• Nuclear Engineering and Technology
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• v.55 no.5
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• pp.1783-1790
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• 2023

Barium Bismuth Oxide Borate (BBOB) has been synthesized for the first time using solution combustion technique. SEM analysis reveal flower shape of the nanoparticles. The formation of the nanoparticles has been confirmed through XRD & FTIR studies which gives the physical and chemical structure of the novel material. The UV light absorption is observed in the range 200-300 nm. The present study highlights the radiation shielding ability of BBOB for different radiations like X/Gamma rays, Bremsstrauhlung and neutrons. The gamma shielding efficiency is comparable to that of lead in lower energy range and lesser than lead in the higher energy range. The bremsstrauhlung exposure constant is comparably larger for BBOB NPs than that of concrete and steel however it is lesser than that of lead. The beauty of BBOB nanoparticles lies in, high absorption of radiations and low emission of secondary radiations when compared to lead. In addition, the neutron shielding parameters like scattering length, absorption and scattering cross sections of BBOB are found to be much better than lead, steel and concrete. Thus, BBOB nanoparticles are highly efficient in absorbing X/Gamma rays, neutrons and bremsstrauhlung radiations.

• Korean Chemical Engineering Research
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• v.40 no.6
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• pp.746-751
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• 2002

Fluidized bed combustion is a coal combustion technology that can reduce both SOx and NOx emission; SOx is removed by limestone that is fed into the combustion chamber and the NOx is reduced by low temperature combustion in a fluidized bed combustor and air stepping, but $N_2O$ generation is quite high. $N_2O$ is not only a greenhouse gas but also an agent of ozone destruction in the stratosphere. The calcium oxide(CaO) is known to be a catalyst of $N_2O$ decomposition. This study of $N_2O$ decomposition reaction in fixed bed reactor packed over CaO bed has been conducted. Effects of parameters such as concentration of inlet $N_2O$ gas, reaction temperature, CaO bed height and effect of $CO_2$, NO, $O_2$ gas on the decomposition reaction have been investigated. As a result of the experiment, it has been shown that $N_2O$ decomposition reaction increased with the increasing fixed bed temperature. While conversion of the reaction was decreased with increasing $CO_2$ concentration. Also, under the present of NO, the conversion of $N_2O$ decomposition is decreased. From the result of kinetic study gained the heterogeneous reaction rate on $N_2O$ decomposition. In the case of $N_2O$ decomposition over CaO, heterogeneous reaction rate is. $\frac{d[N_2O]}{dt}=\frac{3.86{\times}10^9{\exp}(-15841/R)K_{N_2O}[N_2O]}{(1+K_{N_2O}[N_2O]+K_{CO_2}[CO_2])}$. In this study, it is found that the calcium oxide is a good catalyst of $N_2O$ decomposition.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.6
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• pp.451-464
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• 2014

This study used numerical methods to investigates investigate the exhaust gas recirculation (EGR) effect under the condition of boost pressure condition on a homogeneous charge compression ignition (HCCI) combustion engine using numerical methods. The detailed chemical-kinetic mechanisms and thermodynamic parameters for n-heptane, iso-octane, and PRF50 from the Lawrence Livermore National Laboratory (LLNL) are were used for this study. The combustion phase affects the efficiency and power. To exclude these effects, this study decided to maintain a 50 burn point (CA50) at 5 CA after top dead center aTDC. The results showed that the EGR increased, but the low temperature heat release (LTHR), negative temperature coefficient (NTC), and high temperature heat release (HTHR) were weakened due by theto effect of the O2 reduction. The combined EGR and boost pressure enhanced the autoignition reactivity, Hhence, the LTHR, NTC, and HTHR were enhanced, and the heat-release rate was increased. also In addition, EGR decraeased the indicated mean effective pressure (IMEP), but the combined EGR and boost pressure increased the IMEP. As a results, combining the ed EGR and boost pressure was effective to at increase increasing the IMEP and maintaining the a low PRR.

