• 대한기계학회논문집B
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• 제33권2호
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• pp.133-140
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• 2009

A fast-response $CO_2$ analyzer has been developed for measuring the $CO_2$ concentration during transient condition of a SI engine. The analyzer consists of the non-dispersive infrared absorption method, electrical chopping system and water cooling system. The analyzer has good repeatability, linearity and permissible drift characteristic. Besides, it showed 18ms of a response to measure the $CO_2$ concentration. The fast-response $CO_2$ analyzer was applied to a single cylinder SI engine and the $CO_2$ emission was examined during engine start. Simultaneously, the standard exhaust gas analyzer, which has slow response time, was used for confirming the accuracy of the exhaust gas analysis using the fast-response $CO_2$ analyzer. The developed analyzer showed much faster responsive characteristic than that of a standard analyzer and made cycle by cycle exhaust gas analysis possible. The transient engine operating characteristics will be estimated from the $CO_2$ concentration of engine-out emissions and engine operating variables.

• 한국대기환경학회지
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• 제21권6호
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• pp.649-655
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• 2005

Automotive exhaust is suspected to be one of the main reasons of the rapid increase in greenhouse effect gases in ambient air. Although methane emissions are generally orders of magnitude lower than emissions of $CO_{2}$, the global warming potential (GWP) of methane is greater than that of $CO_{2}$. The environmental impact of methane emissions from vehicles is negligible and is likely to remain so for the foreseeable future. In this study, in order to investigate greenhouse gas emission characteristics from gasoline passenger cars, 20 vehicles were tested on the chassis dynamometer and methane emissions were measured. The emission characteristics by model year, mileage, vehicle speed were discussed. Test mode is CVS-15 mode that have been used to regulate for light-duty vehicle in Korea. It was found that $CH_{4}$ emissions showed higher for cold start, old model year and long mileage than hot start, new model year and short mileage, respectively. These results were compared with IPCC emission factors and the overall our results were anticipated to contribute for domestic greenhouse gas emissions calculation.

• 한국자동차공학회논문집
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• 제10권1호
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• pp.84-92
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• 2002

On the cold start of LPG engine, as the engine temperature has not reached its equilibrium temperature, liquid LPG could not be changed perfectly gaseous LPG, although it was passed to the vaporizer. Liquid and gas mixed fuel could influence starting ability and exhaust emission characteristics of LPG engine. In this study, the vaporization characteristic of liquid LPG was investigated with a conventional vaporizer and the vaporizer with heat source(glow plug) installed at preheated chamber inlet, by using the visualization methods and engine test. According to visualization result, even if the engine coolant temperature was $14^{\circ}C$, liquid fuel was supplied to primary chamber over 25 seconds without vaporizing from preheated chamber in such a conventional vaporizer. However, the vaporizer with heat source do not correspond with that, scarcely had been trim on glow plug when LPG began to vaporize. The effectiveness of heat source could be verified by application to the conventional LPG engine.

• 한국자동차공학회논문집
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• 제8권4호
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• pp.51-58
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• 2000

It is well known that the majority of the emissions measured from vehicle exhaust in the US Federal Test Procedure(FTP-75) are emitted during the first 60 seconds. This paper describes an experimental study on SI engine emissions reduction after cold start with interval secondary air injection and coolant control. Secondary air injection after cold start to reduce exhaust emissions causes an exothermic reaction at the exhaust port and gives sufficient air to the catalyst. For that reason engine-out emissions oxidized in the exhaust port and the rapid heating of a catalytic converter after cold start with CSAI and ISAI are estimated. The influence of the coolant temperature on SI engine emissions has been estimated. In the present studycoolant control of the cylinder head tempeature is used to investigate the effect of coolant temperature on SI engine emissions. The results show that engine-out hydrocarbon and carbon monoxide emissions are considerably reduced with interval secondary air injection and coolant control.

• 한국대기환경학회지
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• 제9권2호
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• pp.160-167
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• 1993

As the major methanol fueled vehicle exhaust components, formaldehyde & methanol conversion over the existing commercial 3-way catalyst was examined in a labolatory tains different Ag loadings on commercial 3-way catalyst, and german commercial catalysts for methanol engine exhaust manufactured by a commercial manufacturer. Silver catalysts were prepared by the wet impregnation of silver nitrate solution on commercial 3-way catalyst. These catalysts were characterized with BET Surface area and pore size distribution. In general, the formaldehyde(HCHO) conversion of the tested catalysts was similar to that of methanol$(CH_3OH)$. At 100$^\circ$C, which is equivalent to the cold start condition, 5wt% Ag cat. showed the most excellent HCHO and $CH_3OH$ conversion. The order of activity for conversion of HCHO & $CH_3OH$ to carbon dioxide and water vapor was as follows ; 5wt% Ag/3-way cat.>2wt% Ag/3-way cat.>german cat. front(1) > german cat. rear(2) > 10wt% Ag/3-way cat.> commercial 3-wat catalyst. However there was no significant activity difference between those tested catalysts in the hot run condition of 400$^\circ$C. Therefore, it could be concluded that the Ag-modified 3-way catalyst was the most effective and practical catalyst system which could be capable of removal the HCHO and methanol at the special condition of low temperature such as cold start condition.

