• Title/Summary/Keyword: Combustion pattern

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Synthesis of Li2Mn3O7 and Application to Hybrid Capacitor

  • Kim, Hun-Uk;Shin, Kyoung-Hee;Lee, Bum-Suk;Jeon, Myung-Seok;Jung, Kyu-Nam;Sun, Yang-Kook;Jin, Chang-Soo
    • Journal of Electrochemical Science and Technology
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    • v.1 no.2
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    • pp.97-101
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    • 2010
  • In order to apply hybrid capacitor, $Li_2Mn_3O_7$ was synthesized by combustion method using $LiNO_3$, $Li(CH_3COO){\cdot}2H_2O$ and $Mn(CH_3COO){\cdot}4H_2O$. Spinel pattern was identified the samples calcined over $400^{\circ}C$ in XRD. Intensity of $Mn_2O_3$ peak increased as the calcination temperature increased. To decide n/p ratio and to investigate electrochemical properties, charge-discharge tests of Li/$Li_2Mn_3O_7$ and Li/AC half-cell were carried out. Applying to AC/$Li_2Mn_3O_7$ hybrid capacitor, it had high discharge capacitance of 32.8 F/cc at 100 mA/g.

Structure and Characteristics of Diffusion Flaame behind a Bluff-body in a Divergent Flow(II) (확대유로내의 Bluff-Body 후류확산화염의 구조 및 특성 2)

  • ;;Lee, Joong Sung
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.11
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    • pp.2981-2994
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    • 1995
  • In order to elucidate the effects of positive pressure gradient on flame properties, structure and stabilization, an experimental study is made on turbulent diffusion flame stabilized by a circular cylinder in a divergent duct flow. A commercial grade gaseous propane is injected from two slits on the rod as fuel. In this paper, stabilization, characteristics and flame structure are examined by varying the divergent angle of duct. Temperature, ion current and Schlieren photographs were measured. It is found that critical divergent angle is expected to be about 8 ~ 12 degree through blow-off velocity pattern to divergent angle and the positive pressure gradient influences the flame temperature, intensity of ion current and eddy structure behind the rod. With the increase of divergent angle, typical temperature of recirculation zone is low but intensity of ion current is high in shear layer behind rod. Energy distributions of fluctuating temperature and ion current signals turn up low frequency corresponding to large scale eddies but high frequency corresponding to small scale eddies as well as low with the increase of divergent angle. Therefore the flame structure becomes a typical distributed-reacting flame.

Analysis of in-cylinder steady flow for dual-intake-valve gasoline engine using single-frame particle tracking velocimetry (단일 프레임 입자 추적법을 이용한 흡입 2밸브 가솔린 기관의 실린더 내 정상 유동 해석)

  • Lee, Chang-Sik;Lee, Gi-Hyeong;Im, Gyeong-Su;Jeon, Mun-Su
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.5
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    • pp.650-658
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    • 1997
  • Analysis and control of intake charge motion such as swirl and tumble are very important factors in improving the gasoline engine performance. In this paper, single-frame PTV (particle tracking velocimetry) is used to investigate intake tumble patterns in a steady flow test rig of gasoline engine with dual-intake-valve and pent-roof combustion chamber. Intake tumble pattern is quantified in accordance with blockage ratio of TIV (tumble intensifying valve) with single- frame PTv.The view of the instantaneous 2-D velocity field gives a realistic understanding of in-cylinder flow field. Thus it is confirmed that PTV is a effective tool in engine design. In conventional port, two tumble structures appear clearly, and the larger one is observed under the exhaust valve side and the smaller is right below the intake valve side. The larger vorticity is observed in TIV port, thus it is concluded that TIV have an effect on intensified tumble motion in cylinder flow.

Optimization of Shift Control to Improve Driving Efficiency of Battery Electric Vehicles with Two-speed Transmission (2단 변속기 적용 전기차의 구동 효율 향상을 위한 변속 제어 최적화)

  • Taekho Chung;Younghee Kim
    • Journal of ILASS-Korea
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    • v.28 no.2
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    • pp.62-67
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    • 2023
  • Recently, the global automobile industry is aiming for a transition from internal combustion locomotives to zero-emission vehicles. Electric vehicles powered by battery energy can operate at peak performance and improve fuel economy by applying multiple motors or multi-speed transmissions. In order to design a two-speed transmission, it is necessary to evaluate and analyze the application system and performance of electric vehicles. In this study, control performance optimization of a twostage battery electric vehicle equipped with an AMT-based automatic transmission was performed and performance according to control pattern changes was analyzed. In order to improve the operating efficiency of the motor, the shift control that sets the optimal operating point according to the vehicle speed and required torque was derived from the motor efficiency map. The performance of battery energy consumption and transmission loss energy according to the hysteresis interval was analyzed and optimized. The hysteresis interval applied to the optimal shift map acted as a factor in reducing the frequency and loss of shifts. It has been shown that keeping the hysteresis interval at about 4 km/h can reduce energy consumption while reducing the number of shifts.

