• 한국연소학회:학술대회논문집
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• 2014.11a
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• pp.33-36
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• 2014

Gasification of biomass produces syngas containing CO, $H_2$ and/or $CH_4$, which can then be converted into energy or value-added fuels. One of key issues for efficient gasification is to minimize tar concentration in the syngas for use in a final conversion device such as gas engine. This study investigated the decomposition of primary tar by catalytic cracking using char as catalyst, of which the feature can be integrated into a fixed bed gasifier design. The pyrolysis vapor containing tar from pyrolysis of wood at $500^{\circ}C$ was passed through a reactor filled with or without char at $800^{\circ}C$ for a residence time of 1, 3 or 5 sec. Then, the condensable vapor (water and tar) and gases were analyzed for the yields and elemental composition. Four types of char particles with different microscopic surface area and pore size distribution: wood, paddy straw, palm kernel shell and activated carbon. The results were analyzed for the mass and carbon yields of tar and the composition of product gases to conclude the effects of char types and residence time.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2004.06a
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• pp.105-114
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• 2004

This study investigated the thermal behavior of the nuclear graphite waste generated from the decommissioning of the Korean nuclear research reactor, The first part study investigated the decomposition rate of the nuclear graphite waste up to $1000^{\circ}C$ under various oxygen partial pressures using a thermo-gravimetric analyzer (TGA). Tested graphite waste sample not easily destroyed in the oxygen-deficient condition. However, the gas-solid oxidation reaction was found to be very effective in the presence of oxygen. No significant amount of the product of incomplete combustion was formed even in the limited oxygen concentration of 4% $O_2$. The influence of temperature and oxygen partial pressure was evaluated by the theoretical model analysis of the thermo-gravimetric data. The activation energy and the reaction order of graphite oxidation were evaluated as 128 kJ/mole and 1.1, respectively. The second part of this study investigated the behavior of radioactive elements under graphite oxidation atmosphere using thermodynamic equilibrium model. $^{22}Na$, $^{134}Cs$ and $^{137}Cs$ were found be the semi-volatile elements. Since volatile uranium species can be formulated at high temperatures above $1050^{\circ}C$, the temperature of incinerator furnace should be minimized. Other corrosion/activation products, fission products and uranium were found to be the non-volatile species.

• Journal of Surface Science and Engineering
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• v.34 no.6
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• pp.575-584
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• 2001

Erosion due to abrasive particles contained in gas streams from boilers has been emerged as a significant problem in the coal fired power plants. Particle erosion accounted for approximately 50% of boiler failures and especially flyash erosion was responsible for 20~30% of emergency boiler shutdowns. Particularly, because of the high ash loading and high velocity, most erosion occurs in the boiler tubes and economiser tube bank where the direction of the gas stream changes to $180^{\circ}$ .In this study, a high temperature particle erosion tester was used to evaluate erosion rate in a simulated environment. The erosion parameters such as erosion temperature, particle impact angle, particle velocity and various particle size were changed. Flyash is the combustion product of the pulverized coal, where size is ranging from 1 to $200\mu\textrm{m}$. Flyash composed of mainly SiO$_2$, $A1_2$$_O3$, and $Fe_2$$O_3$has dense spherical particles and irregular particles containing numerous pores and cavities. From the erosion tests at various conditions, the maximum erosion was experienced at impact angles of $30^{\circ}$ to $60^{\circ}$ In addition, erosion rate increased in proportional to velocity and temperature. And from the observation of the eroded surfaces, it was also concluded that 304 stainless steel was mainly eroded by extrusion-forging at high impact angle ($90^{\circ}$) and by microcutting mechanism at low impact angles ($30^{\circ}$ and $45^{\circ}$).

• Journal of the Korean Society of Industry Convergence
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• v.16 no.1
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• pp.21-26
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• 2013

Burned gas of methane-air mixtures with water vapor have been analysed to study the exhaust emission using gas-chromatography and computation. The computations were carried out for the gas analysis using premix code of Chemkin program to compare the experimental results. The quantity of water vapor contained were changed 5% and 10% of total mixtures, and equivalence ratio of mixtures between 0.6 and 1.2 were tested under the ambient temperature 323K and 373K. The results showed CO, $CO_2$ decreased and $H_2$ increased by increasing the water contents. The CO increased and $CO_2$ decreased by increasing the ambient temperature. The $CO_2$ shows the maximum product at equivalence ratio 1.0, in otherwise the $CH_4$ produced the minimum values in the same range. The results showed little difference between these two methods.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2005.11a
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• pp.196-200
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• 2005

A theoretical model for the calculation of chemical equilibrium composition of propellant combustion product is briefly presented for the performance analysis of monopropellant hydrazine rocket engine. Analysis result is compared to that of test and evaluation of 1-lbf class thruster and is scrutinized primarily from the view point of ammonia dissociation fraction. Chemical equilibrium composition and average molecular weight is additionally depicted according to the variation of propellant inlet pressures and the varying nozzle area ratio. The theoretical analysis is tried as a way of derivation of design parameters for mid- and large-thrust class of monopropellant rocket engines.

