• 한국연소학회지
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• 제21권4호
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• pp.23-29
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• 2016

Reactivity of gasification defined by bouardard reaction is critical parameter in efficiency of the gasifier. In this study, char reactivity of the gasification was derived from the experiments using the intrinsic reaction kinetics model. Pressurized wire mesh heating reactor (PWMR) can produce high temperature and high pressure conditions up to 50 atm and 1750 K, respectively and PWMR was designed to evaluate the intrinsic reaction kinetics of $CO_2$ gasification. In this study, Kideco and KCH (sub-bituminous Indonesian coal) were pulverized and converted into char. Experiments used the PWMR were conducted and the conditions of the temperature and pressure were 1373~1673 K, 1~40 atm. To distinguish the pressure effect from high pressurized condition, internal and external effectiveness factors were considered. Finally, the intrinsic kinetics of the Kideco and KCH coal char were derived from $n^{th}$ order reaction rate equations.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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• pp.59-62
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• 2014

Predicting coal combustion by computational fluid dynamics (CFD) requires a combination of complicated flow and reaction models for turbulence, radiation, particle flows, heterogeneous combustion, and gaseous reactions. There are various levels of models available for each of the phenomena, but the use of advanced models are significantly restricted in a large-scale boiler due to the computational costs and the balance of accuracy between adopted models. In this study, the influence of coal devolatilization model and turbulent mixing rate was assessed in CFD for a commercial boiler at 500 MWe capacity. For coal devolatilization, two models were compared: i) a simple model assuming single volatile compound based on proximate analysis and ii) advanced model of FLASHCHAIN with multiple volatile species. It was found out that the influence of the model was observed near the flames but the overall gas temperature and heat transfer rate to the boiler were very similar. The devolatilization rate was found not significant since the difference in near-flame temperature became noticeable when it was multiplied by 10 or 0.1. In contrast, the influence of turbulent mixing rate (constant A in the Magnussen model) was found very large. Considering the heat transfer rate and flame temperature, a value of 1.0 was recommended for the rate constant.

• 한국수소및신에너지학회논문집
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• 제17권4호
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• pp.403-408
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• 2006

The plate reformer consisting of combustion chamber and reforming chamber for 25 kW MCFC stack has been operated and computational fluid dynamics was applied to estimate reactions and thermal fluid behavior in the reformer. The methane air 2-stage reaction was assumed in the combustion chamber, and three step steam reforming reactions were included in the calculation. Flow uniformity, reaction rate and species distribution, and temperature distribution were analyzed. In particular, temperature distribution was compared with the measurements to show good agreement in the combustion chamber, however, inappropriate agreement in the reformer chamber.

• 한국수소및신에너지학회논문집
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• 제31권5호
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• pp.467-479
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• 2020

Various researches are being conducted to reduce greenhouse gases generated by the consumption of traditional energy resources. This study was conducted to numerically analyze the combustion characteristics and N-S reaction behavior with respect to the H₂ content of syngas composed of CO and H₂ in pressurized air combustion. A non-premixed opposed flow flame model was applied a modified detailed mechanism with S-chemistry was developed based on GRI 3.0 to simulate the syngas reaction. As the hydrogen content increased, the flame thickness increased due to the fast reactivity of hydrogen. In the rich region, NO and SO₂ were reduced by reaction with H radical and H bonding of NO was suppressed by the formation of HOSO.

• 한국수소및신에너지학회논문집
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• 제25권1호
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• pp.79-86
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• 2014

In Dimethyl Ether (DME) indirect production processes, DME have a reforming process to separate Methanol. DME has a high cetane number and Methanol has a high octane number. Each fuel has a different combustion characteristics and reactivity. So, this paper was investigated on the combustion characterisitics of DME and Methanol. Basically, Methanol has a effect of retarding ignition. However, Within 10% of total carbon mole number in DME, Methanol slightly changed the onset timing of Low Temperature Reaction (LTR) with increasing thermal-ignition preparation range. It means that controlling combustion phasing of DME can be possible without eliminated LTR. In case of IMEP, the ranges.

• 대한기계학회논문집B
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• 제20권3호
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• pp.1040-1049
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• 1996

The high loading combustion is accomplished by making the turbulent intensity strong and the scale small in the premixed combustor. The Da-mkoler number, which is decreased by short turbulent characteristic time or by long chemical reaction time, can make the distributed reaction flame. So we developed a doubled jet burner for high loading combustion. The doubled jet burner was designed to make the scale of the flame small by the effect of impingement and increasing shear stress with doubled jet. We investigated the turbulence characteristics of unburned mixture and visualized several flames with the typical schlieren photography. Then we studied the influence of several factors that related the scale of flame. Consequently, the doubled jet burner can make the eddy very small. And we can obtain the detail information of the flame scale through ADSF(the Average Distance between Successive Fringes) in the micro- schlieren photography. The ADSF is not a exact flame scale, but it has qualitative trend with increasing turbulent intensity. The ADSF is diminished remarkably with increasing turbulent intensity. The reason is that strong turbulent intensity makes the flame zone thick and flamelets numerous. We can confirm this fact by the signal analysis of ion currents.