Source Estimation of Dioxin in Soil Using a Congener Pattern (이성체 정보를 이용한 토양 중 다이옥신 오염원 해석)

  • Kim, Jong-Guk;Kim, Kyoung-Soo;Kim, Jae-Sik;Shin, Sun-Kyoung;Chung, Young-Hee;Chung, Il-Rok
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.3
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    • pp.316-322
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    • 2005
  • In this study, the concentration of 17 dioxin congeners in the soil samples near a waste incinerator with respect to distance from incinerator and wind directions were investigated. The effect of PCB source was investigated using the cluster analysis method. The total concentration and I-TEQ concentration of dioxin ranged from 31.065 to 7,257.499 pg/g(dry weight) and from 0.099 to 35.191 pg I-TEQ/g(dry weight.), respectively. There was a weak correlation(not statistically significant) observed between soil concentration and wind direction, and the distance from the incinerator. The reason may be due to the presence of the local combustion sources other than the target incinerator. The fraction of PCDFs and PCDDs was also examined to study the effect of incinerator. The fraction of PCDFs was decreased with the distance from the incinerator. The influence of target incinerator was found within a 500-meter radius. The high concentration in the for site was due to small incinerators and the use of agricultural chemicals such as PCP. To investigate the relationship between soil near the incinerator and the sources, the cluster analysis was conducted using the congener pattern. As a result soil samples were divided into four groups and were qualitatively estimated the influence of sources such as incinerator and PCP by comparing the congener pattern of each roups. It was thought that a cluster analysis was a useful statistical method for the source estimation of dioxin.

Determination of Thermoluminescence Properties of MgB4O7 Doped with Dy3+, La3+ and Ho3+ for a Light Tracer Application (비화공식 예광탄 응용을 위한 Dy3+, La3+ 그리고 Ho3+이 도핑된 MgB4O7의 열 발광 특성 분석)

  • Park, Jinu;Kim, Nakyung;Choi, Jiwoon;Koh, Jaehyuk;Chin, Hee Sik;Jung, Duck Hyeong;Shin, Byungha
    • Korean Journal of Materials Research
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    • v.32 no.1
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    • pp.9-13
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    • 2022
  • Bullets flying with a light from the back are called "tracers". Tracers are ignited by the combustion gas of the propellant and emit bright light that allows the shooter to visually trace the flight path. Therefore, tracers mark the firing point for allies to assist shooters to hit target quickly and accurately. Conventional tracers are constructed with a mixture of an oxidizing agent, raw metal, and organic fuel. Upon ignition, the inside of the gun can be easily contaminated by the by-products, which can lead to firearm failure during long-term shooting. Moreover, there is a fire risk such as forest fires due to residual flames at impact site. Therefore, it is necessary to develop non-combustion type luminous material; however, this material must still use the heat generated from the propellant, so-called "thermoluminescence (TL)". This study aims to compare the TL emission of Dy3+, La3+ and Ho3+ doped MgB4O7 phosphors prepared by solid state reaction. The crystal structures of samples were determined by X-ray diffraction and matched with the standard pattern of MgB4O7. Luminescence of various doses (200 ~ 15,000 Gy) of gamma irradiated Dy3+, La3+ and Ho3+ (at different concentrations of 5, 10, 15 and 20 %) doped MgB4O7 were recorded using a luminance/color meter. The intensity of TL yellowish (CIE x = 0.401 ~ 0.486, y = 0.410 ~ 0.488) emission became stronger as the temperature increased and the total gamma-ray dose increased.

Cyclic Properties of Li[Co0.17Li0.28Mn0.55]O2 Cathode Material

  • Park, Yong-Joon;Hong, Young-Sik;Wu, Xiang-Lan;Kim, Min-Gyu;Ryu, Kwang-Sun;Chang, Soon-Ho
    • Bulletin of the Korean Chemical Society
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    • v.25 no.4
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    • pp.511-516
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    • 2004
  • A Li$[Co_{0.17}Li_{0.28}Mn_{0.55}]O_2$ cathode compound was prepared by a simple combustion method. The X-ray diffraction pattern showed that this compound could be classified as ${\alpha} -NaFeO_2$ structure type with the lattice constants of a = 2.8405(9) ${\AA}$ and c = 14.228(4) ${\AA}$. According to XANES analysis, the oxidation state of Mn and Co ions in the compound were 4+ and 3+, respectively. During the first charge process, the irreversible voltage plateau at around 4.65 V was observed. The similar voltage-plateau was observed in the initial charge profile of other solid solution series between $Li_2MnO_3\;and\;LiMnO_2$ (M=Ni, Cr...). The first discharge capacity was 187 mAh/g and the second discharge capacity increased to 204 mAh/g. As the increase of cycling number, one smooth discharge profile was converted to two distinct sub-plateaus and the discharge capacity was slowly decreased. From the Co and Mn K-edge XANES spectra measured at different cyclic process, it can be concluded that irreversible transformation of phase is occurred during continuous cycling process.

