• Title/Summary/Keyword: Comparative calibration

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Classification and Performance Evaluation Methods of an Algal Bloom Model (적조모형의 분류 및 성능평가 기법)

  • Cho, Hong-Yeon;Cho, Beom Jun
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.26 no.6
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    • pp.405-412
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    • 2014
  • A number of algal bloom models (red-tide models) have been developed and applied to simulate the redtide growth and decline patterns as the interest on the phytoplankton blooms has been continuously increased. The quantitative error analysis of the model is of great importance because the accurate prediction of the red-tide occurrence and transport pattern can be used to setup the effective mitigations and counter-measures on the coastal ecosystem, aquaculture and fisheries damages. The word "red-tide model" is widely used without any clear definitions and references. It makes the comparative evaluation of the ecological models difficult and confusable. It is highly required to do the performance test of the red-tide models based on the suitable classification and appropriate error analysis because model structures are different even though the same/similar words (e.g., red-tide, algal bloom, phytoplankton growth, ecological or ecosystem models) are used. Thus, the references on the model classification are suggested and the advantage and disadvantage of the models are also suggested. The processes and methods on the performance test (quantitative error analysis) are recommend to the practical use of the red-tide model in the coastal seas. It is suggested in each stage of the modeling procedures, such as verification, calibration, validation, and application steps. These suggested references and methods can be attributed to the effective/efficient marine policy decision and the coastal ecosystem management plan setup considering the red-tide and/or ecological models uncertainty.

Comparative Analysis of QUAL2E, QUAL2K and CAP Steady State Water Quality Modeling Results in Downstream Areas of the Geum River, Korea (QUAL2E, QUAL2K 및 CAP 모델을 이용한 금강 하류 하천구간 정상상태 수질모델링 결과 비교 분석)

  • Seo, Dongil;Yun, Jong Uk;Lee, Jae Woon
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.1
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    • pp.121-129
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    • 2008
  • Major factors affecting water quality in rivers are transportation, input of pollutant loads and kinetic transformation of pollutants. Government level decision makings on water quality management are based on steady state water quality modeling. However, it is more than often that such a steady state assumption is far from real situations in rivers. Therefore, it is unavoidable to have modeling errors in water quality modeling especially for steady state modeling for longer period of time. Authors attempted to identify sources of errors in results of steady state models and thus tried to find out ways to minimize those errors. Three water quality models, QUAL2E (Brown et al., 1983), QUAL2K (Chapra et al., 2006) and CAP (Seo and Lee, 2000) were applied to the lower stream of the Geum River. $BOD_5$ and COD tend to underestimate observed data while TN and TP showed relatively smaller errors. QUAL2E model provided best calibration results for BOD5 and TP and QUAL2K model showed best calibration results for TN. Since these errors are only relative values, it was difficult to conclude which model is better performing in certain situations. The most probable reasons for errors in water quality modeling are; 1) inappropriate consideration on flow characteristics, 2) lack of information on incoming pollutant load and 3) inappropriate location of sampling for water quality analysis.

Determination of halogen elements in plastics by using combustion ion chromatography (연소IC를 이용한 플라스틱 중 할로겐 물질 정량)

  • Jung, Jae Hak;Kim, Hyo Kyoung;Lee, Yang Hyoung;Lee, Lim Soo;Shin, Jong Keun;Lee, Sang Hak
    • Analytical Science and Technology
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    • v.21 no.4
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    • pp.284-295
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    • 2008
  • For plastics samples, a method using combustion ion chromatography was selected as a method for rapid low-cost analysis to test whether hazardous substances are contained or not. Using combustion ion chromatography, a verification test for F, Cl and Br compounds generated a linear calibration curve with a correlation coefficient of $r^2$ = 0.999~1.000 in the calibration range from 0.5 to 4.0 mg/kg. The detection limits were found to be 0.005~0.024 mg/kg and quantitative limits were found to be 0.014~0.073 mg/kg. The recoveries of combustion ion chromatography using certified reference material (CRM) were found to be 95.5~104.9%. Based on these results, a proficiency test was conducted together with several laboratories in and out of the country, to make comparative analysis of the results from each laboratory. As a result, the data supported the use of combustion ion chromatography as an effective analysis method to deal with regulations for halogen-free electronic products and for other hazardous substances in the electronic products.

