A Experimental Study on the Complex Waterproofing Method of Exposure using PE Textiles of Mesh type and Highly Viscous Urethane (망사형 PE직물과 고점도 우레탄을 이용한 복층형 노출 방수공법에 관한연구)

  • Shao, Xu-Dong;Song, Je-Young;Kim, Young-Suk;Oh, Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.05a
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    • pp.127-130
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    • 2011
  • The duplex waterproofing construction method has been investigated to improve various problems (how to fix the sheet, breaking, air/water pocket, and cracks caused by different materials) of the existing rooftop exposed waterproofing construction method. By using fiber sheet, Net PE fabric, and thixotropy urethane with high viscosity, the waterproofing construction method is to glue the ground and waterproof course by circular dot. The method is also to construct the waterproof course with high hardness by using waterproof membrane coatings in upper hybrid system. By gluing the ground and the waterproof course by circular dot, the study is expected to be useful to minimize the simultaneous breaking in the waterproof course as tensile stress is buffer in case of the ground crackling. Also, since the waterproofing construction method is good at moving and emitting vapor from the ground, it is considered to be effective to minimize any damages caused by air/water pocket and get loose of the waterproof course.

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Effects of Transglutaminase on Pasting and Rheological Properties of Different Wheat Cultivars Blended with Barley or Soy Flour

  • Ahn, Hyun-Joo;Kim, Jae-Hyun;Chang, Yoon-Hyuk;Steffe, James F.;Ng, Perry K.W.;Park, Hee-Ra
    • Food Science and Biotechnology
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    • v.17 no.1
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    • pp.52-57
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    • 2008
  • The effects of transglutaminase (TG) on the pasting and rheological properties of different wheat cultivars ('Sharpshooter', 'Russ', and 'AcAriss') blended with barley (40%) or soy (20%) flour were investigated. In the rapid visco-analyzer (RVA) pasting profile, the addition of barley or soy flour to wheat flour samples induced a decrease in peak, trough, final viscosity, breakdown and setback values. However, TG treatment of these blends significantly increased peak viscosity and breakdown (p<0.05). In particular, TG treatment greatly increased the breakdown of wheat flour blended with soy flour, indicating that the cross-linking of proteins through TG may somehow be related to an increase in starch granule rupturing in pastes. Storage (G') and loss (G") moduli of the sample pastes increased with an increase in frequency ($\omega$), while complex viscosity (${\eta}*$) decreased. In all wheat cultivars, G', G", and $\eta$ were decreased by the addition of barley or soy flour, or TG treatment. Results suggest that protein cross-linking by TG can produce unique and improved properties in wheat flours blended with barley or soy flour.

Changes of Microstructure and Properties of Manufactured Modified Pitches via Pressure Changes during Heat Treatments in Coal Tar Pitch (석탄계 타르의 열처리 중 압력변화에 따른 변성 콜타르 핏치의 미세구조 및 물성 변화)

  • Ko, Hyo Joon;Chung, Sung Mo;Han, Ji Hoon;Park, Chang Uk;Kim, Myung-Soo;Lim, Yun-Soo
    • Korean Journal of Materials Research
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    • v.24 no.6
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    • pp.293-300
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    • 2014
  • Coal-tar pitch, a feedstock which can be heat-treated to create graphite, is composed of very complex molecules. Coal-tar pitch is a precursor of many useful carbon materials (e.g., graphite, carbon fibers, electrodes and matrices of carbon/carbon composites). Modified coal-tar pitch (MCTP) was prepared using two different heat-treatment methods and their properties were characterized and compared. One was prepared using heat treatment in nitrogen gas; the other was prepared under a pressure of 350 mmHg in air. The MCTPs were investigated to determine several properties, including softening point, C/H ratio, coke yield, formation of anisotropic mesophase and viscosity. The MCTPs were subject to considerable changes in chemical composition due to condensation and polymerization in the used-as-received coal-tar pitch after heat-treatment under different conditions. The MCTPs showed considerable increases in softening point, C/H ratio, and coke yield, compared to those of as-received coal-tar pitch. The MCTP formed by heat-treatment in nitrogen showed isotropic phases below $350^{\circ}C$ for 1 h of soaking time. However, MCTP heat-treated under high pressure (350 mmHg) showed isotropic phases below $300^{\circ}C$, and showed anisotropic phases above $350^{\circ}C$, for 1 h of soaking time. The viscosity of the MCTPs increased with increase in their softening points.

A Study on the Rheological Behavior Properties of Short-term Aged Asphalt Binder (단기노화 된 아스팔트 바인더의 유변학적 거동 특성에 관한 연구)

  • Park, Tae-Soon
    • International Journal of Highway Engineering
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    • v.7 no.4 s.26
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    • pp.203-210
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    • 2005
  • The penetration and viscosity tests have been used for the evaluation of the aged asphalt binder performance change. The improved test method has been required because the conventional tests could not evaluate the viscoelastic characteristics and the real behaviour of the aged asphalt binder. The conventional test methods using a different short term aged asphalt binder were tested and the test results were expressed as the penetration index and the residual penetration. The oscillatory and rotational mode tests were performed to find out the rheological characteristics of the short term aged asphalt binder in this study. The test results showed that the change of testing frequency, the speed of the vehicle effects the complex modules and phase angles. The creep compliance and shear viscosity also showed the different test results when the short term aged asphalt binders were tested. The rheological behavior should consider when the pavement design is conducted.

