• Title/Summary/Keyword: Column Form

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Separation Characteristics of Ibuprofen in Kromasil HPLC Column (Kromasil HPLC 칼럼을 이용한 Ibuprofen의 분리특성 연구)

  • Park Joon Sub;Kim Byung Lip;Yoon Tae Ho;Kim In Ho
    • KSBB Journal
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    • v.20 no.3
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    • pp.244-249
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    • 2005
  • Chiral separation of racemic ibuprofen was achieved on a Kromasil KR100-5CHI-TBB column. Some chromatographic parameters (resolution, number of theoretical plates, HETP, capacity factor) are calculated under different separation conditions such as change of mobile phase compositions (hexane / t-BME : 85 / 15, 75 / 15, 65 / 35, 55 /45) as well as acetic acid concentrations for adjusting pH (0.1 to 1 $v/v\%$). Flow rate versus number of theoretical plates and HETP were compared to evaluate column efficiency. To determine the adsorption isotherms, PIM (Pulsed Input Method) was carried out. At concentrations of racemic ibuprofen between 0.1 and 0.3 mg/ml, S- and R-ibuprofen have the same retention time of 4.48 and 5.81 min. Ibuprofen isotherms show a linear form under concentrations of 0.3 mg/ml with eluent (hexane / t-BME = 55 / 45).

Design tables and charts for uniform and non-uniform tuned liquid column dampers in harmonic pitching motion

  • Wu, Jong-Cheng;Wang, Yen-Po;Chen, Yi-Hsuan
    • Smart Structures and Systems
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    • v.9 no.2
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    • pp.165-188
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    • 2012
  • In the first part of the paper, the optimal design parameters for tuned liquid column dampers (TLCD) in harmonic pitching motion were investigated. The configurations in design tables include uniform and non-uniform TLCDs with cross-sectional ratios of 0.3, 0.6, 1, 2 and 3 for the design in different situations. A closed-form solution of the structural response was used for performing numerical optimization. The results from optimization indicate that the optimal structural response always occurs when the two resonant peaks along the frequency axis are equal. The optimal frequency tuning ratio, optimal head loss coefficient, the corresponding response and other useful quantities are constructed in design tables as a guideline for practitioners. As the value of the head loss coefficient is only available through experiments, in the second part of the paper, the prediction of head loss coefficients in the form of a design chart are proposed based on a series of large scale tests in pitching base motions, aiming to ease the predicament of lacking the information of head loss for those who wishes to make designs without going through experimentation. A large extent of TLCDs with cross-sectional ratios of 0.3, 0.6, 1, 2 and 3 and orifice blocking ratios ranging from 0%, 20%, 40%, 60% to 80% were inspected by means of a closed-form solution under harmonic base motion for identification. For the convenience of practical use, the corresponding empirical formulas for predicting head loss coefficients of TLCDs in relation to the cross-sectional ratio and the orifice blocking ratio were also proposed. For supplemental information to horizontal base motion, the relation of head loss values versus blocking ratios and the corresponding empirical formulas were also presented in the end.

A Study of Permanent Form System by Thin Precast Concrete Panel (II) (박판 프리캐스트 콘크리트 영구거푸집 시스템 연구 (II))

  • 남기룡;정문영;정문열;서치호;김윤일
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.10a
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    • pp.749-754
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    • 1997
  • Nowadays domestic building market has undergone several changes. Labor costs are too high and materials are in short supply. These raised building costs and therefore lowered productivity. At this point it is the best way to reduce manual labor and find alternative materials that can improve productivity. In the building process form work take the most part of it. So many formwork systems were developed to reduce the construction period and labor cost. But their technical improvements just limited to adjust form shape-the role of form is not changed. This research developed a new formwork systems that can function to unify or minimze the unit process with cast-in-place type permanent form. In former study (reported in '97 spring seminar), we did the assembling test with column and beam clamps. Furthermore, In this paper, we examined the total systems of form erections and evaluated the structural performances.