Study of Air Flow Effects on Heat Characteristics of Warm Needle Acupuncture (온침 열특성의 기류 영향에 관한 연구)

  • Kim, Jung-Wo Roy;Lee, Hye-Jung;Yi, Seung-Ho
    • Korean Journal of Acupuncture
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    • v.27 no.4
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    • pp.35-47
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    • 2010
  • Objectives : To characterize the thermal properties of traditional warm needle and new warm needle with various air flows as an important environmental factor and to suggest the necessity of maintaining suitable environment of clinics to maximize their efficacy. Methods : We measured the temperature characteristics of traditional moxa warm needle and new moxa charcoal warm needle by applying an automatic temperature acquisition system with thermocouples while external various air flows were supplied. Temperatures of two positions at the needle body were measured while a moxa cone burned. Typical temperature characteristics like peak temperature, duration, curve shape and the efficiency of the heat stimuli by heat amount analysis were executed. Results : Both warm needles showed similar temperature curve with an increase in the air flow. Peak temperature and duration of effective heat decreased with the air flow, as shown in indirect moxibustion on garlic. The temperature change pattern by the air flow became more apparent when the total combustion heat was compared with the effective heat. The values from two positions on the needle body were significantly different, showing a distance dependency from the heat source of warm needle acupuncture. Conclusions : Thermal properties of warm needle acupuncture was observed variously with surrounding air flow of 0.0 - 0.7 m/s. It emphasized the importance of environmental control as well as the warm needle itself such as heat source and needle. The latter has already been known to deliver designated heat to subjects. It also indicated the importance of education and skill of the practitioners of warm needle acupuncture.

A Study on the Characteristics of Fuel Consumption and Emissions of Diesel Vehicles Using Engine Coolant Flow Rate On/Off Control (엔진 냉각수 유량 단속에 의한 디젤 차량의 연비 및 배기가스 특성 연구)

  • Kim, Sung Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.5
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    • pp.2069-2074
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    • 2013
  • The use of the electromagnetic clutch water pump for internal combustion engine vehicles saves fuel and leads to a reduction in emissions. The clutch water pump allows the engine cooling system to select the optimum operation condition by using coolant flow rate on/off control. This study investigated the characteristics of fuel consumption and emissions of the diesel engine cooling system using the clutch water pump. The electromagnetic clutch operation reduced by about 49% of engine warm up period at idle condition and controlled the optimum high coolant temperature at driving condition. Therefore, fuel consumption was enhanced by about 5%, and emissions such as HC, CO and $CO_2$ were also reduced to a certain degree even though NOx increased a little bit, compared to those of the conventional water pump under NEDC mode which represents the real driving pattern.

Source Characteristics of Particulate Trace Metals in Daegu Area (대구지역 부유분진 중 미량금속성분의 발생원 특성연구)

  • 최성우;송형도
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.5
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    • pp.469-476
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    • 2000
  • This study was performed to understand the behavior and source characteristics of particulate trace metals in Daegu area. To do this, total of 84 samples had been collected from January to December 1999. TSP (total suspended particulate matter) and PM-10(particulate matter with aerodynamic diameters less 10${\mu}{\textrm}{m}$) were collected by filters on portable air sampler, and in TSP and PM-10 were analyzed by ICP(Inductively Coupled Plasma Spectrometer) after preliminary treatment. The results were follow as: first, annul means of TSP and PM-10 concentration were 123 and 69$\mu\textrm{g}$/㎤ respectively. The concentration of TSP adn PM-10 were highest in winter season compared to other seasons. Second, the concentration of Al, Fe, Mn were higher in TSP than in PM-10, indicating that these metals are generally associate with natural contributions. Third, a hierarchical clustering technique was used to group 9 metals. The results from the cluster analysis of TSP and PM-10 shows a similar clustering pattern : Fe, Al in a group and the rest of the metals such as Ni, Cr, As, Mn, Cd, Pb, Zn in the other group. One group of metal such as Fe, Al is associated with natural sources such as soil and dust. The other is closely related to urban anthropogenic sources such as fuel combustion, incineration, and refuse burning, Finally, using Al as a reference element, enrichment factors were used for identifying the major particulate contributors. The enrichment factors of Al. Fe<10 (standard value of enrichment factor) were considered to have a significant dust and soil source and termed nonenriched. Ni, Cr, As, Mn, Cd, Pb, Zn》10 is enriched and has a significant which is contributed by athropogenic sources.

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