• Title/Summary/Keyword: Combustion carbon

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Source Identification of Ambient PM-10 Using the PMF Model (PMF 모델을 이용한 대기 중 PM-10 오염원의 확인)

  • 황인조;김동술
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.6
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    • pp.701-717
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    • 2003
  • The objective of this study was to extensively estimate the air quality trends of the study area by surveying con-centration trends in months or seasons, after analyzing the mass concentration of PM-10 samples and the inorganic lements, ion, and total carbon in PM-10. Also, the study introduced to apply the PMF (Positive Matrix Factoriza-tion) model that is useful when absence of the source profile. Thus the model was thought to be suitable in Korea that often has few information about pollution sources. After obtaining results from the PMF modeling, the existing sources at the study area were qualitatively identified The PM-10 particles collected on quartz fiber filters by a PM-10 high-vol air sampler for 3 years (Mar. 1999∼Dec.2001) in Kyung Hee University. The 25 chemical species (Al, Mn, Ti, V, Cr, Fe, Ni, Cu, Zn, As, Se, Cd, Ba, Ce, Pb, Si, N $a^{#}$, N $H_4$$^{+}$, $K^{+}$, $Mg^{2+}$, $Ca^{2+}$, C $l^{[-10]}$ , N $O_3$$^{[-10]}$ , S $O_4$$^{2-}$, TC) were analyzed by ICP-AES, IC, and EA after executing proper pre - treatments of each sample filter. The PMF model was intensively applied to estimate the quantitative contribution of air pollution sources based on the chemical information (128 samples and 25 chemical species). Through a case study of the PMF modeling for the PM-10 aerosols. the total of 11 factors were determined. The multiple linear regression analysis between the observed PM-10 mass concentration and the estimated G matrix had been performed following the FPEAK test. Finally the regression analysis provided source profiles (scaled F matrix). So, 11 sources were qualitatively identified, such as secondary aerosol related source, soil related source, waste incineration source, field burning source, fossil fuel combustion source, industry related source, motor vehicle source, oil/coal combustion source, non-ferrous metal source, and aged sea- salt source, respectively.ively.y.

Combustion Characteristics of the 5 Herb Species in Youngdong Areas (영동지역 5개 초본 수종의 연소특성)

  • Lee, Hae Pyeong;Lee, Si-Young;Park, Young Ju
    • Journal of Korean Society of Forest Science
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    • v.98 no.3
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    • pp.290-296
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    • 2009
  • In this study, we considered the combustion of the various herbs in youngdong areas such as festuca ovina, isodeon japonicus, oplismenus undulatifolius, pueraria thunbergiana, and cirsium japonicum var. ussuriense using the ignition temperature tester, cone calorimeter, smoke density chamber. We confirmed that the range of ignition temperature was $400{\sim}455^{\circ}C$ and the time to ignition and flameout were not recorded. The total heat release of isodeon japonicus was highest and the smoke release of festuca ovina was highest, and the yield of CO and $CO_2$ of pueraria thunbergiana, and cirsium japonicum var. ussuriense were highest among the samples. As a result, we concluded that isodeon japonicus will impact the fire intensity and fire spread and festuca ovina, pueraria thunbergiana, and cirsium japonicum var. ussuriense will influence the refuge.

A Study of the Bituminous Coal Oxidation Factor in Large Scale Boilers for Estimating GHG Emissions

  • Lee, See-Hyung;Kim, Jin-Su;Lee, Jeong-Woo;Lee, Seung-Hee;Lee, Seong-Ho;Jeon, Eui-Chan
    • Asian Journal of Atmospheric Environment
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    • v.5 no.3
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    • pp.189-195
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    • 2011
  • Korea-specific GHG emissions should be estimated correctly in order to ensure effective measurement of climate change variables. The use of country-specific data that reflects fuel and technology characteristics is needed for accurate GHG emissions estimation. Oxidation factors are used to convert existing data into equivalent GHG emissions, and changes in these oxidation factors are directly related to changes in emissions. As such, the oxidation factor is one of the most important variables in using country-specific data to determine GHG emissions. In this study, the oxidation factor of bituminous coal in large scale boilers was estimated using 4,527 data points sampled from eight large-scale boilers that had been using bituminous coal for two years. The average oxidation factor was determined to be 0.997, which is lower than the oxidation factor of 1 that is recommended by the IPCC G/L for large scale boilers when estimating national GHG emissions. However, an oxidation factor less than 1 is assumed for fluidized bed boilers, internal combustion engines, and other small-scale boilers. Accordingly, studies on oxidation factor estimation should be continued to allow for accurate estimation of GHG emissions.