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Optimization of Demucilage Process of Opuntia ficus-indica var. saboten Fruit using High Hydrostatic Pressure Enzyme Dissolution (고압 효소 액화 장치를 이용한 백년초 점질물 분해 공정의 최적화)

  • Im, Sungbin;Lee, Hyungjae;Shim, Jae-Yong;Kim, Tae-Rahk;Kim, Dae-Ok
    • KSBB Journal
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    • v.30 no.2
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    • pp.63-68
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    • 2015
  • This study aimed to develop and optimize a demucilaging process of Opuntia ficus-indica var. saboten (OFI) fruit to increase its usability as functional food ingredient and food additive. Viscozyme and Novozym 33095 as multienzyme complex having a broad spectrum of carbohydrases and pectolytic enzymes, respectively, were used in enzymatic dissolution along with high hydrostatic pressure liquefaction. To optimize the liquefaction process using high hydrostatic pressure liquefying extractor, response surface methodology with 3-factor central composite design was employed with reaction factors such as temperatures (25, 32, 40, 48, and $55^{\circ}C$), pressures (20, 40, 60, 80, and 100 MPa), and times (15, 30, 45, 60, and 75 min). At optimum conditions ($25^{\circ}C$, 100 MPa, and 58.275 min) for high hydrostatic pressure liquefaction process, the processed OFI fruit juice was predicted to have viscosity at 2.917 poise, partly due to the release of free sugars such as fructose and glucose detected using HPLC-ELSA system. The results above suggests that the OFI fruit juice with decreased viscosity may be used for various manufacturing processes of food, beverage, ice cream, and cosmetics.

Correlation of morphological changes of rice starch granules with rheological properties during heating In excess water (가열 조리시 쌀 전분 입자들의 형태학적 변화와 리올로지 특성과의 관계)

  • Lee, Young-Eun;Osman, Elizabeth M.
    • Applied Biological Chemistry
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    • v.34 no.4
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    • pp.379-385
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    • 1991
  • Morphological changes of starch granules from 12 different varieties of rice were examined by scanning electron microscopy during heating at 2.5% (w/v) concentration. Rice starch granules proceeded through a similar pattern of progressive morphological changes daring heating, regardless of variety. Rice starch granules began to swell radially in the initial stage of gelatinization and then undergo radial contraction and random tangential expansion to form complex structures in the latter stage of gelatinization temperature range. At higher temperatures, starch granules softened and melted into thin flat discs, and then stretched into thin filaments to form three-dimensional networks. These progressive morphological changes were reflected in the changes of swelling power, solubility and amylograph viscosity of starch. During the transition of melting or softening, swelling power, solubility and amylograph viscosity increased rapidly. The time of loss of granular structure of starch depended on gelatinization temperature range. The ratio of amylose to amylopectin was largely responsible fur the rate of melting or softening and the fineness of a three-dimensional filamentous network above the gelatinization temperature range. Therefore, both the gelatinization temperature range and amylose content of starch affect the rate of cooking, and amylose content of starch affects the final texture of cooked starch paste.

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Study on the Fabrication of Ceramic Core using a Gel-casting Process in Aqueous medium(I) : Gelation Behavior of Polydispered Ceramic Slip (수용액 매체에서 젤-케스팅 공정을 이용한 세라믹 코어 제조에 관한 연구(I) : 다성분계 분산 세라믹 슬립의 젤화 거동)

  • Kim, Jae-Won;Kim, Du-Hyeon;Kim, In-Su;Yu, Yeong-Su;Kim, Jae-Cheol;Jo, Chang-Yong
    • Korean Journal of Materials Research
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    • v.11 no.2
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    • pp.137-145
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    • 2001
  • A new process, gelcasting in aqueous medium, to fabricate complex-shaped ceramic core has investigated. The ceramic slurry, mixture of fused silica powder and additives such as zircon and cordierite, was electrosterically stabilizes. The slip was prepared by ball milling of polydispered ceramic suspension with monomer, dimer and dispersant. The rheological behavior of slip was evaluated by viscosity measurement. It was found that the high solid loading of polydispersed ceramic slip, which has low viscosity of 50vol%, is possible to obtained. The viscosity of the slip was significantly dependent upon the amount of polymer dispersant and the formulation of monomer and dimer. The green bodies were fabricated through casting and gelation at room temperature followed by drying at $25^{\circ}C$ for 48hrs under relative humidity of 80~85%. Crack-free green body was successfully fabricated through the above process.

