• Title/Summary/Keyword: Complex Carbide

검색결과 26건 처리시간 0.031초

SHS 화학로에 의한 (Ti.W)C 복탄화물의 합성 및 기계적 특성에 관한 연구 (A Study on Synthesis and Mechanical Properties of (Ti.W)C Complex Carbide by SHS Chemical Furnace)

  • 이형복;오유근;이풍헌;장동환
    • 한국세라믹학회지
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    • 제33권4호
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    • pp.418-424
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    • 1996
  • (Ti.W)C complex carbide was synthesized by self-propagating high temperature synthesis (SHS) chemical furnace. Attempt to find the optimal condition for synthesis of (Ti.W)C the effects of molar ratio of Ti:W:C on the synthesized powders and mechanical properties were investigated, Optimum molar ratio of these synthe-sized powder was Ti:W:C=0.7:0.2:1.0 The bulk density M,O.R Hardness Fracture toughness of (Ti.W)C complex carbide sintered at 200$0^{\circ}C$ for 60 min by hot-pressing under the pressure of 20 MPa were 7.6g/cm3, 475 MPa, 17,.7 GPa respectively.

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초고온복합소재용 프리세라믹폴리머 합성 및 응용기술 (Preceramic Polymer Technology for High Temperature Ceramic Composite and its Application)

  • 이윤주;김영희;배성군;이현명;조광연;권우택;김수룡;류도형;신동근
    • Composites Research
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    • 제30권2호
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    • pp.102-107
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    • 2017
  • 프리세라믹폴리머는 기존의 세라믹 공정으로는 얻을 수 없는 다양하고 복잡한 구조의 세라믹 소재를 구현할 수 있다. 대표적인 프리세라믹폴리머인 폴리카보실란은 분자구조 제어를 통해 실리콘과 탄소의 함량비 조절이나 분자구조의 선형성을 향상시키고 분자량 및 분자량분포 제어를 통해 탄화규소섬유를 포함한 다앙한 형상/미세구조의 탄화규소 세라믹을 제조할 수 있다. 본 논문에서는 폴리카보실란의 합성 및 분자구조제어기술과 이를 용융방사 및 안정화, 열처리를 거쳐 제조되는 탄화규소섬유섬유, 그리고 PIP 공정으로 만들어지는 세라믹섬유복합소재 기술에 대하여 논하였다. 더불어 나노다공구조를 갖는 탄화규소 중공사와 같이 폴리카보실란을 이용해 구현할 수 있는 복잡구조의 탄화규소 소재 개발 예를 소개하였다.

염색슬러지 탄화물과 순환 유동층 연소 보일러 플라이애시를 활용한 무시멘트 경화체의 역학적 특성 (Mechanical Properties of Non-cement Matrix Utilizing the Circulating Fluidized Bed Combustion Boiler Fly Ash and Dyeing Sludge Carbide)

  • 김태현;이승호;이용;신진현;이상수
    • 한국건설순환자원학회논문집
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    • 제4권4호
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    • pp.425-430
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    • 2016
  • 산업의 급격한 발달과 함께 사회 또한 급격한 발달을 이루면서 전 세계는 편리한 생활을 이룰 수 있게 되었다. 하지만 이러한 산업의 발달의 이면에는 환경오염으로 인한 지구온난화와 산업부산물 대량 발생 등의 문제가 발생하고 있는 실정이다. 이에 본 연구는 건축분야에서 $CO_2$ 배출 비율이 높은 시멘트의 사용량을 줄이고자 산업부산물인 고로슬래그와 순환 유동층 연소 플라이애시를 사용하였으며, 국내 염색공단에서 배출되고 있는 20만 톤 이상의 슬러지를 재활용하는 방안을 검토하기 위해 염색슬러지 탄화물을 활용한 무시멘트 경화체의 특성에 대한 기초자료를 제시하고자 하였다. 그 결과, 염색슬러지 탄화물의 치환율이 증가함에 따라 공기량은 증가하였고 플로어는 증가하였다. 또한 염색슬러지 탄화물 치환율이 증가함에 따라 휨강도 및 압축강도는 감소하는 경향을 보였다.

Prediction of crack trajectory by the boundary element method

  • Bush, M.B.
    • Structural Engineering and Mechanics
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    • 제7권6호
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    • pp.575-588
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    • 1999
  • A boundary element method is applied to the analysis of crack trajectory in materials with complex microstructure, such as discontinuously reinforced composite materials, and systems subjected to complex loading, such as indentation. The path followed by the crack(s) has non-trivial geometry. A study of the stress intensity factors and fracture toughness of such systems must therefore be accompanied by an analysis of crack trajectory. The simulation is achieved using a dual boundary integral method in planar problems, and a single boundary integral method coupled with substructuring in axisymmetric problems. The direction of crack propagation is determined using the maximum mechanical energy release rate criterion. The method is demonstrated by application to (i) a composite material composed of components having the elastic properties of aluminium (matrix) and silicon carbide (reinforcement), and (ii) analysis of contact damage induced by the action of an indenter on brittle materials. The chief advantage of the method is the ease with which problems having complex geometry or loading (giving rise to complex crack trajectories) can be treated.