• 한국자동차공학회논문집
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• 제10권3호
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• pp.61-69
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• 2002

To meet stringent LEV and ULEV emission standards, a considerable amount of development work was necessary to ensure suitable efficiency and durability of catalyst systems. The main challenge is to cut off the engine cold-start emissions. It is known that up to 80% of the total hydrocarbons(THC) are exhausted within the first five minutes in case of US FTP 75 cycle. Close-Coupled Catalyst(CCC) provides fast light-off temperature by utilizing the energy in the exhaust gas. However, if some malfunction occurred at engine operation and the catalyst temperature exceeds 1050$\^{C}$, the catalytic converter is deactivated and shows the poor conversion efficiency. This paper presents effEcts of engine operating conditions on catalytic converter temperature in a SI engine, which are the indications of catalytic deactivation. Exhaust gas temperature and catalyst temperature were measured as a function of air/fuel ratio, ignition timing and misfire rates. Additionally, light-off time was measured to investigate the effect of operating conditions. It was found that ignition retard and misfire can result in the deactivation of the catalytic converter, which eventually leads the drastic thermal aging of the converter. Significant reduction in light-off time can be achieved with proper control of ignition retard and misfire, which can reduce cold-start HC emissions as well.

• 한국자동차공학회논문집
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• 제10권4호
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• pp.15-22
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• 2002

As the emission regulations on the automobiles have been increasingly stringent, precise control of air/fuel ration is one of the most important issues on the gasoline engines. Although many researches have been carried out to identify the fuel transport phenomena in the port fuel injection gasolines, mixture preparation in the cylinder has not been fully understood due to the complexity of fuel film behavior, In this paper, the mixture preparation during cold engine start is studied by using a Fast Response Flame ionization Detector.(FRFID) In order to estimate the transportation of injected fuel from the intake port into cylinder, the wall wetting fuel model was used. The two coefficient($\alpha$,$\beta$) of the wall-wetting fuel model was determined from the measured fuel mass that was inducted into the cylinder at the first cycle after injection cut-in. $\alpha$( ratio of directly inducted fuel mass into cylinder from injected fuel mass) and $\beta$ (ratio of indirectly inducted fuel mass into cylinder from wall wetted fuel film on the wall) was increased with increasing cooling water temperature. To reduce a air/fuel ratio fluctuation during cold engine start, the appropriate fuel injection rate was obtained from the wall wetting fuel model. Result of air/fuel ratio control, air/fuel excursion was reduced.

• International Journal of Naval Architecture and Ocean Engineering
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• 제4권4호
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• pp.403-411
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• 2012

This study presents the nano-sized particle emission characteristics from a small turbocharged common rail diesel engine applicable to prime and auxiliary machines on marine vessels. The experiments were conducted under dynamic engine operating conditions, such as steady-state, cold start, and transient conditions. The particle number and size distributions were analyzed with a high resolution PM analyzer. The diesel oxidation catalyst (DOC) had an insignificant effect on the reduction in particle number, but particle number emissions were drastically reduced by 3 to 4 orders of magnitude downstream of the diesel particulate filter (DPF) at various steady conditions. Under high speed and load conditions, the particle filtering efficiency was decreased by the partial combustion of trapped particles inside the DPF because of the high exhaust temperature caused by the increased particle number concentration. Retarded fuel injection timing and higher EGR rates led to increased particle number emissions. As the temperature inside the DPF increased from $25^{\circ}C$ to $300^{\circ}C$, the peak particle number level was reduced by 70% compared to cold start conditions. High levels of nucleation mode particle generation were found in the deceleration phases during the transient tests.

• 에너지공학
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• 제18권1호
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• pp.69-73
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• 2009

자동차로부터 배출되는 배출가스의 규제가 최근 더욱 강화되고 있다. 이러한 엄격해지는 규제는 배출가스를 줄이는 대체연료의 개발에 더욱 박차를 가하게 된다. 본 연구는 가솔린, 디젤, LPG 연료를 사용하는 동급의 자동차를 이용하여 배출가스의 특성을 분석 비교하였다. 테스트 모드로는 최근 국내와 북미 배출가스의 주행모드로 사용되는 CVS-75모드를 사용하였다. 배기 특성은 주행조건에 하에서 연구되어졌다. 사용연료인 가솔린, 디젤, LPG연료에 따라 THC, CO, NOx의 배출가스의 특성을 연구했다. 연구결과, LPG연료에 비해 가솔린자동차가 9.8%의 배출가스 감소, 디젤자동차는 12.2% 증가를 나타냈다. 또한 CVS모드에서 가솔린과 LPG는 phase 1의 냉간시동구간에서 THC와 CO는 80%이상을 나타낸다.

• 한국분무공학회지
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• 제23권2호
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• pp.66-73
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• 2018

Volatile organic compounds (VOCs) are well known as ozone precursors from photochemical reactions and contribute to the formation of photochemical smog which pose health hazards. Also, some of these compounds directly affect the human health due to their toxicity such as benzene. In this study, NMVOCs composition in exhaust gas from recreational vehicle (RV) and (MPV) were characterized using a chassis dynamometer. The results for NMVOCs have reported that alkanes emission was higher than alkenes, aromatics and cycloalkanes due to reactive of diesel oxidation catalysts. The NMVOCs composition according to carbon number was highly distributed between C3 and C6~C8. During the engine cold start condition, NMVOCs emission was higher compared to the engine hot start condition due to the increased catalytic activity. The NMVOCs emission with DPF increased compared to that without DPF. The results of this study will be provide to calculate VOCs emissions from mobile source.