Comparative assessment of sequential data assimilation-based streamflow predictions using semi-distributed and lumped GR4J hydrologic models: a case study of Namgang Dam basin (준분포형 및 집중형 GR4J 수문모형을 활용한 순차자료동화 기반 유량 예측 특성 비교: 남강댐 유역 사례)

  • Lee, Garim;Woo, Dong Kook;Noh, Seong Jin
    • Journal of Korea Water Resources Association
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    • v.57 no.9
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    • pp.585-598
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    • 2024
  • To mitigate natural disasters and efficiently manage water resources, it is essential to enhance hydrologic prediction while reducing model structural uncertainties. This study analyzed the impact of lumped and semi-distributed GR4J model structures on simulation performance and evaluated uncertainties with and without data assimilation techniques. The Ensemble Kalman Filter (EnKF) and Particle Filter (PF) methods were applied to the Namgang Dam basin. Simulation results showed that the Kling-Gupta efficiency (KGE) index was 0.749 for the lumped model and 0.831 for the semi-distributed model, indicating improved performance in semi-distributed modeling by 11.0%. Additionally, the impact of uncertainties in meteorological forcings (precipitation and potential evapotranspiration) on data assimilation performance was analyzed. Optimal uncertainty conditions varied by data assimilation method for the lumped model and by sub-basin for the semi-distributed model. Moreover, reducing the calibration period length during data assimilation led to decreased simulation performance. Overall, the semi-distributed model showed improved flood simulation performance when combined with data assimilation compared to the lumped model. Selecting appropriate hyper-parameters and calibration periods according to the model structure was crucial for achieving optimal performance.

A Suggestion for Counting Efficiency Management of the Automation Instrument (자동화장비 계측효율 관리적 측정방법 제안)

  • Park, Jun Mo;Kim, Han Chul;Choi, Seung Won
    • The Korean Journal of Nuclear Medicine Technology
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    • v.22 no.2
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    • pp.105-111
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    • 2018
  • Purpose Quality control of instrument takes up a large part in the Radioimmunoassays. The gamma-ray instrument, which is one of the important instruments in the laboratory, observes the condition and performance of instrument and performs quality control of the instrument by measuring the Normalization, Calibration, Background and etc. However, there are some automation instruments which can't measure the counting efficiency of gamma-ray meters, resulting in insufficient management in terms of performance evaluation of gamma-ray meters. Therefore, the purpose of this paper is to manage the quality control continuously and regularly by suggesting how to measure the counting efficiency of gamma-ray instruments. Materials and Methods In case of a comparative measurement method to a gamma-ray instrument dedicated to nuclear medical examination, the CPM and counting efficiency can be obtained after the measurement of normalization by inserting the I-125 $200{\mu}L$(CPM 50,000~500,000) into the test tube. With this CPM and counting efficiency values, it's possible to calculate the measurement of the DPM value and count the CPM from the automation instrument from the same source, and enter the DPM to calculate the counting efficiency using a comparative measurement method. Another method is to calculate the counting efficiency by estimating the half life using the radiation source information of the tracer in B test reagents of company A. Results According to the calculation formula using the DPM obtained by counting the normalization of gamma-ray meters, the detection efficiency was 75.16% for Detector 1, 76.88% for Detector 2, 77.13% for Detector 3, 75.36% for Detector 4 and 73.2% for Detector 5 respectively. Using another calculation formula estimated from the shelf life, the data of the detection efficiency from Detector 1 to Detector 5 were 74.9%, 75.1%, 76.5%, 74.9% and 73.2% respectively. Conclusion Although the accuracy of counting efficiencies of both methods are insufficient, this is considered to be useful for ongoing management of quality control if counting efficiency is managed after setting the acceptable ranges. For example, if the measurement efficiency is set to 70% or higher, the allowed %difference between measurements is within 3% and the %difference with the detector wall is set within 5%.

