• Bulletin of the Korean Chemical Society
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• v.27 no.10
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• pp.1641-1647
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• 2006

Vibrational relaxation and competitive C-$H_{methyl}$ and C-$H_{ring}$ bond dissociations in vibrationally excited methylpyrazine in the collision with HF have been studied by use of classical trajectory procedures. The energy lost by the vibrationally excited methylpyrazine upon collision is not large and it increases slowly with increasing total vibrational energy content between 20,000 and 45,000 $cm^{-1}$. Above the energy content of 45,000 $cm^{-1}$, however, energy loss decreases. The temperature dependence of energy loss is negligible between 200 and 400 K, but above 45,000 $cm^{-1}$ the energy loss increases as the temperature is raised. Energy transfer to or from the excited methyl C-H bond occurs in strong collisions with HF, that is, relatively large amount of translational energy is transferred in a single step. On the other hand, energy transfer to the ring C-H bond occurs in a series of small steps. When the total energy content ET of methylpyrazine is sufficiently high, either or both C-H bonds can dissociate. The C-$H_{methyl}$ dissociation probability is higher than the C-$H_{ring}$ dissociation probability. The dissociation of the ring C-H bond is not the result of the direct intermolecular energy flow from the direct collision between the ring C-H and HF but the result of the intramolecular flow of energy from the methyl group to the ring C-H stretch.

• Bulletin of the Korean Chemical Society
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• v.34 no.5
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• pp.1494-1502
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• 2013

Energy flow and C-$H_{methyl}$ and C-$H_{ring}$ bond dissociations in vibrationally excited toluene in the collision with $N_2$ and $O_2$ have been studied by use of classical trajectory procedures. The energy lost by the vibrationally excited toluene upon collision is not large and it increases slowly with increasing total vibrational energy content between 5,000 and 45,000 $cm^{-1}$. Intermolecular energy transfer occurs via both of V-T and V-V transfers. Both of V-T and V-V transfers increase as the total vibrational energy of toluene increases. When the total energy content $E_T$ of toluene is sufficiently high, either C-H bond can dissociate. The C-$H_{methyl}$ dissociation probability is higher than the C-$H_{ring}$ dissociation probability, and that in the collision with $N_2$ is larger than with $O_2$.

• International Journal of Naval Architecture and Ocean Engineering
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• v.12 no.1
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• pp.241-257
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• 2020

The rapid proliferation of oil/gas drilling and wind turbine installations with jack-up rig-formed structures increases structural safety requirements, due to the greater risks of operational collisions during use of these structures. Therefore, current industrial practices and regulations have tended to increase the required accidental collision design loads (impact energies) for jack-up rigs. However, the existing simplified design approach tends to be limited to the design and prediction of local members due to the difficulty in applying the increased uniform impact energy to a brace member without regard for the member's position. It is therefore necessary to define accidental load estimation in terms of a reasonable collision scenario and its application to the structural response analysis. We found by a collision probabilistic approach that the kinetic energy ranged from a minimum of 9 MJ to a maximum 1049 MJ. Only 6% of these values are less than the 35 MJ recommendation of DNV-GL (2013). This study assumed and applied a representative design load of 196.2 MN for an impact load of 20,000 tons. Based on this design load, the detailed design of a leg structure was numerically verified via an FE analysis comprising three categories: linear analysis, buckling analysis and progressive collapse analysis. Based on the numerical results from this analysis, it was possible to predict the collapse mode and position of each member in relation to the collision load. This study provided a collision strength assessment between attendant vessels and a jack-up rig based on probabilistic collision scenarios and nonlinear structural analysis. The numerical results of this study also afforded reasonable evaluation criteria and specific evaluation procedures.

• Journal of Ship and Ocean Technology
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• v.5 no.3
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• pp.36-44
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• 2001

The collision energy absorbing characteristics of side structure of the LNG carriers which have the cargo containment systems of the spherical and the membrane types are compared. A failure mechanism of the double hull side structures of 130, 000 $m^3$ class LNG carriers under sideways collision event has been simulated by using the detailed finite element calculations. In ship collision analysis, the finite element method based on explicit time integration has been use[1 with much success. Finite element modeling techniques for detail description of structural members antral ship motion regarding the dynamic behavior allowed to investigate the effect of bow shape and the initial contact position on side shell of collided ship. In the numerical simulations of the ship-to-ship sideways collision, the effect of the colliding bow shapes and the change of the colliding ship draft are investigated. The critical collision energy which is absorbed by a side structure of a collided ship until the fore-end of colliding ship arrives at the boundary of the cargo tank is calculated. The critical speed of specified colliding ships which can not penetrate the boundary of the LNG cargo tank of the collided ship under collision accident if evaluated.

