• Clean Technology
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• v.22 no.3
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• pp.161-167
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• 2016

Catalytic combustion of benzene over various metal cation-exchanged zeolites has been investigated. Y(4.8)-type zeolite showed the highest activity among the used zeolites and Cu/Y(4.8) catalyst also showed the highest activity among metal cation/ Y(4.8) zeolites. The catalytic activity increased according to the amount of adsorbed oxygen acquired from O₂ TPD results. The catalytic activity also increased with an increase of Cu cation concentration on Cu/Y(4.8) catalysts. The conversion of benzene on the combustion reaction depended on not benzene concentration but the oxygen concentration. In addition, the introduction of water into reactants decreased the catalytic activity.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.11a
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• pp.134-137
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• 2009

Combustion tests of a low thrust rocket engine was performed to get combustion characteristics, which used a high concentrated hydrogen peroxide and kerosene as the oxidizer and fuel. The engine consisted of multi injector(six coaxial swirl injectors), chamber, nozzle and catalyst ignition system. The test was carried out by changing O/F ratio from 3.8 to 11.0. The experimental results showed that combustion efficiency was highest at O/F ratio from 5 to 6 and pressure fluctuations of all the range were lower than 5%.

• Journal of the Korea Institute of Military Science and Technology
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• v.13 no.6
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• pp.1180-1187
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• 2010

In the last decade, hydrogen peroxide has received renewed interest as a green propellant which is non-toxic, environmentally clean and relatively easy to handle. This study was performed to acquire the design technique and combustion performance of a 200N bi-propellant engine using hydrogen peroxide and kerosene. The engine which used a catalytic ignition method was designed and cold flow tests were carried out to investigate atomization characteristics. Combustion tests including a pulse mode operation were performed to investigate the combustion performance on various O/F ratios. The results showed that the combustion efficiency and the repeatability of the engine performance were enough to use as an essential database for the development of a high performance engine.

• Journal of ILASS-Korea
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• v.28 no.2
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• pp.55-61
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• 2023

Natural gas is a high-octane fuel that is effective in controlling knocking combustion. In addition, as a low-carbon fuel with a high hydrogen-carbon ratio, it emits less carbon dioxide and almost no particulate matter compared to conventional fossil fuels. Stoichiometric combustion engines equipped with a three-way catalyst are useful in various fields such as transportation and power generation because of their excellent exhaust emission reduction performance. However, stoichiometric combustion engines have a disadvantage of lower thermal efficiency compared to lean combustion engines. In this study, a combination of high compression ratio and Atkinson cycle was implemented in a 11 liter, 6-cylinder, spark-ignition engine to improve the thermal efficiency of the stoichiometric engine. As a result, pumping and friction losses were reduced and the operating range was extended with optimized Atkinson camshaft. Based on the exhaust gas limit temperature of 730℃, the maximum load and thermal efficiency were improved to BMEP 0.66 MPa and BTE 35.7% respectively.

• Transactions of the Korean Society of Automotive Engineers
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• v.19 no.3
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• pp.146-153
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• 2011

American NREL (National Renewable Energy Laboratory) reported that BDF20 could reduce PM, CO, SOx, and cancerogenic matters by 13.6%, 9.3%, 17.6%, and 13% respectively, compared to diesel fuel. BDF20 has been being tested on garbage trucks and official vehicles at Seoul City, which is positive on air environment, but negative on combustion by higher viscosity in winter season. This study investigated the combustion characteristics by applying pilot injection for improving the deterioration of combustibility caused by the higher viscosity of the BDF20 with the combustion flames taken by a high-speed camera and the cylinder pressure diagram. A 4-cycle single-cylinder diesel engine was remodeled to a visible 2-cycle engine taking the flame photographs, which has a common-rail injection system. The test was done laboratory temperature at $5{\sim}6^{\circ}C$. The results obtained are summarized as follows, (1) In the case of without pilot injection, the flame propagation speed was slowed and the maximum combustion pressure became lower. The phenomena became further aggravated as the fuel viscosity gets higher. (2) In the case of with pilot injection, early stage of combustion such as rapid ignition timing and flame propagation was activated since intermediate products formed by pilot injection act as a catalyst for combustion of main fuel.

