• Journal of the korean Society of Automotive Engineers
• /
• v.7 no.2
• /
• pp.55-63
• /
• 1985

This study is focused on deposition process leading to inefficiency and hot corrosion in fossil fuel-fired furnaces and engines. An improved understanding of the coupled thermodynamics, kinetics, and transport processes governing the deposition rate of inorganic oxides and salts from hot gases containing these compounds can suggest more efficient test strategies and control measures. Accordingly, an optical re-evaporation method for accurately measuring the growth rate of deposits under laboratory burner conditions has been developed. To demonstrate the technique and provide data suitable for theoretical model development, a deliberately simple chemical system and target geometry are used. Potassium sulfate(K$_{2}$SO$_{4}$)is introduced into a premixed propane-air flat flame at atmospheric pressure. The growth rate of $K_{2}$SO$_{4}$ on an electrically heated Pt ribbon is measured by re-evaporation technique.

• Journal of the korean Society of Automotive Engineers
• /
• v.14 no.2
• /
• pp.54-64
• /
• 1992

During combustion process in a diesel engine radiation heat transfer is the same order of magnitude as the convection heat transfer. An approximation of heat and momentum source distributions is applied at a level consistent with those used in modelling the soot distribution and the turbulence instead of modelling the fuel spray and the chemical kinetics. This paper illustrates a use of the third order spherical harmonics approximation to the radiative transfer equation and delta-Eddington approximation to the scattering phase function for droplets in the flow. Results are obtained numerically by a time marching finite difference scheme. This study aims to compare heat transfer with convection heat transfer and to investigate the importance of scattering by fuel droplets and of accounting for spatial variations in the extinction coefficient on the radiative heat flux distributions at the walls of a disc shaped diesel engine.

• 한국연소학회:학술대회논문집
• /
• 2012.11a
• /
• pp.129-132
• /
• 2012

Computation is performed to predict number density, volume fraction and size distribution of soot particles in typical operating conditions of a diesel engine. KIVA has been integrated with the CMC routine to consider turbulence/chemistry coupling and gas phase kinetics for heat release and soot precursors. The compositions of soot precursors are estimated by tracking Lagrangian particles to consider spatial inhomogeneity and differential diffusion in KIVA. The soot simulator SWEEP is employed as a postprocessing step to calculate conditional and integral quantities of soot particles.

• 한국연소학회:학술대회논문집
• /
• 2012.11a
• /
• pp.141-143
• /
• 2012

The present study is aiming at numerically analyze the soot formation processes coupled with gas reaction mechanism in turbulent non-premixed and partially premixed flames. In order to realistically represent turbulence-chemistry interactions with detailed chemical kinetics and soot formation behaviour related to the turbulent non-premixed and partially premixed flames, the transient flamelet[1] and flamelet based level-set approach[2] are coupled with soot formation based on the two equation model [3] and DQMOM (Direct Quadrature Method of Moment)[4].

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.1 no.4
• /
• pp.171-181
• /
• 1977

This paper is aiming at calculating NOx concentration, which is one of the harmhul components of emission from the gasoline engine, formed in the combustor through the presess of combustion. Instantaneous temperature and concentration of each components for each division can be determined by the solution of simulatneous equation of reaction equation and equation of energy conservation, inputting the estimated temperature with a considerably wide rage of temperature. After determining instantaneous temperature and instantanous concentration of each components, the nonequilibrium calculation is performed based on the reaction kinetics in order to determine NOx concentration. To summarize the result abtained from the above method ;through the passage of NO concentration, NO concentration is the highest in the first division and it is gradually decreasing through the following divisions In the final division, NO concentation is the lowest.

• 한국전산유체공학회:학술대회논문집
• /
• 1999.11a
• /
• pp.59-64
• /
• 1999

The Equations of Chemical kinetics ate very stiff, which forces the use of an implicit scheme. The problem of implicit scheme, however, is that the jacobian must be solved at each time step. In this paper, we examined the approximate chemical jacobian methods such as Gauss-Seidel, Jacobi partial jacobian and diagonalized jacobian that can be stable without full jacobian, We show that Gauss-Seidel jacobian method is stable and accurate as well as full jacobian and that this is more efficient in supersonic combustion problem about $20\%$ than the full jacobian method with same accuracy,

• Proceedings of the KSME Conference
• /
• 2003.11a
• /
• pp.350-355
• /
• 2003

Flame onset and propagation within hydrogen premixed gas mixture are numerically investigated in an rectangular enclosure. A detailed chemistry for hydrogen reaction is applied to anticipate the thermochemical behavior of intermediate species appropriately. To facilitate computation, 10 species and 16 elementary reaction steps for hydrogen combustion are taken into account. On the basis of 30 % of hydrogen concentration in hydrogen-air mixture, the effects of position and quantity of ignition sources on the flame evolution are analyzed. From the simulation results, the means that can lessen the possible hazard caused by flame propagation are suggested.

• 한국연소학회:학술대회논문집
• /
• 2006.04a
• /
• pp.205-212
• /
• 2006

Three-dimensional numerical study was carried out for the investigation of the detonation wave structures propagating in tubes. Fluid dynamics equations and conservation equation of reaction progress variable were analyzed by a MUSCL-type TVD scheme and four stage Runge-Kutta time integration. Chemical reaction was modeled by using a simplified one-step irreversible kinetics model. The variable gas properties between unburned and burned states were considered by using variable specific heat ratio formulation. The unsteady computational results in three-dimension show the detailed mechanisms of rectangular and diagonal mode of detonation wave instabilities resulting same cell length but different cell width in smoked-foil record. The results for the small reaction constant shows the spinning mode of three-dimensional detonation wave dynamics, which was rarely observed in the previous numerical simulation of the detonation waves.

• Journal of Korean Society for Atmospheric Environment
• /
• v.16 no.6
• /
• pp.665-674
• /
• 2000

A major source of the hazardous waste generated is from chemical industries producing plastics, herbicides, pesticides and chlorinated solvents. All of these processes produce a class if hazardous waste termed the chlorinated hydrocarbons(CHCs), either directly or from undesirable side reactions. In this study, we investigated the destruction characteristics of hazardous waste through incineration. A nonequilibrium combustion model was used to describe the effect of the chemical kinetics due to the flame inhibition characteristics of $CCl_4$ which was used as the surrogate of hazardous waste. A parametric screening studies was made in a dump incinerator proposed in this study. The dump incinerator showed high $CCl_4$ DRE(Destruction and Removal Efficiency) as 5 nines. $CCl_4$/CH$_4$ ratio appeared to be most important in the destruction of $CCl_4$ through incineration.

• Journal of Energy Engineering
• /
• v.18 no.4
• /
• pp.239-246
• /
• 2009

A fundamental investigation has been conducted on the combustion of single particle of a sub-bituminous coal char burning at different temperatures and residence times. The lab-scale test setup consisted of a drop tube furnace where gas temperatures varied from $900^{\circ}C$ to $1400^{\circ}C$. A calibrated two color pyrometer, mounted on the top of the furnace, provided temperature profiles of luminous particle during a char oxidation. An amount of char mass reacted during the reaction is measured with thermogravimetry analyzer by using an ash tracer method. As a result, mass and area reactivity as well as reaction rate coefficients are determined for the char burning at atmospheric pressure condition.