• Bulletin of the Korean Chemical Society
• /
• 제34권11호
• /
• pp.3377-3380
• /
• 2013

The spectrophotometric and electrochemical properties of tetraazo(p-carboxy)phenylcalix[4]arene (p-CAC) in the presence of various metal ions were investigated by UV/Vis spectroscopy and voltammetry in $CH_3CN$. p-CAC showed selective color changes to $Cu^{2+}$ over other metal ions from light orange to colorless, in accordance with hypsochromic shift in UV/Vis spectra. Voltammetric measurements also showed high selectivity for $Cu^{2+}$.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2000년도 하계학술대회 논문집 C
• /
• pp.1739-1741
• /
• 2000

DC current density-voltage and impedance spectroscopy studies have been performed on indium-tin-oxide(ITO)/para-sexiphenyl(6p)/aluminium organic electroluminescent device. The device exhibited a blue color emission, The turn-on voltage of the device is observed at 5V from the current density-voltage measurements. The impedance spectroscopy measurements show that a resonance frequency shift with applied DC bias is observed and a single semi-circle Cole-Cole plot is confirmed. The bias-dependent bulk resistance and bias-independent bulk capacitance is observed.

• 한국생산제조학회지
• /
• 제21권1호
• /
• pp.58-64
• /
• 2012

Instead of the surface pattern arranged repeatedly in two axial direction on a plane, we propose double patterns superposing two one-axial linear patterns as a reference target for surface encoding. A upper layer of the superposed pattern is the transparent glass with grooves cut in it at a fixed pitch. The position is sensed by detecting a shift of beam due to difference of a refractive index. And a lower layer is the aluminum with color-coated grooves. The amount of beam reflected on the layer varies according to its targeting position and is detected for encoding. For the above reference pattern, we can detect two-axial positions using only the single beam. Furthermore, the pattern size can be expanded with a size of the detector kept constant, meaning that the measured range can be expanded easily. In this paper, we review the existing optical encoding methods for grid pattern, and discuss the hardware implementation of the suggested surface encoding method.

• 소성∙가공
• /
• 제12권5호
• /
• pp.487-492
• /
• 2003

Tension variations with heat treatment in shadow mask for flat braun tubes are investigated in this study. In CRT, landing shift of the electron beam due to thermal deformation of the tension mask made the color purity of screen worse. In order to get the final results of thermal deformation, the tensile force within the mask and the welding processes between the rail and the extended mask have to be analysed sequentially. In this study, the effect of heat treatment is studied in terms of tension variations of shadow mask during its manufacturing process.

• Bulletin of the Korean Chemical Society
• /
• 제22권7호
• /
• pp.727-731
• /
• 2001

Conjugated-non-conjugated alternating block copolymers containing distyrylarylene units were synthesized via Wittig reaction for chemiluminescent fluorophores. The polymers were differentiated from others by the presence of aromatic unit in the chromophoric block. When UV-VIS, photoluminescence and chemiluminescence spectra of these materials were compared with copolymers, a strong bathochromic effect was observed. A more pronounced red shift and higher chemiluminscence efficiency were observed in the polymer with anthracene ring. Sodium salicylate-catalyzed reaction of bis(2-carbopentyloxy-3,5,6-trichlorophenyl) oxalate with hydrogen peroxide produced a strong chemiluminescence from blue to yellow-green light emission with wavelength of 450-537 nm in the presence of the fluorophore. The chemiluminescent intensity decayed exponentially. The glow of chemiluminescence maintained more than l2 hr and was visible with the naked eye.

• 식물병연구
• /
• 제27권1호
• /
• pp.38-44
• /
• 2021

Xylella fastidiosa is the most damaging pathogen in many parts of the world. To increase diagnostic capability of X. fastidiosa in the field, the loop-mediated isothermal amplification (LAMP) and polymerase chain reaction (PCR) assay were developed to mqsA gene of citrate-synthase (XF 1535) X. fastidiosa and evaluated for specificity and sensitivity. Both assays were more robust than current published tests for detection of X. fastidiosa when screened against 16 isolates representing the four major subgroups of the bacterium from a range of host species. No cross reaction with DNA from healthy hosts or other species of bacteria has been observed. The LAMP and PCR assays could detect 10-4 pmol and 100 copies of the gene, respectively. Hydroxynaphthol blue was evaluated as an endpoint detection method for LAMP. There was a significant color shift that signaled the existence of the bacterium when at least 100 copies of the target template were present.