Parameter Calibration of Storage Function Model and Flood Forecasting (2) Comparative Study on the Flood Forecasting Methods (저류함수모형의 매개변수 보정과 홍수예측 (2) 홍수예측방법의 비교 연구)

  • Kim, Bum Jun;Song, Jae Hyun;Kim, Hung Soo;Hong, Il Pyo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.1B
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    • pp.39-50
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    • 2006
  • The flood control offices of main rivers have used a storage function model to forecast flood stage in Korea and studies of flood forecasting actively have been done even now. On this account, the storage function model, which is used in flood control office, regression models and artificial neural network model are applied into flood forecasting of study watershed in this paper. The result obtained by each method are analyzed for the comparative study. In case of storage function model, this paper uses the representative parameters of the flood control offices and the optimized parameters. Regression coefficients are obtained by regression analysis and neural network is trained by backpropagation algorithm after selecting four events between 1995 to 2001. As a result of this study, it is shown that the optimized parameters are superior to the representative parameters for flood forecasting. The results obtained by multiple, robust, stepwise regression analysis, one of the regression methods, show very good forecasts. Although the artificial neural network model shows less exact results than the regression model, it can be efficient way to produce a good forecasts.

Evaluation of water-Soluble Lubricant for Cold Forging and Optimization of Coating Process (냉간단조용 수용성 윤활제의 평가 및 윤활 처리 공정의 최적화)

  • Lim, W.J.;Lee, I.S.;Je, J.S.;Ko, D.C.;Kim, B.M.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2007.05a
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    • pp.149-154
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    • 2007
  • The zinc prosphate film treatments used to lubricating treatment of mostly cold forging processes. But there are several problems happened to lubricating treatment process such as happening harmful environment on person, complex lubrication processing occurring in energy and time consumption, eco-destructive and chemical by-product generation, the needs of waste disposal etc. As a result, a water-soluble lubricant was developed to replace the perfect or some of the zinc prosphate film in the world. In order to solve these problems, this study evaluated the performance of the typical water-soluble. In this study, for these requirement inquiry of two part. First, about possibility of replace zinc phosphate lubricant, quantitatively evaluation developed of water-soluble lubricant for cold forging vs zinc phosphate lubricant. Second, About optimization of coating Process use to equipment with practicable automatic coating Process. The performance evaluation of these lubricants was conducted using the double cup extrusion test and spike forging test. With the use of the commercial FE code DEFORM, friction factor calibration curves, i.e. cup height ratio vs. punch stroke and spike height vs. punch stroke, were established for different friction factor values. By matching the cup height ratio and the punch stroke and spike height vs. punch stroke from experiment to that obtained from FE simulations, the friction factor of the lubricants was determined. Survey of comparative analysis use to SEM that sprayed lubricant surface structure of grain shape and characteristic of lubricant performance based on grain shape and deformed lubricant surface expansion. As a result, developed lubricant were found to perform comparable to or better than zinc phosphate. And thought this result, innovatively cope with generated problem of existing lubrication process.

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Comparative study of the radiopacity of resin cements used in aesthetic dentistry

  • Montes-Fariza, Raquel;Monterde-Hernandez, Manuel;Cabanillas-Casabella, Cristina;Pallares-Sabater, Antonio
    • The Journal of Advanced Prosthodontics
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    • v.8 no.3
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    • pp.201-206
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    • 2016
  • PURPOSE. The aim of this study was to compare the radiopacity of 6 modern resin cements with that of human enamel and dentine using the Digora digital radiography system, to verify whether they meet the requirements of ANSI/ADA specification no. 27/1993 and the ISO 4049/2000 standard and assess whether their radiopacity is influenced by the thickness of the cement employed. MATERIALS AND METHODS. Three 3-thickness samples (0.5, 1 and 1.5 mm) were fabricated for each material. The individual cement samples were radiographed on the CCD sensor next to the aluminium wedge and the tooth samples. Five radiographs were made of each sample and therefore five readings of radiographic density were taken for each thickness of the materials. The radiopacity was measured in pixels using Digora 2.6 software. The calibration curve obtained from the mean values of each step of the wedge made it possible to obtain the equivalent in mm of aluminium for each mm of the luting material. RESULTS. With the exception of Variolink Veneer Medium Value 0, all the cements studied were more radiopaque than enamel and dentin (P<.05) and complied with the ISO and ANSI/ADA requirements (P<.001). The radiopacity of all the cements examined depended on their thickness: the thicker the material, the greater its radiopacity. CONCLUSION. All materials except Variolink Veneer Medium Value 0 yielded radiopacity values that complied with the recommendations of the ISO and ANSI/ADA. Variolink Veneer Medium Value 0 showed less radiopacity than enamel and dentin.