• Journal of Energy Engineering
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• v.22 no.4
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• pp.413-419
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• 2013

The present study used the MILD combustor, which has coaxial cylindrical tube. The outside tube of the MILD combustor corresponds to the exhaust gas passage and the inner side tube is the furnace passage. A numerical analysis was accomplished to elucidate the characteristics of exhaust gas entrainment toward the inner furnace with the changes of venturi nozzle geometrical parameters, nozzle position, nozzle gap between high pressure air nozzle and venturi nozzle, and with the change of high pressure nozzle inlet velocity. The entrainment flow rate for the case with the high pressure air nozzle attached at the exhaust gas wall has relatively small change with the change of nozzle gap. That for the case with the high pressure air nozzle exposed to the exhaust gas has monotonically increase with the change of nozzle gap. The flow rate ratio of entrainment flow rate has considerably increase tendency with relatively lower air inlet velocity, on the other hand, that with relatively higher air inlet velocity could be seen relatively small increase.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.11
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• pp.1005-1013
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• 2010

This study was conducted to assess the spray control of flash boiling with mixed fuel in consideration of HCCI (Homogeneous Charge Compression Ignition) engine condition. Mixed fuel existing in two phase regions can control the process of mixture formation under low temperature and density by using the spray resulting from flash boiling which is able to induce rapid evaporation of fuel spray as well as the evaporation of high boiling point component. Because HCCI engine injects the fuel early under ambient conditions, it can facilitate the chemical control of ignition combustion and physical control such as breakup and atomization of liquid fuel by flash boiling of mixed fuel which consists of highly ignitable light oil and highly volatile gasoline. This study was conducted by performing video processing after selected composition and molar fraction of the mixed fuel as major parameters and photographed Schlieren image and Mie scattered light corresponding to the flash boiling phenomenon of the fuel spray that was injected inside a constant volume vessel. It was found that flash boiling causes significant changes in the spray structure under relatively low temperature and density. Thus, we analyzed that the flash boiling spray can be used for HCCI combustion by controlling the mixture formation at the early fuel injection timing.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.6
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• pp.657-665
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• 2010

Carbon dioxide ($CO_2$) is known to be a major greenhouse gas partially emitted from waste combustion facilities. According to the greenhouse gas emission inventory in Korea, the quantity of the gas emitted from waste sector in 2005 represents approximately 2.5 percent of all domestic greenhouse gas emission. Currently, the emission rate of greenhouse gas from the waste sector is relatively constant partly because of both the reduced waste disposal in landfills and the increased amounts of waste materials for recycling. However, the greenhouse gas emission rate in waste sectors is anticipated to continually increase, mainly due to increased incineration of solid waste. The objective of this study was to analyze the property of Municipal Solid Waste (MSW) and estimate $CO_2$ emissions from domestic MSW incineration facilities. The $CO_2$ emission rates obtained from the facilities were surveyed, along with other two methods, including Tier 2a based on 2006 IPCC Guideline default emission factor and Tier 3 based on facility specific value. The $CO_2$ emission rates were calculated by using $CO_2$ concentrations and gas flows measured from the stacks. Other parameters such as waste composition, dry matter content, carbon content, oxidation coefficient of waste were included for the calculation. The $CO_2$ average emission rate by the Tier 2a was 34,545 ton/y, while Tier 3 was 31,066 ton/y. Based on this study, we conclude that Tier 2a was overestimated by 11.2 percent for the $CO_2$ emission observed by Tier 3. Further study is still needed to determine accurate $CO_2$ emission rates from municipal solid waste incineration facilities and other various combustion facilities by obtaining country-specific emission factor, rather than relying on IPCC default emission factor.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.4
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• pp.448-453
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• 2016

Erosion and abrasion caused by cavitation damage occur in fluid equipment, such as ships or impellers. Similarly, the equipment damage from noise and vibration can shorten its life. This study analyzed the importance of the parameter characteristics of the process optimization of HVOF (High Velocity Oxygen Fuel spraying), which is generally used in a variety of industries for enhancing the resistibility from the cavitation phenomenon. The surface of the ALBC3 substrate was coated with an amorphous powder as a filler metal according to the experimental design using the Taguchi method, and then the characteristics with each parameter were analyzed using a porosity measurement test. The optimal process conditions was a combustion pressure of 80psi, coating distance of 270mm, gun speed of 200mm/s, and powder feed rate of 25g/min as a result of the HVOF coating by applying the experimental design. The combustion pressure, coating distance and powder feed rate were more than 25% and indicated a similar contribution rate, but the contribution rate of the gun speed was 19%, which was slightly less than the others. The contribution rate with each parameter was only slightly significant. On the other hand, all four parameters were found to be important in the contribution rate aspects of the HVOF coating process.

