• Korean Journal of Materials Research
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• v.33 no.8
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• pp.337-343
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• 2023

3Y-TZP (3 mol% yttria-stabilized tetragonal zirconia polycrystals) ceramics have excellent mechanical properties including high fracture toughness, good abrasion resistance as well as chemical and biological stability. As a result, they are widely used in mechanical and medical components such as bearings, grinding balls, and hip implants. In addition, they provide excellent light transmittance, biocompatibility, and can match tooth color when used as a dental implant. Recently, given the materials' resemblance to human teeth, these ceramics have emerged as an alternative to titanium implants. Since the introduction of CAD/CAM in the manufacture of ceramic implants, they've been increasingly used for prosthetic restoration where aesthetics and strength are required. In this study, to improve the surface roughness of zirconia implants, we modified the 3Y-TZP surface with a biocomposite of hydroxyapatite and forsterite using room temperature spray coating methods, and investigated the mixed effect of the two powders on the evolution of surface microstructure, i.e., coating thickness and roughness, and biological interaction during the in vitro test in SBF solution. We compared improvement in bioactivity by observing dissolution and re-precipitation on the specimen surface. From the results of in vitro testing in SBF solution, we confirmed improvement in the bioactivity of the 3Y-TZP substrate after surface modification with a biocomposite of hydroxyapatite and forsterite. Surface dissolution of the coating layer and the precipitation of new hydroxyapatite particles was observed on the modified surface, indicating the improvement in bioactivity of the zirconia substrate.

• Journal of the Korean Society of Food Science and Nutrition
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• v.33 no.2
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• pp.447-450
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• 2004

Overall migration through epoxy layer coated wood was investigated to estimate the coating thickness satisfying the regulatory limit. As an index of overall migration, KMnO$_4$ oxidizable extractives by the food simulant water solution was used. Migration pattern in interest range could described by a simple diffusion model and the temperature dependence of the permeability index could be explained by Arrhenius equation. The thickness of epoxy coating greater than 0.004 mm was analyzed to be required for satisfying the regulatory guideline.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.11a
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• pp.179-179
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• 2009

For the deposition of the semiconductor nanocrystals or quantum dots, it is required to have the substrates with smooth surface roughness. Slot-die coating method wad adopted and optimized varying the processing parameters like coating speed, gap distance, solution concentration, etc to get the smooth coated films on flexible substrates. The coating speed in slot-die method was varied from 1 m/min to 2.5 m/min focusing especially on its industrial usage. The gap distance between the substrate surface and slot-die lip was changed also to control mainly the thickness of coated films.

• Steel and Composite Structures
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• v.15 no.1
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• pp.1-14
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• 2013

Predicting the fire resistance of structures has been significantly advanced by full scale fire tests in conjunction with improved understanding of compartmental fire. Despite the progress, application of insulation is still required to parts of structural steelwork to achieve over 60 minutes of fire rating. It is now recognised that uncertainties on insulation properties hinder adaptation of performance based designs for different types of structures. Intumescent coating has recently appeared to be one of most popular insulation types for steel structures, but its design method remains to be confirmed by empirical data, as technical difficulties on the determination of the material properties at elevated temperatures exist. These need to take into account of further physiochemical transitions such as moving boundary and endothermic reaction. The impetus for this research is to investigate the applicability of the conventional differential equation solution which examines the temperature rise on coated steel members by an inorganic intumescent coating, provided that the temperature-dependent thermal/mechanical insulation properties are experimentally defined in lab scale tests.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.25 no.2
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• pp.304-311
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• 2001

The present work examines the influence of surface coating on the temperature and the thermo-mechanical stress field produced by friction due to sliding contact. A two-dimensional transient model of a layered medium submitted to a moving heat flux is prsented. A solution technique based on the boundary element method employing the multiregion technique is utilized. Results are presented showing the influence of coating thickness, thermal properties, Peclet number, and mechanical properties. It has been shown that the mechanical properties and thickness of coating have a significant influence on the stress field, even for low temperature increase. The effects of the ratios of shear modulus become more important for low temperature increase than the effects of the ratios of other mechanical properties.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.08a
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• pp.201-201
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• 2011

