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http://dx.doi.org/10.5012/bkcs.2013.34.11.3377

Spectrophotometric and Electrochemical Study of Cu2+-Selective Azocalix[4]arene Bearing p-Carboxyl group  

Kim, Tae Hyun (Department of Chemistry, Soonchunhyang University)
Kim, Jong Seung (Department of Chemistry, Korea University)
Kim, Hasuck (Department of Energy Systems Engineering, Daegu Gyeongbuk Institute of Science and Technology)
Publication Information
Bulletin of the Korean Chemical Society / v.34, no.11, 2013 , pp. 3377-3380 More about this Journal
Abstract
The spectrophotometric and electrochemical properties of tetraazo(p-carboxy)phenylcalix[4]arene (p-CAC) in the presence of various metal ions were investigated by UV/Vis spectroscopy and voltammetry in $CH_3CN$. p-CAC showed selective color changes to $Cu^{2+}$ over other metal ions from light orange to colorless, in accordance with hypsochromic shift in UV/Vis spectra. Voltammetric measurements also showed high selectivity for $Cu^{2+}$.
Keywords
Azocalixarene; Copper ion; Colorimetry; Voltammetry;
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