A Study on Diesel Engine Performance with Ar and $CO_2$ Addition (Ar과 $CO_2$ 첨가에 따른 디젤기관의 성능에 관한 연구)

  • 정영식;이상만;채재우
    • Transactions of the Korean Society of Automotive Engineers
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    • v.5 no.4
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    • pp.93-99
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    • 1997
  • The re quest to develop the engines that are able to run without air or with very little oxygen condition is raised with the interest of ocean science or the mines. This research had already be gun before the world war II, but had been stagnant owing to the appearance of nuclear power. Recycle diesel engines have ability to run under the above mentioned condition the recycle diesel engine recirculates exhaust gases into intake port and consumes additional oxygen supplied by oxygen tank. Carbon dioxide is controlled by the absorber. The combustion and emission characteristics of recycle diesel engines are quite different with conventional one because the working fluids of recycle diesel engines consist of Ar, $CO_2$ and $O_2$ as well as $N_2$. Recycle diesel engine is therefore different with general diesel engine from the viewpoint of intake air composition. It is required to investigate the effect of intake composition in the combustion and emission to know recycle diesel engine. In this study, NOx concentration, smoke and cylinder pressure are measured with the variation of Ar and $CO_2$ Reduces show that the addition of Ar reduces NOx but increases smoke. Otherwise $CO_2$ reduces smoke and NOX simultaneously. Only $CO_2$ increases the ignition delay and both gases increase fuel consumption Ar addition is superior to $CO_2$ addition for the performance of recycle diesel engine system but $CO_2$ has the avantage with respect to emission.

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Disposal and Waste-to-Fuel of Infected Poultry with Avian Influenza(AI) Using Thermal Hydrolysis Reaction (열가수분해 반응을 이용한 조류인플루엔자(AI) 감염 가금류의 사체처리 및 연료화)

  • Song, Chul-Woo;Kim, Nam-Chan;Jeong, Guk;Ryu, Jae-Keun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.24 no.4
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    • pp.49-57
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    • 2016
  • In this study, a thermal hydrolysis technology was used to treat the poultry carcasses that were killed due to Avian Influenza (AI) occurrence, as well as to determine the possibility of fueling for the resultant products. Experimental results showed that the poultry carcasses were liquefied except for sand, and showed the optimum efficiency at $190^{\circ}C$ and operating time of 60 minutes. It has been shown that liquid products obtained after thermal hydrolysis has good conditions for fuel conversion since it had high carbon contents and calorific value, as well as low ash content. In addition, it was possible to operate the thermal hydrolysis facility by using only the waste heat generated in the combustion without injecting the auxiliary fuel, and the exhaust gas generated in the combustion has a small influence on the atmosphere.

A Study of the Flame Transfer Function Characteristics using Cold-flow Transfer Function in a Partially Premixed Model Gas Turbine Combustor (부분 예혼합 가스터빈 연소기에서의 비연소 전달함수 계측으로부터의 화염전달함수 특성 파악)

  • Joo, Seongpil;Kim, Seongheon;Yoon, Jisu;Yoh, Jai-ick;Yoon, Youngbin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.5
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    • pp.54-60
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    • 2017
  • In order to identify the characteristics of the flame transfer function gain, cold-flow transfer function was introduced, which is the part of the combustion instability research. Nitrogen and carbon dioxide was used to obtain the cold-flow transfer function and input/output variables was measured by hot wire anemometry. Density and fluid flow rate affect the cold-flow transfer function gain and peak frequency. In addition, acoustic resonance frequency affects the peak frequency of gain in the fuel feeding line.

Estimation of Biomass Loss and Greenhouse Gases Emissions from Surface Layer Burned by Forest Fire (산불로 인한 지표층 연소량 및 온실가스 배출량 추정)

  • Lee, Byungdoo;Youn, Ho Jung;Koo, Kyosang;Kim, Kyongha
    • Journal of Korean Society of Forest Science
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    • v.101 no.2
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    • pp.286-290
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    • 2012
  • Globally, the forest fires are a significant contributor of carbon dioxide and other greenhouse gases in the atmosphere. In this study, fuel load consumed by forest fire and emission of green house gases were analysed in the surface layer. For this, remaining fuel was collected and weighed with the species (Japanese red pine, deciduous) and the forest fire types (surface fire, crown fire) in the 51 forest fires. 8,361 kg/ha fuel load was consumed in deciduous forest damaged by surface fire, and 8,055 kg/ha, 12,333 kg/ha in Japanese red pine burned by surface fire and crown fire. The combustion ratios were 78, 59, and 90%, respectively. 15,856 kg/ha the green house gases such as $CO_2$, $CH_4$, $CH_4$ in deciduous forest burned by surface fire was emitted and 14,834 kg/ha, 22,709 kg/ha in Japanese red pine burned by surface fire and crown fire.

