• 제목/요약/키워드: Colloidal Droplet

검색결과 10건 처리시간 0.025초

Novel Phase States in Highly Charged Colloidal Suspensions

  • Terada Y.;Muramoto K.;Tokuyama M.
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2003년도 The Fifth Asian Computational Fluid Dynamics Conference
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    • pp.19-20
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    • 2003
  • Brownian-dynamics simulation on highly charged colloidal suspensions is performed by employing Tokuyama effective force recently proposed. The radial distribution function suggests that there exist three novel phases, a gas phase, a liquid droplet phase, and a face-centered cubic (FCC) crystal droplet phase, depending on the minimum values of that potential. The dynamics of droplet growth is also investigated both in liquid droplet phase and in crystal droplet phase. Thus, different types of characteristic growth stages are found.

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콜로이드 액적의 증발에 의한 입자 증착에 관한 연구 (A Study on Particle Deposition of an Evaporating Colloidal Droplet)

  • 위상권;이정용
    • 대한기계학회논문집B
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    • 제30권7호
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    • pp.663-670
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    • 2006
  • The presented study aims to investigate the colloidal droplet deposition caused by evaporation of the liquid. In the numerical analysis, the evaporation is carried out by using different evaporation function intended to obtain different shape of solute deposition. In the experiment, the colloidal droplets of different solvents are placed on a glass plate and the surface profiles are measured after drying the solvents of the droplets to investigate the effect of the solvent evaporation on the final deposition profile. Comparing the surface profiles obtained under different conditions, the optimum drying conditions of colloidal droplets are, determined to obtain uniform surface profiles. The numerical results showed that ring-shaped deposition of solute was formed at the edge of the droplet due to the coffee stain effect and the height of the ring was reduced at the lower evaporation rate. The experiments showed that the boiling point of a solvent was critical to the surface uniformity of the deposition profile and the mixture of solvents with different boiling points influenced the uniformity as well.

SiO2 나노입자 현탁액의 충돌 및 퍼짐에 관한 실험적 연구 (Experimental study on impact and spreading of SiO2 nanoparticle colloidal suspension droplets)

  • 허형규;이상준
    • 한국가시화정보학회지
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    • 제11권3호
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    • pp.12-16
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    • 2013
  • The impact and spreading behaviors of silicon dioxide nanoparticle colloidal suspension droplets were quantitatively visualized using a high-speed imaging system. Millimeter-scale droplets were generated by a syringe pump and a needle. Droplets of different velocity were impacted on a non-porous solid surface. Images were consecutively recorded using a CMOS high-speed camera at 5000 fps (frames per second) for millimeter-scale droplets. Temporal variations of droplet diameter, velocity and maximum spreading diameters were evaluated from the sequential images captured for each experimental condition. Effects of Reynolds number, Weber number, and particle concentration were investigated experimentally.

난용성 리바록사반 약물의 자가 유화 시스템 분말 제조를 위한 콜로이드 실리카 함유 분말의 제조 및 평가 (Fabrication and Evaluation of Colloidal Silica Containing Powders for Solid Self-emulsifying Drug Delivery System of Poorly Water Soluble Rivaroxaban)

  • 진성규
    • 한국분말재료학회지
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    • 제30권4호
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    • pp.305-309
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    • 2023
  • This study aims to prepare a colloidal silica-containing powder to enhance the solubility and dissolution rate of rivaroxaban using a self-nanoemulsifying drug delivery system (SNEDDS). We investigate the impact of colloidal silica on a nanoemulsion system for preparing powdered SNEDDS. The liquid SNEDDS comprises 30/20/50 (w/w/w) Peceol/Cremophor RH40/Tween 80, which results in the formation of the smallest droplets. Three powdered SNEDDS formulations are prepared by suspending the liquid SNEDDS formulation using colloidal silica and spray drying. The powdered SNEDDS prepared with liquid SNEDDS and colloidal silica at a ratio of 1/0.5 (w/w) exhibits the highest water solubility (0.94 ± 0.62 vs. 26.70 ± 1.81 ㎍/mL) and dissolution rate (38.4 ± 3.6 vs. 85.5 ± 3.4%, 45 min) when compared to the drug alone. Morphologically, the liquid SNEDDS is adsorbed onto colloidal silica and forms smaller particles. In conclusion, an SNEDDS containing rivaroxaban, prepared using colloidal silica, facilitates the creation of a nanoemulsion and enhances the water solubility of rivaroxaban. Accordingly, this technology holds significant potential for commercialization.

열처리 조건이 잉크젯 인쇄된 실버 패턴의 형상에 미치는 영향 (Effect of Thermal Treatment Conditions on Shapes of Inkjet Printed Silver Patterns)

  • 신권용;강경태;조영준;이상호
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2011년도 제42회 하계학술대회
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    • pp.1712-1713
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    • 2011
  • Inkjet technology have many merits in plenty of industrial applications. However, deposited droplet has a very critical issue that is coffee ring effect, for the application to an industrial manufacturing process. To remove the coffee ring effect, the effect of thermal treatment conditions on shapes of inkjet printed silver patterns were investigated in various surface condition. The surface changes were characterized by the contact angle measurement. Droplets from a 50 ${\mu}m$ nozzle were printed on the substrate after optimizing the ejection of individual droplets. Ink with a high boiling point of main solvent results in coffee ring effect. This result implies that the dominant factor that determines the shape of droplet is the drying conditions of main solvent of silver nanoparticle colloidal ink. As a results, selecting a proper thermal treatment conditions is very crucial for better shapes of inkjet printed silver nanoparticle colloidal patterns.

