• Journal of Korean Society of Environmental Engineers
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• v.39 no.11
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• pp.607-612
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• 2017

The effect of carbonic anhydrase on $CO_2$ absorption rates and the heat of reaction were evaluated in various amine solutions for post combustion $CO_2$ capture process. The $CO_2$ absorption rate was analyzed in 30 wt% MEA, AMP, DMEA, MDEA aqueous solutions with and without carbonic anhydrase (250 mg/L) from bovine erythrocyte. $CO_2$ absorption rates were increased in all solutions with carbonic anhydrase. The effect of carbonic anhydrase on absorption rates was more in tertiary amine (DMEA and MDEA) solutions than in primary amine (MEA) and hindered amine (AMP) solutions. The heat of reaction of MEA, DMEA, MDEA aqueous solutions with and without carbonic anhydrase were measured using reaction calorimeter. Carbonic anhydrase decreased the heat of absorption in all solutions. The results suggested that tertiary amines that have the excellent desorption ability were suitable for applying carbonic anhydrase to the post combustion $CO_2$ capture process and the effect of carbonic anhydrase was best in MDEA solution.

• Journal of the Korean Society of Marine Environment & Safety
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• v.26 no.7
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• pp.915-921
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• 2020

Thermoacoustic instability caused by air conditioning in a combustion chamber has emerged as a problem that must be solved to establish a stable combustion system. Thermoacoustic instability is largely divided into primary and secondary acoustic instability. In this study, an experimental study of the effects of heat losses was conducted to investigate the mechanism of secondary acoustic instability. To generate the secondary acoustic instability, a quarter-wavelength resonator with one open end and one closed end was used, and the inside of the resonator was filled with premixed gases. Subsequently, secondary acoustic instability with downward-propagating flames could be realized via thermal expansion on the burnt side. To control heat losses qualitatively, an additional co-axial tube was installed in the resonator with air or nitrogen supply. Therefore, additional diffusion flames can be formed at the top of the resonator depending on the injection of the oxidizer into the co-axial tube when rich premixed flames are used. Consequently, secondary acoustic instability could not be achieved by increasing heat losses to the ambient when the additional diffusion flame was not formed, and the opposite result was obtained with the additional diffusion flame.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.29 no.9 s.240
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• pp.997-1005
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• 2005

The extinction characteristics of low strain rate normal gravity (1-g) nonpremixed methane-air flames were studied numerically and experimentally. A time-dependent axisymmetric two-dimensional (2D) model considering buoyancy effects and radiative heat transfer was developed to capture the structure and extinction limits of 1-g flames. One-dimensional (1D) computations were also conducted to provide information on 0-g flames. A 3-step global reaction mechanism was used in both the 1D and 2D computations to predict the measured extinction limit and flame temperature. A specific maximum heat release rate was introduced to quantify the local flame strength and to elucidate the extinction mechanism. Overall fractional contribution by each term in the energy equation to the heat release was evaluated to investigate the multi-dimensional structure and radiative extinction of 1-g flames. Images of flames were taken for comparison with the model calculation undergoing extinction. The two-dimensional numerical model was validated by comparing flame temperature profiles and extinction limits with experiments and ID computation results. The 2D computations yielded insight into the extinction mode and flame structure of 1-g flames. Two combustion regimes depending on the extinction mode were identified. Lateral heat loss effects and multi-dimensional flame structure were also found. At low strain rates of 1-g flame ('Regime A'), the flame is extinguished from the weak outer flame edge, which is attributed to multi-dimensional flame structure and flow field. At high strain rates, ('Regime B'), the flame extinction initiates near the flame centerline due to an increased diluent concentration in reaction zone, which is the same as the extinction mode of 1D flame. These two extinction modes could be clearly explained with the specific maximum heat release rate.

• Journal of Energy Engineering
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• v.12 no.3
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• pp.223-230
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• 2003

A study was performed to measure and analyze the gas-side fouling of heat exchanger to cool the exhaust gas from sludge incinerator at ironworks. The incinerator gas passes through inside of the vertical tubes of heat exchanger to preheat the combustion air. This kind of fouling occurs at the entrance region of the heat exchanger and thus the perforated fouling plate was designed to measure the gas-side fouling and to analyze the particulate deposit. As a result of analysis, the particulate deposition rate was influenced by temperature, particulate composition and size and also the deposition patterns were different according to the location of perforated fouling plate. The computational analysis was performed to obtain the deposition rates at the perforated fouling plate and the calculation showed that the deposition rate was varied with the hole size and particulate size. It was proved that the fouling at the entrance region of heat exchanger could be measured by the perforated fouling plate designed in this study.