• 한국연소학회:학술대회논문집
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• 2000.05a
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• pp.122-132
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• 2000

Computational fluid dynamic simulation is performed for the floating turbulent premixed flames stabilized in stagnation flows of Cho et al. [1] and Cheng and Shepherd [2]. They are both in the wrinkled flamelet regime far from the extinction limit with $u'/S^{0}_{L}$ less than unity. The turbulent flux is given in the first moment closure as a sum of the classical gradient flux due to turbulent motions and the countergradient flux due to thermal expansion. The parameter $N_{B}'s$ are greater than unity with the countergradient flux dominant over the gradient flux. The countergradient flux is assumed to be zero in $\bar{c}<0.05$. The flame surface density is modeled as a symmetric parabolic function with respect to $\bar{c}$. The product of the maximum flame surface density and the mean stretch factor is considered as a tuning constant to match the flame location. Good agreement is achieved with the measured $\tilde{w}$ and $\bar{c}$ profiles along the axis in both flames.

• Transactions of Materials Processing
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• v.27 no.4
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• pp.201-210
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• 2018

An airbag is an essential automotive component used in all kinds of vehicles such as an internal combustion engine and an electric motor vehicle and is used to minimize the damage of an occupant in the event of an accident. Airbag-related parts are being monopolized by a small number of foreign companies around the world. In this situation, it is necessary to develop and research the airbag-related part molding technology for expansion of the domestic airbag-related market and corporate export. As a part of this research, we have developed a mold for airbag inflator cap. The development consists of three steps which are the design of components, analysis of the design and verification of it. In the case of the design, the transfer type mold was designed for the multi-cylindrical shaped feature. Analysis was then conducted on the design. By examining the results of analysis, changing features and numbers of punches and dies were added in the analysis and repeatedly analyzed. After the addition, proper dimensions from the analysis were achieved, and prototypes were practically produced and verified. In the case of prototype verification, Pressurizing Burst Test was conducted on the existing products and the prototype. By comparing the results of the test, the possibility of replacing the existing product of the airbag inflator cap is presented in this paper.

• Journal of the Korean Society of Propulsion Engineers
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• v.15 no.6
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• pp.7-14
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• 2011

Various sizes of hydrazine monopropellant thruster have been used on satellite and space launcher vehicle. The test and handling procedure of hydrazine monopropellant thruster are usually difficult because of the toxicity of hydrazine and its decomposition product gases. Therefore, the numerical analysis can help understand the effects of various design parameters and can reduce the time as well as expenses. In this study, the numerical analysis is performed by modelling the catalyst bed as one dimensional porous medium. Thereby, resulting physical phenomena are examined by considering the variation of catalyst bed characteristics incurred by catalyst granule failure.

• Particle and aerosol research
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• v.5 no.2
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• pp.45-52
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• 2009

Black carbon, which is a by-product of combustion of fossil fuel and biomass burning, is the component that imposes the largest uncertainty on quantifying aerosol climate effect. The direct, indirect and semi-direct climate effects of black carbon depend on its state of the mixing with other water-soluble aerosol components. The process that transforms hydrophobic externally mixed black carbon particles into hygroscopic internally mixed ones is called "aging". In most climate models, simple parameterizations for the aging time scale are used instead of solving detailed dynamics equations on the aging process due to the computation cost. In this study, a new parameterization for the black carbon aging time scale due to condensation and coagulation is presented as a function of the concentration of hygroscopic atmospheric components and the black carbon particle size. It is shown that the black carbon aging time scale due to condensation of sulfuric acid vapors varies to a large extent depending on the sulfuric acid concentration and the black carbon particle size. This result indicates that the constant aging time scale values suggested in the literature cannot be directly applied to a global scale modeling. The aging time scale due to coagulation with internally mixed aerosol particles shows an even stronger dependency on particle size, which implies that the use of a particle-size-independent aging time scale may lead to a large error when the aging is dominated by coagulation.

• 한국연소학회:학술대회논문집
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• 2002.11a
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• pp.129-139
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• 2002

From the view of the environmental protection against the use of fossil fuels, a great of efforts have been exerted to find an alternative energy source. Hydrogen may become an alternative. However the product species of the hydrogen flame is only $H_2O$, which emits only non-luminous radiation so the radiation from it is much smaller than that for a hydrocarbon flame. In this study, the authors designed and fabricated a laboratory scale test furnace to study thermal characteristics of hydrogen-air diffusion flame. In addition, the effects of addition of reacting as well as non-reacting solid particles were experimentally investigated. Among the total heat flux to the wall, about 75% was occupied by radiation while 25 % by convection. When the aluminum oxide ($Al_2O_3$) particles were added, the radiative heat flux was reduced due to heat blockage effects. On the other hand, the total as well as the radiative heat flux was increased when the carbon particles were seeded, since the overall temperature increased. The effects of swirl and excess air ratio were also examined.