• 공업화학
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• 제31권1호
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• pp.61-66
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• 2020

본 연구에서는 압착·코팅방식 촉매 제조 공정에 첨가제로 사용되는 콜로이드 실리카의 특성이 제조된 촉매의 성능 및 열적 안정성에 미치는 영향을 연구하였다. 이를 위해 4종의 콜로이드 실리카를 대상으로 실리카 형상 및 크기, 비표면적 및 기공특성, 성분 등을 분석하였으며 해당 콜로이드 실리카를 적용하여 제조한 V₂O₅/TiO₂ 촉매의 특성 평가 및 NOx 전환율에 대한 연구를 수행하였다. 콜로이드 실리카를 이용하여 제조한 촉매의 특성은 적용한 콜로이드 실리카의 특성에 따라 달라지며, 특히 콜로이드 실리카 내 피독물질 함량은 촉매 성능에 직접적인 영향인자인 것으로 분석되었다. 또한 콜로이드 실리카 내 실리카 함량이 높을수록 촉매의 열안정성과 성능이 향상되는 것으로 나타났다.

• 한국신뢰성학회지:신뢰성응용연구
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• 제14권1호
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• pp.11-19
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• 2014

A colloidal silica slurry has been manufactured by mixing nano silica powders having different grain size to improve the reliability of Sapphire wafer CMP process. The main reliability problem of CMP process such as the breaking of wafer can be prevented by reducing the size of particles in a slurry. While existing commercial colloidal silica slurries are usually made of single grain size silica powder of about 120nm, in the present study 40nm and 100nm silica powders are mixed to achieve a similar removal rate. The new colloidal silica slurry showed wafer removal rate of $3.04{\mu}m/120min$ while that of a commercial colloidal silica slurry was $3.03{\mu}m/120min$. The roughness was less than $4{\AA}$ and scratch was 0. It is also expected that the reduction of the size of nano silica particles can improve the dispersion stability and prolong the useful life of the slurry.

• 한국전기전자재료학회논문지
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• 제17권3호
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• pp.272-277
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• 2004

The primary aim of this study is to investigate new semi-abrasive free slurry including acid colloidal silica and hydrogen peroxide for copper chemical-mechanical planarization (CMP). In general, slurry for copper CMP consists of colloidal silica as an abrasive, organic acid as a complex-forming agent, hydrogen peroxide as an oxidizing agent, a film forming agent, a pH control agent and several additives. We developed new semi-abrasive free slurry (SAFS) including below 0.5％ acid colloidal silica. We evaluated additives as stabilizers for hydrogen peroxide as well as accelerators in tantalum nitride CMP process. We also estimated dispersion stability and Zeta potential of the acid colloidal silica with additives. The extent of enhancement in tantalum nitride CMP was verified through anelectrochemical test. This approach may be useful for the application of single and first step copper CMP slurry with one package system.

• Korean Chemical Engineering Research
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• 제49권5호
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• pp.535-540
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• 2011

금속염인 lanthanum nitrate를 증류수에 용해시킨 후 실란커플링제인 ${\gamma}$-glycidyloxypropyl trimethoxysilane과 금속산화물인 colloidal silica를 이 용액에 첨가하여 sol-gel법에 의해 유-무기 혼성 용액을 제조하였다. 또한 spiropyran계 광변색 염료를 용매인 tetrahydrofuran에 용해시킨 후 앞서 제조한 혼성 용액과 혼합하여 광 변색 코팅 용액을 제조하였다. 그 후 기재인 polycarbonate 시트에 코팅시키고 열 경화시켜 광 변색성을 갖는 하드 코팅 막을 제조하였다. 이 과정 중 colloidal silica의 첨가량이 코팅 막의 광변색 특성에 미치는 영향을 조사하였다. Colloidal silica의 첨가량이 증가할수록 코팅 막의 소색속도가 빨라졌으며 연필경도가 증가하였다.

• 펄프종이기술
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• 제37권3호
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• pp.33-40
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• 2005

In this study, a nano-colloidal silica sol was applied to control the anti-slip property by spraying on kraft paper. Two kinds of nano-colloidal silica sol which have cationic and anionic charge were applied in kraft paper, and the friction and physical strength properties of kraft paper were investigated. The application of colloidal silica sol on wet web in wet-end process by spraying method was tried to improve the friction property and to avoid the general problems of machine contaminations caused by the scattering of sprayed silica particles in dryer part. The physical properties of sheet were also improved by the application of wet web spraying method, and the optimum conditions of wet web spraying operation were closely related with the conditions of pH and electrical charge of wet web and silica sol.