• Korean Chemical Engineering Research
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• v.44 no.4
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• pp.404-409
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• 2006

The catalytic combustion of toluene over Pd-Cu/USY zeolite has been examined by using FT-IR spectroscopy in a closed system under dry and humid conditions. The catalytic combustion of toluene (700 ppmv) in the temperature range of $80-220^{\circ}C$ has been investigated by using a fixed bed reactor. The Pd-Cu/USY catalyst showed the highest catalytic performance with respects to the PdO-CuO/USY and Pd/USY. Comparing to $PdO/Al_2O_3$ catalysts, the slight improvement in conversion was observed over PdO/USY catalysts under humid condition since USY zeolite is hydrophobic substrate and water give an additional oxygen source to zeolite surface like oxygen. The reduced catalysts showed more enhanced catalytic activity due to the reduced activation energy of combustion of toluene than oxidized catalysts such as PdO/USY and PdO-CuO/USY.

• 한국연소학회:학술대회논문집
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• 2004.11a
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• pp.217-222
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• 2004

In recent year, as the current and future emission regulations go stringent, the research of exhaust manifold and CCC has become the subject of increasing interest and attention. This study is concerned with the systematic approach to improve catalyst flow uniformity and light-off behavior through the basic understanding of exhaust flow characteristics. Computational approach to the unsteady compressible flow for exhaust manifold of 4-1 type and 4-2-1 type and CCC system of a 4-cylinder DOHC gasoline engine was performed to investigate the flow distribution of exhaust gases. In this study, through calculation, the effects of geometric configuration of exhaust manifold on flow structure and its maldistribution in monolith were mainly investigated to understand the exhaust flow patterns in terms of flow uniformity. Based on the design guidance resulting from this fundamental study, the flow uniformity of 4-2-1 type exhaust manifold demonstrated the more improved exhaust characteristics than that of the 4-1 type one.

• Carbon letters
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• v.14 no.2
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• pp.99-104
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• 2013

We investigated the effects of parametric synthesis conditions of catalysts such as sintering temperature, sorts of supports and compositions of catalysts on alignment and length-control of carbon nanotubes (CNTs) using catalyst powders. To obtain aligned CNTs, several parameters were changed such as amount of citric acid, calcination temperature of catalysts, and the sorts of supports using the combustion method as well as to prepare catalyst. CNTs with different lengths were synthesized as portions of molybdenum and iron using a chemical vapor deposition reactor. In this work, the mechanisms of alignment of CNTs and of the length-control of CNTs are discussed.

• 유체기계공업학회:학술대회논문집
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• 2002.12a
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• pp.482-485
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• 2002

Development projects in KAIST rotted to the micro thermal device is introduced. Multi disciplinary research team is composed by combustion group and semiconductor group in KAIST and catalyst research center in KRICT to develop micro thermal/fluidic device and various items are on development. Among the projects, various kind of componenst that is required by the micro thermal devicesystem is introduced. Technology related to development of micro combustor, Micro igniter, micro fabrication of 3D structure, micro reactor and micro catalyst preparation is introduced.

• 한국신재생에너지학회:학술대회논문집
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• 2006.11a
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• pp.477-480
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• 2006

In this study, we investigated operating characteristics of the LNG burner for steam methane reforming. The developed LNG burner and catalytic reactor to supply an efficient heat transfer between the combustion gas and catalyst got a good response of various operating load within 5-7 minute and high efficiency for steam methane reforming as a conversion of methane over 90%. We calculated the volume of catalyst for $1Nm^3/hr$ steam LNG reforming as $211cc/(Nm^3/hr\;H_2)$ and got the operating condition and design data of the burner and steam reforming for LNG.