• 한국자동차공학회논문집
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• 제16권6호
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• pp.74-80
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• 2008

A combustion of CAI engine is purely dominated by fuel chemical reactions. In order to simulate the combustion of CAI engine, it should be considered the effect of fuel components and chemical kinetics. So it needs enormous computational power. To overcome this problem reduced problem of needing massive computational power, chemical kinetic mechanism and multi-zone method is proposed here in this paper. A reduced chemical kinetic mechanism for a gasoline surrogate was used in this study for a CAI combustion. This gasoline surrogate was modeled as a blend of iso-octane, n-heptane, and toluene. For the analysis of CAI combustion, a multi-zone method as combustion model for a CAI engine was developed and incorporated into the computational fluid dynamics code, STAR-CD, for computing efficiency. This coupled multi-zone model can calculate 3 dimensional computational fluid dynamics and multi-zoned chemical reaction simultaneously in one time step. In other words, every computational cell interacts with the adjacent cells during the chemical reaction process. It can enhance the reality of multi-zone model. A greatly time-saving and yet still relatively accurate CAI combustion simulation model based on the above mentioned two efficient methodologies, is thus proposed.

• 한국화재소방학회논문지
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• 제13권3호
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• pp.3-17
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• 1999

산호제의 양이 충분치 못한 밀폐된 공간에서는 화재가 발생하지 않으리라는 기대를 깨고, 다공성 물질내부에서 공극안에 있는 산화제를 이용하여 서서히 연소되는 smoldering 반응을 통하여 대형 화재가 발생할 수 있다. 본 논문에서는 하나의 실제 화재 사건을 화재 조사 방법에 의하여 기술한 보고서를 바탕으로 하여 smoldering 연소가 화재의 발생에 미치는 영향을 예시하였으며, 예시된 사고의 smoldering 연소를 강제대류에 의한 하향식 역방향 smoldering으로 모델링하였다. 화학반응으로는 열분해가 없는 1 단계 반응이 채택되어, 온도 및 산화제의 공간적 분포와 smoldering의 전파속도를 수치적으로 모사하였다. 수치결과로서 유입되는 산화제의 양과 연료의 공극률이 반응지역의 전파속도를 결정하는 가장 우세한 인자로 파악되었다. 그러므로 smoldering 에 의한 화재 발생시 유입되는 산화제의 양과 연료의 공극률과의 관계를 알고 있다면 주어진 연료의 공극률에 대하여 유입되는 산화제의 양을 제어함으로써 불길로의 천이를 억제할 수 있음을 제시하고 있다.

• 한국세라믹학회지
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• 제41권1호
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• pp.76-80
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• 2004

분무연소합성법을 이용하여 나노 크기의 산화아연(ZnO) 콜로이드를 제조하였다. 연소반응을 위한 산화제로서 $Zn(NO_3)_2{\cdot}6H_2O$와 환원제(연료)로서 $CH_6N_4O$를 사용하였다. DTA/TGA를 이용하여 열분석을 행한 결과 $230^{\circ}C$에서 전구체 혼합물의 착화(ignition)에 의한 연소반응으로 생각되는 발열피크가 나타났다. 그러나 분무 연소 반응의 경우 ${\mu}m$ 크기의 액적들로 인해 착화를위한 분자 또는 기들의 함량이 상대적으로 적기 때문에 분무된 액적들의 착화를 위해 연소반응기의 온도를 $500^{\circ}C$로 유지하였다. 응집체의 형성을 억제하기 위하여 여과매체를 사용하여 액적의 개수 농도를 감소시켰으며, 에어로졸 입자의 체류시간을 2.5초로 조절하여 열 유체의 흐름을 층류로 유도하였다. 제조된 입자들의 모양은 모두 구형이었으며, 평균 입자 크기는 180nm이었다. XRD와 TEM 분석 결과 각각의 콜로이드들은 ZnO 고유의 결정성을 나타내고 있었으며, hexagonal 구조를 가지는 것으로 확인되었다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 제26회 KOSCO SYMPOSIUM 논문집
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• pp.119-127
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• 2003

In this study we propose an unsteady I-dimensional model of bed combustion with multiple solid phases, which confers a phase on each solid material. This model can be applied to a variety of bed combustion cases of various configurations and ignition methods. It contains fuel combustion, gaseous reaction, heat transfers between each phase, and geometric changes of the solid particles. An iron ore sintering pot is selected for verifying the model validity and simulation results are compared with the limited experimental data set of various coke contents and air supply rates. They predict the experimental results well and show applicabilities to the various system of the fuel bed with various solid materials.