• 한국세라믹학회지
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• 제15권1호
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• pp.28-34
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• 1978

In order to develop the high refractory composite materials consisting of mullite and carborundum, Hadong kaolin and coal coke were selected as the starting materials. Silicone carbide crystals formed during the high-temperature reaction between kaolin and coke were detected by X-ray diffraction method and identified by electron diffraction. The temperature at which the amorphous silicone carbide begins to crystallize could be assumed to be about 155$0^{\circ}C$, which is the lower temperature claimed by others.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 1997년도 한국자동제어학술회의논문집; 한국전력공사 서울연수원; 17-18 Oct. 1997
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• pp.1778-1781
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• 1997

The coke oven plant on a steel works has not, in the past, been regarded as a prime user of modern instrument technology. The reason for this perception may be due to the fact that the basic design of the coke battery has been changed little over the years. The recording and analysis of oven pushing force on a routine basis is seen as a means of monitoring plant operation. A torque sensor is set up at the shaft of the rotor for measuring pushing force. Pushing force data which is communicated form torque sensor to staor by telemetry method are shown on MMI(Man-Machine Interface) screen and stored in the database automatically. Perhaps the most important feature is that is allows a problem oven to be identified at an early stage and for corrective action to be taken before it develops into a refusal to push. In this way the mechanical loads imposed on the battery structlure can be held to a necessary minimum, so helping to prolong its service life.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2004년도 제28회 KOSCO SYMPOSIUM 논문집
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• pp.141-148
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• 2004

Coal combustion in an iron ore sintering bed is a key parameter that determines quality of the sintered ores and productivity of the process. In this study, effects of the different types of coal coke and anthracite - on the combustion in the iron ore sintering bed are investigated by modeling and experiment. Fuel characteristics of coke and anthracite are observed through a few basic analysis and thermo-gravimetric analysis. It was found that coke has a higher reactivity than anthracite due to the difference of surface area and density. Those characteristics are reflected to the 1-D unsteady simulation of the iron ore sintering bed. Calculation results show that different reactivity of the fuel can affect the bed combustion, which implies the further investigation should be performed for obtaining optimal combustion conditions in the sintering bed.

• 한국생산제조학회지
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• 제21권5호
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• pp.697-701
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• 2012

Numerical modeling for a coke dry quenching process was developed and evaluated. The cokes had similar characteristics to a porous material, therefore, its quenching analysis was simplified as a cooling process of porous blocks. A uniform inlet temperature and constant properties of materials in the oven were also assumed. With given operating conditions, temperature profiles in the cokes were calculated and compared to the actual values. The calculated temperature gradient was high at the upper part of the coke flow and the cooling rate decreased as cokes came down to the exit port. The exit port temperature of cokes was similar to the measured value, however, temperature-dependent material properties and operating conditions must be considered to predict the temperature precisely. The calculated results could be applied to design a coke oven to produce high quality cokes.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.79-84
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• 2003

In this study we propose an unsteady I-dimensional model of an iron ore sintering bed with multiple solid phases, which confers a phase on each solid material. This model contains coke combustion, limestone decomposition, gaseous reaction, heat transfers between each phase, and geometric changes of the solid particles. Simulation results are compared with the limited experimental data set of various coke contents and air supply rates. Effect of the coke diameter is also evaluated. They predict the experimental results well and show applicabilities to the various system of the fuel bed with various solid materials.

• 한국연소학회지
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• 제9권2호
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• pp.30-37
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• 2004

Coal combustion in an iron ore sintering bed is a key parameter that determines quality of the sintered ores and productivity of the process. In this study, effects of the different types of coal - coke and anthracite - on the combustion in the iron ore sintering bed are investigated by modeling and experiment. Fuel characteristics of coke and anthracite are observed through a set of basic analysis and thermo-gravimetric analysis. Coke has a higher reactivity than anthracite due to the difference of surface area and density, and these characteristics are reflected in the 1-D unsteady simulation of the iron ore sintering bed. Calculation results show that different reactivity of the fuel can affect the bed combustion.