Comparative Analyses of Bioactive Constituents from Forsythia suspensa and Forsythia viridissima by HPLC-DAD

  • Won, Tae-Hyung;Liao, Lijuan;Lee, Seung-Ho;Son, Jong-Keun;Shin, Jong-Heon
    • Natural Product Sciences
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    • v.17 no.4
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    • pp.328-336
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    • 2011
  • A high-performance liquid chromatography (HPLC) with diode array detector (DAD) method was established for the discrimination of a folk medicine Forsythia suspensa and Forsythia viridissima. Five and three representative metabolites of the lignan and phenolic glycoside classes were selected for the analysis from F. suspensa and F. viridissima, respectively. The optimal chromatographic conditions were obtained on an ODS column (5 ${\mu}m$, $4.6{\times}250$ mm) with the column temperature at $40^{\circ}C$. The mobile phase was composed of methanol and 0.3% acetic acid using an isocratic elution with the flow rate 1 mL/min. Detection wavelength was set at 280 nm. All calibration curves showed good linear regression ($r^2$ > 0.996) within test ranges. Limits of detection (LOD) and limits of quantitation (LOQ) values were lower than 0.096 and 0.291 ${\mu}g/mL$, respectively. The developed method provided satisfactory precision and accuracy with overall intra-day and inter-day variations of 0.07-0.63% and 0.14-0.62%, respectively, and the overall recoveries of 97.79-102.46% for all of the compounds analyzed. In addition, effectiveness of diverse extraction methods was compared to each other for the development of standard analytical method. The verified method was successfully applied to the quantitative determination of representative metabolites in fifty-three commercial F. suspensa samples and fifteen commercial F. viridissima samples from diverse sources. The overall analytical results showed the unequivocal differences in bioactive constituents between F. suspensa and F. viridissima.

Reliability analysis of proposed capacity equation for predicting the behavior of steel-tube concrete columns confined with CFRP sheets

  • Raza, Ali;Khan, Qaiser uz Zaman;Ahmad, Afaq
    • Computers and Concrete
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    • v.25 no.5
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    • pp.383-400
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    • 2020
  • Due to higher stiffness to weight, higher corrosion resistance, higher strength to weight ratios and good durability, concrete composite structures provide many advantages as compared with conventional materials. Thus, they have wide applications in the field of concrete construction. This research focuses on the structural behavior of steel-tube CFRP confined concrete (STCCC) columns under axial concentric loading. A nonlinear finite element analysis (NLFEA) model of STCCC columns was simulated using ABAQUS which was then, calibrated for different material and geometric models of concrete, steel tube and CFRP material using the experimental results from the literature. The comparative study of the NLFEA predictions and the experimental results indicated that the proposed constitutive NLFEA model can accurately predict the structural performance of STCCC columns. After the calibration of NLFEA model, an extensive parametric study was performed to examine the effects of different critical parameters of composite columns such as; (i) unconfined concrete strength, (ii) number of CFRP layers, (iii) thickness of steel tube and (iv) concrete core diameter, on the axial load capacity. Furthermore, a large database of axial strength of 700 confined concrete compression members was developed from the previous researches to give an analytical model that predicts the ultimate axial strength of composite columns accurately. The comparison of the predictions of the proposed analytical model was done with the predictions of 216 NLFEA models from the parametric study. A close agreement was represented by the predictions of the proposed constitutive NLFEA model and the analytical model.