Preparation and Thermal Performance of Fullerene-Based Lead Salt

  • Guan, Hui-Juan;Peng, Ru-Fang;Jin, Bo;Liang, Hua;Zhao, Feng-Qi;Bu, Xing-Bing;Han, Wen-Jing;Chu, Shi-Jin
    • Bulletin of the Korean Chemical Society
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    • v.35 no.8
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    • pp.2257-2262
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    • 2014
  • $C_{60}$ is widely investigated because of its unique structure. But its applications in solid propellant seem to be relatively neglected. $C_{60}$ has more outstanding features than carbon black which is widely used as a catalyst ingredient of solid propellant. To combine the advantages of fullerene and lead salts, another good composite in propellant catalysts, we synthesized a kind of fullerene phenylalanine lead salt (FPL) and explored its thermal performances by differential thermal analysis (DTA) and thermogravimetry analysis (TGA). The results show it undergoes four exothermic processes started from 408 K. Combined TGA and X-ray diffractometer (XRD), the decomposition mechanism of FPL was derived by TG-IR and comparing IR spectra of FPL and its residues after burned to $327^{\circ}C$, $376^{\circ}C$ and $424^{\circ}C$, respectively. Effect of FPL on the decomposition characteristic of hexogen (RDX), a type of explosive in propellant, has been investigated using DTA at different heating rate, which shows the decomposition temperatures of the explosive are all reduced by more than 20 K. The corresponding activation energy ($E_a$) is decreased by $30kJ{\cdot}mol^{-1}$. So FPL has potential application as a combustion catalyst in solid propellant.

Polychlorinated Dibenzo-p-dioxins and Polychlorinated Dibenzofurans in Marine Sediments from Mokpo Coastal Water of Korea

  • Moon, Hyo-Bang;Kang, Sung-Kyung;Seo, Won-Ju;Choi, Min-Kyu;Yu, Jun;Choi, Hee-Gu;Park, Jong-Soo
    • Fisheries and Aquatic Sciences
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    • v.10 no.2
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    • pp.93-101
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    • 2007
  • Concentrations of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) were determined in marine sediments from Mokpo coastal water of Korea. Total and toxic equivalent (TEQ) concentrations of PCDD/Fs ranged from 19.4 to 175pg/g dry weight and ranged from 0.195 to 2.87 pg WHO-TEQ/g dry weight, respectively. These PCDD/F concentrations were below the safety sediment value (20 pg TEQ/g dry weight) of chronic toxicity. A highly significant correlation between the concentrations of PCDD/Fs and total organic carbon (TOC) in marine sediments was observed. Overall PCDD/F concentrations in the sediments were elevated in rivers and at inner locations close to harbors, indicating that these contaminants derived from local discharges of human activities. PCDD/F concentrations measured in our study were lower than those in several industrialized areas in Korea. Nonparametric multidimensional scaling (MDS) ordination showed that combustion processes from industrial complexes are the major source of PCDD/Fs in Mokpo coastal water.

An Analysis on the Effect of Environmental Improvement on Replacing CNG Bus in Seoul with Electric Bus (서울의 CNG버스를 전기버스로 대체했을 때 환경 개선 효과 분석)

  • Choi, Byeong-Joo;Na, Hae-Joong;Choi, Uk-Don;Kim, Jong-Hae
    • Journal of IKEEE
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    • v.24 no.3
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    • pp.821-827
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    • 2020
  • In particular, vehicles with internal combustion engines of public transportation such as diesel and CNG buses are in urgent need of measures to reduce emissions as they have a long daily total mileage, long driving hours and a large number of vehicles. In this paper, the fuel consumption rate (km/kWh) was actually measured through road test of electric buses. Based on the measured values, CO2 emissions from internal combustion engines and electric buses were calculated per bus. In addition to environmental improvement effects such as the expected reduction of carbon dioxide compared to CNG buses when replacing city buses with electric buses, additional effects were analyzed when the replacement of CNG buses is expanded to electric buses.