• Title/Summary/Keyword: Cobalt (Co)

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Fuctionalization of SBA-16 Mesoporous Materials with Cobalt(III) Cage Amine Complex

  • Han, Sang-Cheol;Sujandi, Sujandi;Park, Sang-Eon
    • Bulletin of the Korean Chemical Society
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    • v.26 no.9
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    • pp.1381-1384
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    • 2005
  • Surface modification of tridimensional cubic mesoporous silica, SBA-16, was investigated with pendant arm functionalized cobalt diaminosarcophagine (diAMsar) cage complex which covalently grafted onto the silica surface through the silication with sylanol group. The spectroscopic results showed that the mesoporous structure was preserved under the $[Co(diAMsar)]^{3+}$ grafting reaction condition. Successful grafting prevented the cobalt diAMsar cage from leaching out from the SBA-16 support.

Preparation and Characterization of Ordered Nanostructured Cobalt Films via Lyotropic Liquid Crystal Templated Electrodeposition Method

  • Al-Bishri, Hassan M.;El-Hallag, Ibrahim S.;El-Mossalamy, Elsayed H.
    • Bulletin of the Korean Chemical Society
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    • v.31 no.12
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    • pp.3730-3734
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    • 2010
  • A simple, inexpensive and less time consuming electrochemical methods were carried out to prepare ordered mesoporous cobalt films. Ordered mesoporous cobalt films were successfully synthesized by templated electrodepostion of hexagonal $H_1$-e Co ion. The electrodeposited mesopores films were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), low angle X-ray diffraction (XRD) and voltammetric methods. The applicability of thin films as high - performance super capacitors electrode materials is demonstrated electrochemically using cyclic voltammetry (CV) technique.

Theoretical study of cross sections of proton-induced reactions on cobalt

  • Yigit, Mustafa
    • Nuclear Engineering and Technology
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    • v.50 no.3
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    • pp.411-415
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    • 2018
  • Nuclear fusion may be among the strongest sustainable ways to replace fossil fuels because it does not contribute to acid rain or global warming. In this context, activated cobalt materials in corrosion products for fusion energy are significant in determination of dose levels during maintenance after a coolant leak in a nuclear fusion reactor. Therefore, cross-section studies on cobalt material are very important for fusion reactor design. In this article, the excitation functions of some nuclear reaction channels induced by proton particles on $^{59}Co$ structural material were predicted using different models. The nuclear level densities were calculated using different choices of available level density models in ALICE/ASH code. Finally, the newly calculated cross sections for the investigated nuclear reactions are compared with the experimental values and TENDL data based on TALYS nuclear code.

Recovery of Cobalt from Waste Cathode Active Material Using Organic Acid (폐 리튬이온 배터리 양극으로부터 유기산을 이용한 코발트 회수)

  • Moon, Ji-Hoon;Ahn, J.E.;Kim, Hyun-Jong;Sohn, S.H.;Lee, H.W.;Kim, H.S.
    • Applied Chemistry
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    • v.16 no.1
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    • pp.73-76
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    • 2012
  • Due to the developments of communications equipment and electronic devices, lithium ion secondary battery usage is growing. Along with demand increasing, the amount of scrap has been steadily increasing. In this study, method of cobalt recovery using organic eco-friendly is proposed. Sulfuric acid, Malic acid, Citric acid at reflux device had good cobalt leaching efficiency. And Sulfuric acid, Malic acid at the autoclave increased cobalt leaching efficiency.

Formation Mechanism of Cobalt Silicide by Solid Phase Reaction in Co/Ti/Si system (Co/Ti/Si 계에서 고상반응에 의한 Cobalt Silicide 형성기구 고찰)

  • Lee, Seung-Heon;Bae, Jun-Cheol;Sin, Dong-Won;Park, Chan-Gyeong
    • Korean Journal of Materials Research
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    • v.6 no.8
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    • pp.808-816
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    • 1996
  • (100) Si 기판위에 전자 빔 증착법을 이용하여$ 90\AA$두께의 Ti과 $120\AA$두께의 Co를 순차적으로 증착시켰다. 그 후 질소분위기하의 $350-900^{\circ}C$온도구간에서 급속열처리함으로써 (100) Si 기판위의 Co/Ti 이중 박막의 실리사이드화 반응이 일어나게 했으며 이를 XRD, AES, TEM을 이용하여 분석하였다. $500^{\circ}C$이하의 온도에서는 Co원자들이 Ti층쪽으로 빠르게 확산하여 Si와 반응하기 이전에 Ti원자들과 상호 혼합되어 어떠한 실리사이드도 형성되지 않았다. $500^{\circ}C$에서 열처리된 시편의 고분해능전자현미경 영상을 통해 Co-Ti 혼합층과 실리콘 기판과의 계면에서 (100)Si 기판과 정합관계를 가지는 CoSi2가 형성되었음을 확인했다. $600^{\circ}C$열처리에 의해 Co-Ti-Sitka성분 실리사이드가 형성되기 시작하였으며, 형성된 삼성분 실리사이드는 Ti의 out-diffusion에 의해 $900^{\circ}C$ 이상의 온도에서는 불안정하였다. Co/Ti이중 박막에 의해 형성된 CoSi2는 실리콘 기판과 평탄한 계면을 가지며 실리콘 기판에 대해 (100)우선성장방위를 가졌다.

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