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A Study on the Flow and Control Characteristics of Magneticfluid in Actuator (액추에이터에서의 자성유체 제어 및 유동 특성에 관한 연구)

  • Kim, Joong;Chun, Un-hack;Lee, Hee-Sang;Lee, Bong-Gyu;Hwang, Seung-Sik;Oh, Chang-Bok
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.7
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    • pp.258-267
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    • 1999
  • The aim of the study is to provide fundamental information for the development of magneticfluid actuator. To achieve the aim, the force and dynamic characteristics of magenticfluid are investigated by experiment for the various of tube diameter, height and position of magneticfluid column in magneticfield according to supplied voltage of solenoid coil, wave form and frquency. From this study, actuating force of magneticfluid is generated by magneticfield. The magnitude of force increases as the intensity of magneticfield becomes strong and the center of magneticfield becomes lower than the center of magneticfluid column. And the force of magneticfluid relates to the volume of magneticfluid more than the height and diameter. The response delay time decreases as the height of magmeticfluid more than the height and diameter. The response delay time decrease as the height of magneticfluid column becomes longer and the center of magneticfield becomes lower than the center of magniticfluid column. But, the approaching time increases as supplied voltage becomes higher and the center of magneticfiled becomes higher than the center of magniticfluid column. The frequency generating maximum force is 1Hz and the critical frequency is about 4Hz.

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Evaluation of Improvement on Sediment for Practical Application in Prawn Farm (새우 양식장에 적용을 위한 저질개선 평가)

  • Kim Woo-Hang;Kim Doo Hee
    • Proceedings of KOSOMES biannual meeting
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    • 2004.05b
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    • pp.81-84
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    • 2004
  • Control of Sediment is very important in prawn farm due to the eruption of toxic material such as W1ionized H2S, NH3 and NO2-. In this study, column test study, column with filter media such as activated carbon, zeolite, oyster shell and iron chloride to evaluate the reduction of toxicity from sediment ammonia-N(NH3) was effectively removed by Zeolite and oyster shell. It was indicated that ammonium ion(NH4+) was removed by ion exchange of zeolite. And the ammonia in the column of oyster shell was existed as the form of NH4+, which is not toxic for prawn because oyster shell was stably kept around pH 8. Therefore, some of ammonia(NH3) was reduced by oyster shell. Hydrogen sulfide and COD were effectively removed by adsorption of activated carbon and a partial removal of hydrogen sulfide was accomplished by Oyster shell. Phosphorous was removed by activated carbon, oyster shell and iron chloride. In prawn farm, the concentration of ammonia was increased with increase of pH by algae photosynthesis in the column of activated carbon, zeolite and iron chloride, but it was revealed that pH was stably kept in the column of oyster shell.

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Simplified analytical model for flexural response of external R.C. frames with smooth rebars

  • Campione, Giuseppe;Cannella, Francesco;Cavaleri, Liborio;Monaco, Alessia
    • Structural Engineering and Mechanics
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    • v.66 no.4
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    • pp.531-542
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    • 2018
  • In this paper an analytical model in a closed form able to reproduce the monotonic flexural response of external RC beam-column joints with smooth rebars is presented. The column is subjected to a constant vertical load and the beam to a monotonically increasing lateral force applied at the tip. The model is based on the flexural behavior of the beam and the column determined adopting a concentrated plasticity hinge model including slippage of the main reinforcing bars of the beam. A simplified bilinear moment-axial force domain is assumed to derive the ultimate moment associated with the design axial force. For the joint, a simple truss model is adopted to predict shear strength and panel distortion. Experimental data recently given in the literature referring to the load-deflection response of external RC joints with smooth rebars are utilized to validate the model, showing good agreement. Finally, the proposed model can be considered a useful instrument for preliminary static verification of existing external RC beam-column joints with smooth rebars for both strength and ductility verification.

Transport behavior of PVP (polyvinylpyrrolidone) - AgNPs in saturated packed column: Effect of ionic strength and HA (포화 컬럼실험에서 이온강도 변화 및 유기물질 출현에 의한 PVP로 코팅된 은나노 입자의 거동 연구)

  • Heo, Jiyong;Han, Jonghun;Her, Namguk
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.3
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    • pp.263-270
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    • 2016
  • Recent Engineered nanoparticles were increasingly exposed to environmental system with the wide application and production of nanomaterials, concerns are increasing about their environmental risk to soil and groundwater system. In order to assess the transport behavior of silver nanoparticles (AgNPs), a saturated packed column experiments were examined. Inductively coupled plasma-mass spectrometry and a DLS detector was used for concentration and size measurement of AgNPs. The column experiment results showed that solution chemistry had a considerable temporal deposition of AgNPs on the porous media of solid glass beads. In column experiment, comparable mobility improvement of AgNPs were observed by changing solution chemistry conditions from salts (in both NaCl and $CaCl_2$ solutions) to DI conditions, but in much lower ionic strength (IS) with $CaCl_2$. Additionally, the fitted parameters with two-site kinetic attachment model form the experimental breakthrough curves (BTCs) were associated that the retention rates of the AgNPs aggregates were enhanced with increasing IS under both NaCl and $CaCl_2$ solutions.