• 한국분말재료학회지
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• 제30권4호
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• pp.305-309
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• 2023

This study aims to prepare a colloidal silica-containing powder to enhance the solubility and dissolution rate of rivaroxaban using a self-nanoemulsifying drug delivery system (SNEDDS). We investigate the impact of colloidal silica on a nanoemulsion system for preparing powdered SNEDDS. The liquid SNEDDS comprises 30/20/50 (w/w/w) Peceol/Cremophor RH40/Tween 80, which results in the formation of the smallest droplets. Three powdered SNEDDS formulations are prepared by suspending the liquid SNEDDS formulation using colloidal silica and spray drying. The powdered SNEDDS prepared with liquid SNEDDS and colloidal silica at a ratio of 1/0.5 (w/w) exhibits the highest water solubility (0.94 ± 0.62 vs. 26.70 ± 1.81 ㎍/mL) and dissolution rate (38.4 ± 3.6 vs. 85.5 ± 3.4%, 45 min) when compared to the drug alone. Morphologically, the liquid SNEDDS is adsorbed onto colloidal silica and forms smaller particles. In conclusion, an SNEDDS containing rivaroxaban, prepared using colloidal silica, facilitates the creation of a nanoemulsion and enhances the water solubility of rivaroxaban. Accordingly, this technology holds significant potential for commercialization.

• 펄프종이기술
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• 제33권4호
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• pp.1-6
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• 2001

Today's paper industry tries to use greater amount of high yield pulp and recycled fiber and to close mill water system, which results in higher fines content and buildup of organic and inorganic contaminants in white water system. Researches are being focused to develop chemical additives that provide good retention and drainage in a closed papermaking system. A microparticle retention system consisted of cationic guar gum and anionic colloidal silica so has been developed to meet the requirements for improving machine speed and product quality. The objective of this investigation was to determine the effects of the degree of cationic guar gums, charge density and structure of anionic colloidal silica sols, and the degree of system closure on the performances of this microparticle retention system. Cationic guar gums and anionic colloidal silica sols with higher charge densities showed better retention performance. Particularly, wider maximum in retention was obtained when structure colloidal silica was used suggesting as mechanism of microparticle bridging is functioning in this system.

• Korean Chemical Engineering Research
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• 제48권5호
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• pp.561-567
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• 2010

Isophrone diisocyanate, poly(tetramethylene glycol)과 dimethylol propionic acid로부터 제조된, polyurethane 부분중합체의 미반응 NCO기를 aminopropyl triethoxysilane으로 capping시켜 silylated waterborne polyurethane을 합성하였다. 연이어 이것을 colloidal silica와 혼합하여 silylated waterborne polyurethane/silica nanocomposite를 제조하였다. 동적빛 산란법에 의해 측정된 nanocomposite 입자의 평균 크기는 silica 함유량과 무관하게 거의 일정한 수치를 나타내었다. 그러나 제조된 nanocomposite의 열적안정성은 순수한 waterborne polyurethane보다 우수하였다.

• Journal of Advanced Marine Engineering and Technology
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• 제29권1호
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• pp.98-106
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• 2005

The chemical conversion film formed on magnesium alloy was investigated by using the colloidal silica with some parameters such as solution pH. temperature, solution conditions, and treatment time. Moreover. the solutions consisted of colloidal silica titanium sulfate, and cobalt ions were used for the colloidal silica film to having a good corrosion resistance and adhesion properties. It was thought that the film at 298K was made with combination of Si-O. The quantity of film formed at high temperature such as 333K and 353K is smaller than dissolved quantity during chemical conversion treatment. Adding $CoSO_4$ to the colloidal silica solution enhanced the adhesion force between the silica film and magnesium substrate, The optimum conditions for the chemical conversion treatment solution were PH 2.90 s treatment, and 298K.

• 한국재료학회지
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• 제16권2호
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• pp.123-128
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• 2006

[ $BaMgAl_{10}O_{19}:Mn^{2+}$ ](BAM:Mn) phosphor particles with spherical shape were prepared by spray pyrolysis from colloidal solution with silica. The phosphor particles prepared by spray pyrolysis from aqueous solution had irregular morphology after high temperature post-treatment. On the other hand, the phosphor particles prepared from spray solution with colloidal silica had spherical shape after post-treatment. Colloidal silica used as additive improved the spherical shape and filled morphology of the precursor particles prepared by spray pyrolysis. The precursor particles with filled structure produced the BAM:Mn phosphor particles with spherical shape and non-aggregation characteristics after post-treatment at $1400^{\circ}C$ under reducing atmosphere. The phosphor particles prepared from colloidal solutions formed the crystal structure of BAM:Mn phosphor irrespective of the silica contents. The BAM:Mn phosphor particles prepared from aqueous and colloidal solutions had similar photoluminescence intensities under vacuum ultraviolet.