• 한국재료학회:학술대회논문집
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• 한국재료학회 1999년도 추계학술발표강연 및 논문개요집
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• pp.155-155
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• 1999

• 한국세라믹학회지
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• 제40권5호
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• pp.481-487
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• 2003

고로 연소대의 거동에서 석탄, 미연소탄, 코크스의 함량을 측정할 수 있는 분석기술이 필요하다 탄소질 재료에 분말 X-선 회절 정량법을 적용하여 석탄, 미연소탄, 코크스의 혼합시료에 대하여 탄소의 함량을 정량적으로 파악할 수 있는 방법을 연구하였다. 분석을 위하여 석탄을 1000~140$0^{\circ}C$의 온도에서 시간을 달리하여 미연소탄을 제조하여 XRD를 이용하여 분석하였다. 또한, XRD 분석을 위해 제조된 시료에 대하여 HCI과 HF용액을 이용하여 시료 내에 포함된 광물성분을 제거하였다. XRD측정 결과로부터 결정 층의 두께(L $c_{(002)}$)와 결정 층의 크기(L $a_{(10)}$), 방향족분율, 흑연화도, 면간거리( $d_{0.2}$), 탄소 층의 수( $N_{ι}$)를 측정하였다. 그 결과로 열처리 온도가 증가됨에 따라 L $c_{(002)}$, L $a_{(10)}$, 흑연화도는 증가하였으며, 면간거리와 반가폭은 감소하였다. 따라서 미연소탄-코크스 혼합물에 대한 결정층의 두께자료는 합성시료로부터 미연소탄의 함량을 정량화할 수 있었다.

• Korean Chemical Engineering Research
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• 제54권4호
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• pp.501-509
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• 2016

황함유량이 높아 독성 폐기물로서 분류되는 석유코크스를 역청탄 및 아역청탄과 혼합하여 가스화 공정을 통해 액체연료를 생산하는 공정의 경제성을 분석하였다. 공정의 경제성을 분석하기 위한 2,000 톤/일 규모의 액화 공정은 가스화, 정제, Fischer-Tropsch 전환 등으로 이루어진다. 기발표된 자료들로부터 적절한 검토 기준을 통해 건설비용 및 매출액을 산정하였고 석유코크스/석탄의 혼합비에 따른 경제성을 평가하였다. 경제성 평가 결과, 원소황의 생산과 판매 증가로 인해서 석유코크스의 경제성이 석탄보다 우수했으며 수분 함량이 낮은 역청탄과의 혼합이 보다 높은 경제성을 가지는 것으로 나타났다. 아역청탄의 경우, IRR (Internal rate of return)이 10% 이상이 되기 위해서는 석유코크스와의 혼합이 적어도 40 wt% 이상이 되어야 함을 확인하였다.

• 한국추진공학회지
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• 제25권3호
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• pp.56-61
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• 2021

본 연구에서는 극초음속 비행체의 냉각제로 사용되는 액체탄화수소 연료와 흡열 촉매의 안정적 사용을 위해 Al₂O₃와 H-ZSM-5를 stainless steel tube 내벽에 코팅하는 연구를 수행하였다. 액체탄화수소 연료의 흡열분해 반응에서 coke 생성이 불가피하며, stainless steel tube reactor를 냉각채널로 사용하게 됨에 따라 Fe, Ni 금속이 filamentous coke 생성을 유발한다. 이에 따라 stainless steel에 H-ZSM-5를 코팅함으로써, Fe과 Ni 금속이 액체탄화수소 연료에 직접 노출되는 것을 방지하고 filamentous coke 생성을 억제하고자 하였다. 또한 stainless steel과 H-ZSM-5 사이에는 Al₂O₃을 코팅하여, 부착 강도를 증진 시키고자 하였다.