• 폴리머
• /
• 제31권2호
• /
• pp.148-152
• /
• 2007

콜레스테릭 액정모노머를 이용하여 액정표시장치용 선택반사 칼라필터 원형을 개발하였다. 콜레스테릭 액정은 특정한 기판처리 조건에서 나선(helical twist) 구조를 갖는 액정으로서 피치와 비슷한 크기의 입사 파장을 반사시키는 독특한 선택반사의 광특성을 갖는다. 실험결과 R, G, B의 파장영역을 반사시키는 반구형으로 패턴된 콜레스테릭 반사 필름을 개발하여 그 반사파장의 피크 값을 살펴본 바, 시야각 방향 변화에 따라 적색, 녹색필름은 단파장쪽으로 반사파장 피크가 이동하였으며 청색의 경우 별다른 변화가 없었다. 포토리소그래피를 이용하여 포토레지스트(Photo-resist)를 thermal reflow방식으로 마이크로미터 크기의 반구형의 주기적인 패턴을 얻을 수 있었으며 그 위에 형성된 적색, 녹색, 청색의 필름은 패턴이 없는 경우에 비하여 시야각에 따른 반사파장의 변화가 적음을 육안을 통하여, 그리고 Lab좌표를 통해서 각각 정량적으로 확인할 수 있었다.

• 한국통신학회논문지
• /
• 제34권6C호
• /
• pp.593-603
• /
• 2009

본 논문은 스테레오 카메라가 이동하는 환경에서 카메라 움직임을 보정하여 새로운 다수의 사람을 검출하는 방법과 검출된 사람을 추적하고, 실루엣을 추출하는 통합된 시스템을 제안한다. 제안하는 시스템은 사람 검출, 추적, 실루엣 추출 3가지 모듈로 구성되어 있으며 3가지 모듈은 카메라가 이동하는 환경을 고려한 것이다. 사람 검출 모듈에서는 카메라 움직임(egomotion) 보정을 이용한 움직이는 영역 추출 결과와 스테레오 정보를 결합하여 움직이는 객체를 검출하였으며, 추적모듈은 변위 정보가 가중된 히스토그램 알고리즘으로 검출된 객체를 추적한다. 실루엣을 추출하는 모듈은 트라이맵(trimap)을 이용하여 사람의 실루엣 부분을 대략적으로 추정하는 단계와 그래프컷(graph cut)을 적용하여 정교하게 실루엣 추출하는 단계로 이루어져 있다. 본 논문에서 제안하는 방법을 실내 환경에서 팬-틸트(pan-tilt) 스테레오 카메라로 획득한 실험데이터를 대상으로 실험한 결과 다수의 사람의 검출 및 추적, 정교한 실루엣 추출이 가능한 것을 확인하였다. 본 논문의 실루엣 추출결과는 제스처 인식이나 걸음걸이 인식 등의 다양한 분야에도 적용가능하다.

• 한국전기전자재료학회논문지
• /
• 제28권9호
• /
• pp.581-586
• /
• 2015

We studied optical and electrical properties of two-wavelength white tandem organic light-emitting diodes using red and blue materials. White fluorescent OLEDs were fabricated using Alq3 : Rubrene (3 vol.% 5 nm) / SH-1 : BD-2 (3 vol.% 25 nm) as emitting layer (EML). White single fluorescent OLED showed maximum current efficiency of 9.7 cd/A, and tandem fluorescent OLED showed 18.2 cd/A. Commission Internationale de l'Eclairage (CIE) coordinates of single and tandem fluorescent OLEDs was (0.385, 0.435), (0.442, 0.473) at $1,000cd/m^2$, respectively. White hybrid OLEDs were fabricated using SH-1 : BD-2 (3 vol.% 10 nm) / CBP : $Ir(mphmq)_2(acac)$ (2 vol.% 20 nm) as EML. White single hybrid OLED showed maximum current efficiency of 7.8 cd/A, and tandem hybrid OLED showed 26.4 cd/A. Maximum current efficiency of tandem hybrid OLED was more twice as high as single OLED. CIE coordinates of single hybrid OLED was (0.315, 0.333), and tandem hybrid OLED was (0.448, 0.363) at $1,000cd/m^2$. CIE coordinates in white tandem OLEDs compared to those for single OLEDs observed red shift. This work reveals that stacked white OLED showed current efficiency improvement and red shifted emission than single OLED.

• 폴리머
• /
• 제34권4호
• /
• pp.376-380
• /
• 2010

분자내 전하이동(intramolecular charge transfer, ICT)이 가능한 도너-$\pi$-억셉터(D-$\pi$-A)타입의 발색단 을 근간으로 한 폴리머를 신규 합성하였다. 이 폴리머는 UV-visible spectra 측정결과 용액 상태에서 뿐만 아니라 고체박막 상태에서도 카르보닐기(carbonyl group)에서 기인하는 흡수와 함께 ICT에 의한 장파장 영역에서의 흡수가 관 찰되었다. $Eu^{3+}$ 이온의 첨가에 의해 장파장영역에서 일어나는 흡수의 적색이동(red shift)을 유도하였으며, 더불어 용 액과 박막의 색상도 황색에서 적색으로 변화하는 것이 관찰되었다. 합성된 고분자의 형태 및 유기 용매에 대한 용해도 는 가교제의 함량에 따라 다양한 특성을 나타내었다. 또한, 첨가된 가교제의 함량과 $Eu^{3+}$ 이온의 첨가는 성막 특성의 향상을 유도하였다.