• Journal of Energy Engineering
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• v.19 no.3
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• pp.182-187
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• 2010

This study was the effect of inserting CO tube on $NO_x$ and CO emission characteristics in a compact combustion chamber. In detail, $NO_x$ and CO emission characteristics with changing of distance due to inserting CO tube between a burner and a main heat exchanger were investigated. For this study, the commercial program, FLUENT with GRI 2.11 detail reaction mechanism, was used for the numerical study and a commercial heat exchanger was tested for the experimental study. As results, when the CO tube was inserted between a burner and a main heat exchanger, it was verified that $NO_x$ and CO emissions was decreased simultaneously as CO tube was closed to a burner and the distance between CO tube and a main heat exchanger was increased.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2006.05a
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• pp.275-278
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• 2006

Systematic experiments in $CH_4/Air$ counterflow diffusion flames diluted with He have been undertaken to study the oscillatory instability in which lateral heat loss could be remarkable at low global strain rate. The oscillatory instability arises for Lewis numbers greater than unity and occurs near extinction condition. The dynamic behaviors of extinction in this configuration can be classified into three modes; growing, harmonic and decaying oscillation mode near extinction. As the global strain rate decreases, the amplitude of the oscillation becomes larger. This is caused by the increase of lateral heat loss which ran be confirmed by the reduction of lateral flame size. Oscillatory edge flame instabilities at low global strain rate are shown to be closely associated with not only Lewis number but also heat loss (radiation and lateral heat loss).

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.10
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• pp.4679-4684
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• 2013

Compared with internal combustion engine, the electric vehicle has a limitation of low driving range due to low battery capacity due to relatively low energy density. Moreover, the energy consumption rapidly increases up to 30% during winter season with operating electric heater. In this study, electric vehicle performance was evaluated using heat pump having higher energy efficiency rather than electric heater for cabin heating. Electric vehicle system and heat pump system were developed using 1-D simulation software called AMESim, the simulation result indicated that the energy consumption could be reduced approximately 66% when the electric heating system was replaced with the heat pump system. As a result, the driving range is expected to increase the similar value. This study proved the merit of heat pump for cabin heating in electric vehicle, and it could contribute to developing suitable heating method for electric vehicles.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.33 no.3
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• pp.107-113
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• 2005

A calorimeter of 2-ton thrust level rocket engine chamber has been developed to measure the wall heat flux. The liner of the chamber is made of copper-chromium alloy to maximize the heat transfer performance and structural strength. 1-D design code based on empirical correlations has been used for the prediction of the global thermal characteristics while 3-D CFD has been applied for the verification of local cooling performance. The predicted average wall heat flux at the throat is 43 $MW/m^{2}$ for the combustion chamber pressure of 53 bar. The chamber structure is confirmed to be safe at the pressure of 150 bar through 2-D stress analysis and measurement of the strain of the test species. Finally, the test of pressurizing the calorimeter chamber has been performed with water at the pressure of 150 bar in room temperature environment. No thermal damage has been detected after the hot-fire test in the test nozzle of same cooling performance with the developed calorimeter though the measured throat heat flux is higher than the design value by 10%.

• Transactions of the Korean hydrogen and new energy society
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• v.19 no.2
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• pp.103-110
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• 2008

The most failure mode of PEM fuel cell is gas crossover caused by pinhole formation in MEAs. The degradation phenomena of MEA with pinholes were evaluated in various accelerated operation condition, such as OCV, low humidity and high partial pressure of oxygen. The performances of MEA with pinholes were almost same before and after normal 144 hours operation($70^{\circ}C$, $640mA/cm^2$, 65%RH $H_2/air$). The results of accelerated operation showed that OCV and low humidity condition more deteriorated MEA than gas crossover owing to pinholes. When oxygen was used as cathode gas, the pinholes of MEA were enlarged due to heat of combustion reaction on Pt catalyst of electrodes. This combustion reaction occurred at pinholes near gas inlet and resulted in local MEA failure.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.3452-3457
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• 2007

Experiments were carried out in an atmopheric pressure, lab-scale gas turbine combustor to see the effect of partial premixing on unstable flame structure and $NO_X$ emission characteristics. The swirl angle is 45 deg., fuel-air mixing degrees were varied 0, 50, and 100% respectively at equivalence ration ranging from 0.53 to 0.79. The evaluation of phased-locked OH chemiluminescence images were acquired with an ICCD. $NO_X$ emission characteristics were also investigated at each experimental condition. The effect of the fuel-air mixing degree on the flame structure was obtained from phase-locked $OH^*$ images. And it was obtained from local heat release characteristics that the information about the region which the combustion instability was amplified or damped. It also could be confirmed that ${\sigma}$ has greatly influence on $NO_X $emission characteristics at lean regimes. It would be expected that it could provide invaluable data for understanding the mechanism of combustion instability