• Journal of the Korean Society of Marine Environment & Safety
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• v.5 no.2
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• pp.99-111
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• 1999

The object of this study is to get the superior double hull structure to its crashworthiness against collision comparing absorbed energy capacities of its various types with each other, varying material properties, collision positions and velocities, and structural arrangements such as double hull width, web and stringer spaces, etc. Local absorbed energy capacities, failure behaviors and damage extents of their members are also considered during collision in addition to the estimations of their global ones. This paper describes a series of numerical simulations of collisions between DWT 45,000 oil tanker(struck ship) and DWT 10,500 rigid one(striking ships) using Hydrocode LS/DYNA3D. Collisions are assumed to occur at the middle of struck ship with striking one moving at right angle to its centerline. The following remarks were obtained through this study: More flexible the double hull structure is, much superior its crashworthiness against collision is. The increment of double hull width does not give much influence than other factors do. The exact use of material property such as failure strain is also important on the numerical simulation of collision.

• Journal of the Korean Society for Railway
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• v.1 no.1 s.1
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• pp.1-9
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• 1998

Described in this paper is the result of a study on collision analysis of TGV-K using 1-dimensional model for crashworthy design. Crashworthy design of the front end is very important because majority of the impact energy (more than 70%) is absorbed by the crush of the front end when the train is collided with an obstacle like a tank lorry. Guideline for the crashworthy design can be described from the collision analysis of the whole train using a 1-dimensional model. Since the headstock of TGV-K is not designed in a crashworthy point of view, a conceptual design of the headstock to improve crashworthiness is suggested and evaluated using 1-dimensional collision analysis. The suggested design, which adopts an energy absorber and a crashworthy headstock, shows a good behaviour on the accident scenario of SNCF (collision at 110 km/h against a movable rigid mass of 15 ton).

• Journal of the Korean Society for Marine Environment & Energy
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• v.2 no.2
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• pp.86-94
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• 1999

This paper describes a development of Collision/grounding Strength Assessment System (COSAS) using simplified method. This method is formulated in closed-form equation by taking into account crushing caused by bulbous bow collision and cutting caused by forward speed grounding. To verify the accuracy of the developed system, some examples for test models of double side/bottom structure in collision/grounding situation are considered. This system might be useful for analysis of structural damage of oil tankers in collision/grounding.

• Transactions of the Korean Society of Automotive Engineers
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• v.23 no.5
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• pp.524-536
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• 2015

The paper aims to design and verify tearing tube type energy absorption device applied in tram to ensure safety in case of collision accident. Energy capacity of tearing tube is determinated based on EN15227 and Standard Collision Scenarios Criterion in Detail in Republic of Korea. Tearing tube is designed based on theoretical model suggested by X.Huang et al. and assumption by T.Y. Reddy et al. Real scale collision tests are conducted to analyze the energy absorption characteristics and deformation mode. Bending of curl tips is absorbed collision energy when curl tips and tube body are contacted to each other from the tests and we suggest and include the formula on bending of curl tips in theoretical model.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.28 no.1
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• pp.7-12
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• 2016

In this study, a simplified collision model of pile protective structures against a navigation vessel was proposed and verified. The model of pile protective structure were composed by two plastic hinges at below of cap slab and the inside of ground. A nonlinear equation of motions was developed in consideration of the kinematic energy, potential energy and deformation energy in collision event. The developed simplified model were verified by the precise finite element collision analysis of the vessel and the protective structure.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.36 no.1
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• pp.31-38
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• 2016

In this paper, the deformation-energy curves of the plastic hinges and the vessel bow, which are the major energy dissipation mechanism of a pile protective structures, were estimated, and the parametric study was performed by using those curves to apply the simplified collision model which developed in the previous study. Considered parameters were the mass of slab, the number of piles, the mass of vessel and the collision speed. As results, the difference of energy dissipation mechanism of two pile types (filled and non-filled) were revealed, and the collision behaviors of the protective structures could be tuned by the control of the inertia mass of capping slab. Therefore the simplified collision model can be used in a primary design and optimal design.