• Title/Summary/Keyword: Columnar

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Effects of Deposition Variables on Plasma-Assisted CVD of TiN Films (TiN박막의 증착특성에 미치는 플라즈마 화학증착변수들의 영향)

  • 이정래;김광호;신동원;박찬경
    • Journal of the Korean Ceramic Society
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    • v.31 no.10
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    • pp.1188-1196
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    • 1994
  • TiN films were deposited onto high speed steel(SKH9) and silicon wafer by plasma-assisted chemical vapor deposition(PACVD) using a TiCl4/N2/H2/Ar gas mixture. The effects of deposition temperature, R.F. power, and H2 concentration on the deposition of TiN were studied. The residual chlorine content and the microhardness of TiN films were also investigated. It was found that TiN films grew with a columnar structure of a strong (200) preferred orientation regardless of the substrate type and the deposition variables. The TiN films consisted of columnar-grains of about 50 to 100 nm in diameter. The columnar grains themselves contained much finer fibrous grains. As deposition temperature increased, the residual chlorine content decreased sharply. R. F. powder enhanced the deposition rate largely. Increasing of H2 concentration had little effect on the residual chlorine.

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Effect of Surface Roughness on Nitriding of Aluminum by Electron Cyclotron Resonance Plasma (ECR 플라즈마에 의한 알루미늄 질화처리시 표면조도의 영향)

  • 김진수;안재현;고경현;오수기
    • Journal of the Korean institute of surface engineering
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    • v.24 no.4
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    • pp.215-221
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    • 1991
  • Microstructure evolution during low temperature vapor deposition exhibits wel-developed columnar structure mainly owing to geometrical shadowing effect of surface roughness. It is concluded that this structure is concided with many theoretical models suggested so far. In case of aluminum nitride film deposition consisted of etching and nitriding step employing ECR plasma, the rougher the surface before etching, the finer and more cone-and-whisker structure can be developed. In turn, this fine structure affects the formation and growth of columnar as well as offers many sites available for mechanical lock-up. Conclusively, the formation of well-defined columnar structures depends on the initial surface roughness.

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Effect of Columnar Structures on Exchange Anisotropy Field in Magnetoresistive NiO/NiFe Bilayers

  • Jai-Young Kim;Gyeong-Su Park;Jae-Chul Ro;Su-Jeong Suh
    • Journal of Magnetics
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    • v.4 no.3
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    • pp.88-91
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    • 1999
  • A series of NiO/NiFe bilayer films are deposited with the variation of Ar sputtering pressure for the NiO layers only. As the pressure for the NiO layers increases, the exchange anisotropy field (HEX) decreases gradually and becomes extinct at 2.5 mTorr, at which the maximum coercive force (HC) in the NiO/NiFe films is obtained. Randomly oriented columnar structures with HEX a few tens of Oe and oriented columnar structures with zero HEX are observed in the NiP layers by highvoltage hihg-resolution transmission electron microscopy. The vanishing of the HEX in the oriented structures is attributed to the lack of exchange anisotropy energy (EEX) between NiO and NiFe layers, which results in little contribution of interfacial unidirectional pinning anisotropy to the interface of NiO/NiFe bilayer.

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Intratesticular Simple cyst lined by ciliated columnar epithelium: A Case Report (섬모원주상피로 피복된 고환내 단순낭 1례)

  • Kim, Ji-Yoon;Lim, Hwa-Soo;Moon, Ki-Hak;Kim, Mi-Jin;Cho, Jae-Ho
    • Journal of Yeungnam Medical Science
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    • v.22 no.2
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    • pp.266-269
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    • 2005
  • An intratesticular simple cyst is a rare lesion. The pathogenesis of such lesions is uncertain. Clinically, an intratesticular simple cyst may be difficult to differentiate from a cystic neoplasm. However, preoperative diagnosis is possible using ultrasonography (US). Testis-sparing surgery with simple enucleation of the cyst has a favorable outcome. We report an intratesticular simple cyst in a 48-year-old male who had a non-tender cystic mass in the right testis for 2 years. The diagnosis was made by preoperative US. The patient underwent a testis-sparing surgery. After simple excision of the cyst, histological examination revealed a simple cyst lined by ciliated cuboidal and columnar epithelium.

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A True Cholesteric Columnar Liquid Crystal

  • Cho, I-Whan;Lim, Young-Soo
    • Bulletin of the Korean Chemical Society
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    • v.9 no.2
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    • pp.98-101
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    • 1988
  • A pure columnar cholesterogen based on the octasubstituted phthalocyanine $(PcH_2)$, S-(+)-2, 3, 9, 10, 16, 17, 23, 24-octakis[5-(dodecyloxy)-2-oxa-pentyl]-phthalocy anine(1a), is described. To evaluate a cholesteric character of 1a, the corresponding achiral $PcH_2$ 1b and the copper complex of chiral $PcH_2$ 1a (CuPc), S-(+)-2,3,9,10,16,17,23,24-octakis[4-(dodecyloxy)- 2-oxapentyl]-phthalocyanine(2a) were also prepared. The chiral 1a exhibited a typical cholesteric texture change in which the transition of platelet (blue phase) to fan-shape texture was observed (K-M-I), whereas the corresponding achiral 1b showed only a focal conic texture (K- M-I). This is the first instance of a pure columnar cholesterogen observed with discotic liquid crystal systems.