A Study of the Effect of Tungsten Oxide on W, WC Powder and Alloy Properties

  • Jiang, Cijin;Shen, Paul;Wang, Huan
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.654-655
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    • 2006
  • This is about the effects deoxidization, carbonization and alloying preparation on fine grain W, WC, and grade YG8 powder reduced by "yellow tungsten oxide" and "blue tungsten oxide". The result indicates that yellow tungsten has single composition and blue tungsten oxide has complex composition. With this feature, yellow tungsten oxide got better uniformity and concentration distribution on fine particle size W and WC powder than blue tungsten oxide's. The grade alloy YG8 that made of this W or WC powder has uniform alloy construction, concentrated WC grain distribution and better alloy properties.

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고규소 고몰리브덴 구상흑연주철의 온도 의존 특성에 미치는 규소와 몰리브덴의 영향 (Effects of Si and Mo on the Temperature-Dependent Properties of High Si High Mo Ductile Cast Irons)

  • 최경환;이상목;김명호;윤상원;이경환
    • 한국주조공학회지
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    • 제29권6호
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    • pp.257-264
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    • 2009
  • The effects of silicon and molybdenum on the temperature-dependent properties of high silicon and high molybdenum ductile cast iron were investigated. Microstructure was composed of ferrite, cell boundary complex carbide, carbide precipitated in the grain and graphite. The number and size of carbide decreased with the increase of silicon content and increased with the increase of molybdenum content, however, the size of cell boundary carbide increased above 0.81wt%Mo. The room temperature tensile strength increased with the increase of silicon and molybdenum contents. That did not increase with the latter with more than 0.8wt%. Meanwhile the high temperature tensile strength showed the similar trend to that of room temperature one, that of the specimen with 0.55wt%Mo was the highest. The $A_1$ transformation temperature increased with the silicon and molybdenum contents, and showed similar tendency with the variation of strength. It was discussed due to the solubility limit of Molybdenum in ferrite, of which value was assumed to be in the vicinity of 0.81wt%Mo. The weight after oxidation at 1,173K showed the result caused by the difference in solubility of molybdenum in the matrix. That and the thickness change after oxidation did not show any consistent trend with the silicon and molybdenum contents.

Numerical simulation of dimensional changes during sintering of tungsten carbides compacts

  • Bouvard, D.;Gillia, O.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 1997년도 추계학술강연 및 발표대회 강연 및 발표논문 초록집
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    • pp.7-7
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    • 1997
  • During sintering of very porous green bodies, as obtained by compaction of hard powders - such as tungsten carbide or ceramics - or by injection moulding, important shrinkage occurs. Due to heterogeneous green density field, gravity effects, friction on the support, thermal gradients, etc., this shrinkage is often non-uniform, which' may induce significant shape changes. As the ratio of compact dimension to powder size is very high, the mechanics of continuum is relevant to model such phenomena. Thus numerical techniques, such as the finite element method can be used to simulate the sintering process and predict the final shape of the sintered part. Such type of simulation has much been developed in the last decade firstly for hot isostatic pressing and next for die compaction. Finite element modelling has been recently applied to free sintering. The simulation of sintering should be based on constitutive equations describing the thermo-mechanical behaviour of the material under any state of stress and any temperature which may arise within the sintering body. These equations can be drawn either from experimental data or from micromechanical models. The experiments usually consist in free sintering and sinter-forging tests. Indeed applying more complex loading conditions at high temperature under controlled atmosphere is delicate. Micromechanical models describe the constitutive behaviour of aggregates of spheres from the deformation of two-sphere contact either by viscous flow or grain boundary diffusion. Such models are not able to describe complex microstructure and mechanisms as observed in real materials but they can give some basic information on the formulation of constitutive equations. Practically both experimental and theoretical approaches can be coupled to identify the constitutive equations. Such procedure has been performed for modelling the sintering of compacts obtained by die pressing of a mixture of tungsten carbide and cobalt powders. The constitutive behaviour of this material during sintering has been described by a linear viscous constitutive model, whose functions have been fitted from results of free sintering and sinter-forging experiments. This model has next been introduced in ABAQUS finite element code to simulate the sintering of heterogeneous green compacts of various geometries at constant temperature. Examples of simulations are shown and compared with experiments.

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니켈계 합금의 볼엔드밀 가공에서 절삭 방향에 따른 영향 (Analysis of Cutter Orientation when Ball Nose End Milling Nickel Based Superalloys)

  • 이득우
    • 대한기계학회논문집A
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    • 제24권10호
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    • pp.2496-2501
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    • 2000
  • High speed ball end milling is attracting interest in the aerospace industry for the machining of complex 31) airfoil surfaces in nickel based superalloys, Experimental work is detailed on the effect of cutter orientation on tool life, cutting forces, chip formation, specific force and workpiece surface roughness, when high speed ball end milling nickel based supperalloy(lnconel 718). Dry cutting was performed using 8min diameter solid carbide cutters coated with either TiA1N or CrN for the workpiece mounted at an angle of 45˚ from the cutter axis. A horizontal downwards cutting orientation provided the best tool life with cut lengths~50% longer than for all other directions. Evaluation of cutting forces and associated spectrum analysis of results indicated that cutters employed in a horizontal downwards direction produced the least vibration.