• Clean Technology
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• v.20 no.4
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• pp.425-432
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• 2014

The effect of two important parameters of a catalytic membrane reactor (CMR), hydrogen selectivity and hydrogen permeance, coupled with an Ar sweep flow and an operating pressure on the performance of a water gas shift reaction in a CMR has been extensively studied using a one-dimensional reactor model and reaction kinetics. As an alternative pre-combustion $CO_2$ capture method, the feasibility of capturing a pressurized and concentrated $CO_2$ in a retentate (a shell side of a CMR) and separating a purified $H_2$ in a permeate (a tube side of a CMR) simultaneously in a CMR was examined and a guideline for a hydrogen permeance, a hydrogen selectivity, an Ar sweep flow rate, and an operating pressure to achieve a simultaneous capture of a concentrate $CO_2$ in a retentate and production of a purified $H_2$ in a permeate is presented. For example, with an operating pressure of 8 atm and Ar sweep gas for rate of $6.7{\times}10^{-4}mols^{-1}$, a concentrated $CO_2$ in a retentate (~90%) and a purified $H_2$ in a permeate (~100%) was simultaneously obtained in a CMR fitted with a membrane with hydrogen permeance of $1{\times}10^{-8}molm^{-2}s^{-1}Pa^{-1}$ and a hydrogen selectivity of 10000.

• Clean Technology
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• v.27 no.3
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• pp.207-216
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• 2021

Major anthropogenic emissions of elemental mercury (Hg⁰) occur from coal-fired power plants, and the emissions can be controlled successfully using NH₃-SCR (selective catalytic reduction) systems with catalysts. Although the catalysts can easily convert the gaseous mercury into Hg²⁺ species, the reactions are greatly dependent on the flue gas constituents and SCR conditions. Numerous deNO_xing catalysts have been proposed for considerable reduction in power plant mercury emissions; however, there are few studies to date of elemental mercury oxidation using SCR processes with MW- and full-scale coal-fired boilers. In these flue gas streams, the chemistry of the mercury oxidation is very complicated. Coal types, deNO_xing catalytic systems, and operating conditions are critical in determining the extent of the oxidation. Of these parameters, halogen element levels in coals may become a key vehicle for obtaining better Hg⁰ oxidation efficiency. Such halogens are Cl, Br, and F and the former one is predominant in coals. The chlorine exists in the form of salts and is transformed to gaseous HCl with a trace amount of Cl₂ during the course of coal combustion. The HCl acts as a very powerful promoter for high catalytic Hg⁰ oxidation; however, this can be strongly dependent on the type of coal because of a wide variation in the chlorine contents of coal.

• Smart Media Journal
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• v.13 no.6
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• pp.54-61
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• 2024

Recently, due to the increase in domestic and international online e-commerce platforms and the increase in container traffic at domestic ports, the operating ratio of large trucks has increased, and the number of truck fires is continuously increasing. In particular, spontaneous combustion is the most common cause of truck fires. Various academic approaches have been attempted to prevent truck fires, but due to the lack of research on the spontaneous tire ignition phenomenon that occurs during braking, this research directly designed and manufactured an experimental device to establish an environment similar to the braking system of a truck. A non-contact temperature sensor was installed on the brake device of the experimental device to collect temperature data generated from the brake device. Based on the data collected from the temperature sensor of the brake device and the temperature sensor on the tire surface, the ARIMA model among the time series prediction models was used to Appropriate parameters were selected to suit the temperature change trend, and as a result of comparing and analyzing the measured and predicted data, an accuracy of over 90% was obtained. Based on this, a plan was proposed to reduce the rate of fires in trucks by providing real-time warnings and support for truck drivers to respond to overheating phenomena occurring in the braking system.