Cause of Rockfall at Natural Monument Pohang Daljeon-ri Columnar Joint (천연기념물 포항 달전리 주상절리의 낙석 발생원인)

  • Kim, Jae Hwan;Kong, Dal-Yong
    • Economic and Environmental Geology
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    • v.55 no.5
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    • pp.497-510
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    • 2022
  • Monthly monitoring, 3D scan survey, and electrical resistivity survey were conducted from January 2018 to August 2022 to identify the cause of rockfall occurring in Daljeon-ri Columnar Joint (Natural Monument No. 415), Pohang. A total of 3,231 rocks fell from the columnar joint over the past 5 years, and 1,521 (47%) of the falling rocks were below 20 cm in length, 978 (30.3%) of 20-30 cm, and 732 (22.7%) of rocks over 30 cm. While the number of rockfalls by year has decreased since 2018, the frequency of rockfalls bigger than 30 cm tends to increase. Large-scale rockfalls occurred mainly during the thawing season (March-April) and the rainy season (June-July), and the analysis of the relationship between cumulative rainfall and rockfall occurrence showed that cumulative rainfall for 3 to 4 days is also closely related to the occurrence of rockfall. Smectite and illite, which are expansible clay minerals, were observed in XRD analysis of the slope material (filling minerals) in the columnar joint, and the presence of a fault fracture zone was confirmed in the electrical resistivity survey. In addition, the confirmed fault fracture zone and the maximum erosion point analyzed through 3D precision measurement coincided with the main rockfall occurrence point observed by the BTC-6PXD camera. Therefore, the main cause of rockfall at Daljeon-ri columnar joint in Pohang is a combination of internal factors (development of fault fracture zones and joints, weathering of rocks, presence of expansive clay minerals) and external factors (precipitation, rapid thawing phenomenon), resulting in large-scale rockfall. Meanwhile, it was also confirmed that the Pohang-Gyeongju earthquake, which was continuously raised, was not the main cause.

GLOBAL EXISTENCE FOR A PARTIALLY LINEAR 3D EULER FLOW

  • Kim, Namkwon;Lkhagvasuren, Bataa
    • Journal of the Korean Mathematical Society
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    • v.55 no.1
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    • pp.211-224
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    • 2018
  • We consider a certain three dimensional Euler flow with infinite energy, which is sometimes called the columnar or two and half dimensional flow. We prove the global smoothness of such flow in ${\mathbb{R}}^3$ when the initial data is in some Sobolev or Besov spaces and ${\partial}_3u_3$ is nonnegative.

Ceramic Coating by Electron Beam PVD for Nanos-Tructure Control (나노구조 제어를 위한 EB-PVD법에 의반 세라믹스 코팅)

  • Matsbara, Hideaki
    • Ceramist
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    • v.9 no.6
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    • pp.24-29
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    • 2006
  • Electron beam physical vapor deposition (EB-PVD) process has currently been applied to thermal barrier coatings (TBCs) for aircraft engines. Due to unique columnar structure, EB-PVD TBCs have advantages in resistances to thermal shock and thermal cycle for their applications, compared to films prepared by plasma spray By the EB-PVD equipment, we successfully obtained yttria-stabilized zirconia (YSZ) layer which has columnar and feather like structure including a large amount of nano size pores and gaps. The EB-PVD technique has been developed for coating functional perovskite type oxides such as (La, Sr)MnO3. Electrode properties have been improved by interface and structural control.

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Synthesis and Mesomorphic Properties of Palladium(II) Complexes Based on 3,4,5-Trialkoxy Benzonitrile Ligands

  • 이명수;유용식;최문근
    • Bulletin of the Korean Chemical Society
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    • v.18 no.10
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    • pp.1067-1070
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    • 1997
  • The synthesis and characterization of the nitrile ligands 3,4,5-tridodecyloxy benzonitrile (7) and 3,4,5-trioctadecyloxy benzonitrile (8), and their corresponding palladium(Ⅱ) complexes are described. The nitrile ligands display only a crystalline phase and do not show liquid crystalline behavior, while their corresponding palladium(Ⅱ) complexes dispaly an enantiotropic columnar mesophase. The induction of the columnar mesophase is mainly due to dimerization through the palladium complexation of the half disk-like nitrile ligands giving rise to a trans square planar geometry.