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분무연소합성(SCS)법에 의한 나노크기 물라이트(3Al2O3.42SiO2) 콜로이드 제조 (Nano-Sized Mullite(3Al2O3.42SiO2) Colloids Fabricated by Spray Combustion Synthesis (SCS) Technique)

  • 이상진;전병세
    • 한국세라믹학회지
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    • 제41권4호
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    • pp.297-301
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    • 2004
  • 분무연소합성법을 이용하여 나노크기의 물라이트(3Al$_2$O$_3$$.$2SiO$_2$) 콜로이드를 제조하였다. 연소반응을 위한 산화제로서 Al(NO$_3$)$_3$$.$9$H_2O$와 환원제(연료)로서 CH$_{6}$N$_4$O를 사용하였으며, 실리카 소스로서 콜로이드 실리카를 첨가하였다. 분무된 액적들의 착화를 위해 연소반응기의 온도를 80$0^{\circ}C$로 유지하였다. 액적의 응고에 의한 액적크기 성장을 억제하기 위하여 금속 스크린 필터를 사용함으로써 액적의 개수 농도를 감소시켰으며, 에어로졸 입자의 체류시간을 2.5초로 유지하여 열 유체의 흐름을 층류로 유도하였다. 제조된 입자들의 모양은 모두 구형이었으며, 평균입자크기는 130nm이었다 XRD와 TEM 분석 결과 각각의 초미립자들은 정량화합물의 물라이트 결정성을 나타내었다.

화염분무열분해 공정에 의해 합성되어진 Zn2SiO4:Mn 형광체 (Zn2SiO4:Mn Phsophor Particles Prepared by Flame Spray Pyrolysis)

  • 강윤찬;손종락;정경열
    • 한국재료학회지
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    • 제14권8호
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    • pp.600-606
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    • 2004
  • $Zn_{2}SiO_{4}:Mn$ phosphor particles were prepared by a flame spray pyrolysis method. It has been generally known that the high-temperature flame enables fast drying and decomposition of droplets. In the present investigation, the morphology and luminescent property of $Zn_{2}SiO_{4}:Mn$ phosphor were controlled in a severe flame preparation condition. The particle formation in the flame spray pyrolysis process was achieved by the droplet-to-particle conversion without any evaporation of precursors, which made it possible to obtain spherical $Zn_{2}SiO_{4}:Mn$ particles of a pure phase from a droplet. Using colloidal solutions wherein dispersed nano-sized silica particles were adopted as a silicon precursor. $Zn_{2}SiO_{4}:Mn$ particles with spherical shape and filled morphology were prepared and the spherical morphology was maintained even after the high-temperature heat treatment, which is necessary to increase the photoluminescence intensity. The $Zn_{2}SiO_{4}:Mn$ particles with spherical shape, which were prepared by the flame spray pyrolysis and posttreated at $1150^{\circ}C$, showed good luminescent characteristics under vacuum ultraviolet (VUV) excitation.

다양한 제형을 활용한 화장수의 제조와 보습효과 (Formation of Skin Lotions Using Various Vehicles and Skin Hydration Effects for a Skin)

  • 조완구;김수정
    • 한국응용과학기술학회지
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    • 제26권2호
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    • pp.124-131
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    • 2009
  • We have produced, characterized and compared different colloidal vehicles based on nanoemulsions. We also have investigated morphology and droplet distribution by means of electron microscope and photon correlation spectroscopy. Nanoemulsion systems characterized by different method on formulations have been obtained. Hydration power has been studied by means of a corneometer, measuring the skin electrical capacitance before and after the application of various type of skin lotions. It has been demonstrated that nanoemulsion with oil or fatty alcohol displayed a pronounced hydration power with respect to the solubilization system. In order to compare the smoothness of the skin after using skin lotion, we have measured the friction force. The skin lotions produced by nanoemulsion technique show improved smoothness of an atopic skin.

세라마이드 IIIB와 각질층 지질을 함유한 나노에멀젼의 거동 (Behaviour of Nanoemulsions Containing Ceramide IIIB and Stratum Corneum Lipids)

  • 조완구;김경아;장선일;조병옥
    • 대한화장품학회지
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    • 제44권1호
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    • pp.31-37
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    • 2018
  • 오일/정제수(O/W) 나노에멀젼은 피부의 투과성을 변화시키는 효과적인 매개체이다. 본 연구에서 우리는 콜레스테롤, 팔미틴산과 같은 피부 각질층 지질과 세라마이드 IIIB (CIIIB)의 피부 적용을 위한 콜로이드성 운반체 역할을 하는 나노에멀젼의 제조와 특성화에 초점을 두었다. 나노에멀젼을 최적화하기 위해, 입자 크기, 나노에멀젼 안정성 및 CIIIB의 용해도와 관련하여 유화 공정 조건을 검토하였다. $80^{\circ}C$의 유화 온도 및 PIC (phase inversion composition) 유화법을 통해 입자 크기의 감소가 관찰되었다. CIIIB는 오일 및 물에 대한 용해도가 낮다. CIIIB의 농도가 증가하면 나노 에멀젼의 입자 크기가 증가하였다. Lipoid S75-3을 오일 상에 첨가하면 CIIIB의 용해도가 증가하여 DSC 측정에서 보여지는 일부 상호 작용을 나타냈다. CIIIB와 피부 각질층 지질은 결정화 또는 물리적 불안정성 없이 성공적으로 나노 에멀젼에 혼입될 수 있었다. 결론적으로, 피부 각질층 지질을 함유하는 안정한 나노 에멀젼은 피부를 위한 효과적인 보습 시스템으로서 효과적일 수 있다.