Structural performance of reinforced concrete wall with boundary columns under shear load

  • Chu, Liusheng;He, Yuexi;Li, Danda;Ma, Xing;Cheng, Zhanqi
    • Structural Engineering and Mechanics
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    • v.76 no.4
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    • pp.479-489
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    • 2020
  • This paper proposed a novel form of reinforced concrete (RC) shear wall confined with boundary columns. The structural effect of applying steel fiber reinforced concrete (SFRC) in the wall-column systems was studied. Three full-scale wall samples were constructed including two RC wall-RC column samples with different stirrup ratios and one RC wall-SFRC column sample. Low frequency cyclic testing was carried out to investigate the failure modes, hysteretic behavior, load-bearing capacity, ductility, stiffness degradation and energy dissipation. ABAQUS models were set up to simulate the structural behavior of tested samples, and good agreement was achieved between numerical simulation and experimental results. A further supplementary parametric study was conducted based on ABAQUS models. Both experimental and numerical results showed that increasing stirrup ratio in boundary columns did not affect much on load bearing capacity or stiffness degradation of the system. However, applying SFRC in boundary columns showed significant enhancement on load bearing capacity. Numerical simulation also shows that the structural performances of RC wall-SFRC column system were comparable to a wall-column system fully with SFRC.

An approach for partial strengthening of circular RC columns using outer steel tube

  • Hwang, Ju-young;Kwak, Hyo-Gyoung
    • Steel and Composite Structures
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    • v.38 no.6
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    • pp.739-749
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    • 2021
  • This paper introduces an improved design equation to evaluate the resisting capacity of circular reinforced concrete (RC) columns partially strengthened with outer steel tube. When RC column members are required to be strengthened according to the change in the loadings considered and/or the deterioration progress in columns, wrapping up RC column with steel circular tube, which takes the form of concrete filled steel tube (CFST), has been popularly considered because of its structural advantage induced from the confinement effect. However, the relatively high construction cost of steel tube is restricting its use to the required region, while deriving the shape of a partial CFST column. To evaluate the resisting capacity of a partial CFST column, numerical analyses need to be performed, and a numerical model proposed in the previous study for the numerical analysis of full CFST columns is used to conduct parametric studies for the introduction of a design equation. The bond-slip effect developed along the interface between the in-filled concrete and the exterior steel tube is taken into consideration and the validity of the numerical model has been established through correlation studies between experimental data and numerical results for partial CFST circular columns. Moreover, parametric studies make it possible to introduce a design equation for determining the optimum length of outer steel tube which produces partial CFST circular columns.

A Study on the Structure and lateral Loading Capacity of Wooden Frame of Ancient Commoner's House (고대 민가의 구조 및 목조 프레임의 수평내력에 관한 연구)

  • 서정문;최인길;전영선;이종림;신재철;허택영
    • Journal of the Earthquake Engineering Society of Korea
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    • v.1 no.2
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    • pp.31-37
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    • 1997
  • Structural details of the three-bay-straw-roof house which was the most common form of residence as a commoner's house during ancient period are suggested. Wooden frames are used in the house. The typical form of joint used is Sagaemachum. The static lateral loading capacity of the frames is evaluated through the test on full scale models. The effects of joint type at the column head and wooden lattice on the lateral loading capacity and the failure modes of frames are analyzed. The ultimate lateral loading capacity and displacement of the ordinary frame at failure are 1.090 N and 400 mm(1/6rad), respectively. These values for the frame with high column are 4,160 N and 250 mm(1/9.6rad), respectively. The behavior of joint at column head controls the overall lateral loading capacity of the frame and shows very large nonlinearity. The general failure modes of joint for an ordinary frame and a frame with high column are shear and bending failure at the branches of Sagaemachum, respectively.

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