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Effects of Multiple Enzyme (ROVABIO® Max) Containing Carbohydrolases and Phytase on Growth Performance and Intestinal Viscosity in Broiler Chicks Fed Corn-Wheat-Soybean Meal Based Diets

  • Lee, So-Yeon;Kim, Jong-Seol;Kim, Jin-Man;An, Byoung-Ki;Kang, Chang-Won
    • Asian-Australasian Journal of Animal Sciences
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    • v.23 no.9
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    • pp.1198-1204
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    • 2010
  • This study was conducted to investigate the effects of dietary supplementation with multiple enzymes composed of phytase plus carbohydrolases (ROVABIO$^{(R)}$ Max, RM) on growth performance, nutritional availability and intestinal viscosity in broiler chicks. A total of one thousand, one-day-old male broiler chicks were randomly allotted into treatment groups that received one of five experimental diets for 32 days. Each group consisted of 40 birds and all experiments included five replicates. The dietary treatments included PC (a positive control diet), NC1 (65 kcal/kg, 0.15% and 0.10% less ME, available phosphorus and calcium levels, respectively, than the PC diet), NC2 (85 kcal/kg, 0.20% and 0.10% less ME, available phosphorus and calcium levels, respectively, than the PC diet), NC1+RM (NC1 plus ROVABIO$^{(R)}$ Max) and NC2+RM (NC2 plus ROVABIO$^{(R)}$ Max). The average body weights, daily body weight gains and feed conversion rates of the chicks fed a diet containing RM improved significantly or tended to improve. The treatments also had no effect on the carcass characteristics or blood parameters, but the viscosity of the intestinal contents of the chicks fed the diet containing RM was significantly lower than that of chicks in the NC without RM groups. Additionally, chicks fed the dietary RM showed increased breaking strength and ash content of the tibia when compared to chicks that received the non-RM diets. Taken together, the results of the present study indicated that the addition of multiple enzymes consisting of phytase plus NSP enzymes improved the growth performance and mineral status of the tibia in broiler chickens fed corn-wheat-soybean meal-based diets with reduced levels of nutrients. Further, these findings suggest that the improved animal performance is associated with reduced intestinal viscosity by the dietary enzyme complex.

Rheological Properties of Citrus Pectin Solutions (감귤류 펙틴 용액의 리올리지 특성)

  • Hwang, Jae-Kwan
    • Korean Journal of Food Science and Technology
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    • v.27 no.5
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    • pp.799-806
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    • 1995
  • The steady shear and small amplitude oscillatory dynamic rheological properties of citrus pectin $([\eta]=3.75\;dL/g)$ were characterized for a wide range of pectin concentrations $({\sim}6%)$. The typical power-law flow was observed above 2.0% concentration, and the shear rate dependence of viscosity increased with pectin concentration. The transition from dilute to concentrated regime, determined from the double logarithmic plot of ${\eta_{sp.o}}\;vs\;C[\eta]$, occurred at a critical coil overlap parameter $C^{*}[\eta]\approx4.0$, at which ${\eta_{sp.o}}$ corresponded to approximately 10.0. The slopes of ${\eta_{sp.o}}\;vs\;C[\eta]$, at $C[\eta]\;at\;C[\eta]C^{*}[\eta]$were 1.1 and 4.5, respectively. The steady viscosity $(\eta)$ displayed a good superposition at ${\eta}/{\eta}_o\;vs\;{\gamma}/{\gamma}_{0.8}$ relation with an exception of high concentration (6%), which arised from the significant deviation of flow behavior index (n values of $\eta_{a}=K\gamma^{n-1}$) at high concentration. Dynamic measurements showed that the loss modulus $(G^{\prime\prime})$ was much higher than the storage modulus $(G^\prime)$for all concentrations studied, indicating predominant viscoelastic liquid-like behavior of pectin solutions. The frequency dependence of $G^\prime$ was higher than that of $G^\prime\prime$ at the same concentration, whose trend was more pronounced with decreasing pectin concentration. The shear viscosity $(\eta)$ was almost identical to the complex viscosity $(\eta^{*})$ at low concentration, following the Cox-Merz rule, but they became increasingly different at high concentration.

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Studies on Metal Complex Formation of Poly (styrene-co-Acrylic acid) (스틸렌-아크릴산계 공중합체의 금속착물 형성에 관한 연구)

  • Kim, Kong-Soo;Kim, Soo-Jong;Cho, Suk-Hyeong;Chun, Yong-Chul
    • Applied Chemistry for Engineering
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    • v.2 no.1
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    • pp.70-76
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    • 1991
  • Water soluble poly(sulfonated styrene-co-acrylic acid) was polymerized with sulfonated styrene and acrylic acid in the presence of silver sulfate at $99^{\circ}C$ for 4 hrs. The complex formation of poly(sulfonated styrene-co-acrylic acid) with Cu(II) was carried out. The maximum absorption wavelength of the poly(sulfonated styrene-co-acrylic)-Cu(II) system at different pH values was observed at 274 nm and 295 nm. The reduced viscosity of the poly(sulfonated styrene-co-acrylic acid)-Cu(II) complex were measured in the various pH ranges. The formation constants and stability constants of poly(sulfonated styrene-co-acrylic acid)-Cu(II) complex were calculated from Bjerrum method. The changes of enthalpy, free energy and entropy in the above reaction were determined by Ringbom method.

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