Recently, mussel-inspired surface modification, called polydopamine coating has been extensively implemented to many areas, due to its material versatility and ease to use. In particular, incubation of substrates in an alkaline dopamine solution resulted in self-polymerization of dopamine and modified variety of material surfaces, including noble metals, metal oxides, ceramics, and synthetic polymers. However, the polydopamine coating has a drawback to practical use; it takes more than 12 hrs to introduce sufficient polydopamine layers to solid substrates. Here, we investigated the rate-enhanced polydopamine coating by varying reaction conditions: pH, concentration, and the addition of the oxidizing agent. As a result, the optimum condition for fast polydopamine coating was found, and solid substrates were efficiently coated with polydopamine layers in just few minutes using the condition. The polydopamine-modified surface was characterized by XPS and contact angle goniometry, and the biocompatibility of the modified surface was also proved by cell attachment test.

• Journal of the Korean institute of surface engineering
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• v.49 no.5
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• pp.395-400
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• 2016

This article reports improved corrosion resistance and adhesion of electro-paint (E-paint) with fluoride conversion coating (FCC) on AZ31 Mg alloy for the first time. These improvements were observed in comparison to chemically polished samples with no chemical conversion coating and samples with cerium conversion coatings (CeCC). FCCs were prepared in a hydrofluoric acid (HF) solution for four different times; 10, 30, 60, and 120 s. The colour of the samples changed from light gold to brown with increasing immersion time, indicating the formation of thicker FCC coatings with increasing immersion time. The adhesion of the E-paint on FCC-coated AZ31 Mg alloy was tested after 500 h of immersion in deionized (DI) water. Salt spray test (SST) results revealed delamination of E-paint on the chemically polished sample, severe blistering on the samples with CeCC, but no delamination and no blistering on the samples with FCC.

• Journal of Adhesion and Interface
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• v.6 no.4
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• pp.7-11
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• 2005

Multi-walled carbon nanotubes (CNTs), which were purified by etching in 25% $H_2SO_4/HNO_3$ solution at $60^{\circ}C$ for 2 h, were modified via plasma polymerization coating of acrylic acid, allylamine or acetylene, and then utilized to prepare PEI/CNT composites. First, plasma polymerization conditions were optimized by measuring the solvent resistance of coatings in THF, chloroform and NMP, and the tensile strength of PEI/CNT (0.5%) composites as a function of plasma power (20~50 W) and monomer pressure (20~50 mTorr). The tensile strength of PEI/CNT composites was further evaluated as a function of CNT loading (0.2, 0.5 and 1%). Finally, FT-IR was utilized to provide a better understanding of the improved tensile properties of PEI/CNT composites via plasma polymerization coating of CNTs. Plasma polymerization of acrylic acid greatly enhanced the tensile strength of PEI/CNT composites, as did allylamine but to a lesser degree, while acetylene plasma polymerization coating decreased tensile strength.

• Journal of the Korean Ceramic Society
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• v.34 no.7
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• pp.747-757
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• 1997

ZSM-5 zeolite composite membranes have been synthesized from a silica sol solution containing TPABr as an organic template by the dip-coating and the pressurized-coating hydrothermal treatment techniques. The CO2 separation efficiency of synthesized composite membranes was also investigated. The permeation mechanism of CO2 through ZSM-5 membranses was the surface diffusion, and that of N2, O2, and He gases was Knudsen diffusion or activated diffusion depending on the synthetic method of membranes and the measurement temperature. The CO2/N2 separation factor of the membrane prepared by the dip-coating hydrothermal treatment was 2.5 at about 12$0^{\circ}C$, while the ZSM-5 composite membrane synthesized by the pressurized-coating hydrothermal treatment technique showed the CO2/N2 separation factor of 9.0 at room temperature higher than that ever reported in the literature.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.26 no.7
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• pp.550-554
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• 2013

Carbon nanotubes (CNT) / polyvinylidene fluoride (PVDF) piezoelectric composite films for nanogenerator devices were fabricated by spray coating method. When the CNT/PVDF mixture solution passes through the spray nozzle with small diameter by the compressed nitrogen gas, electric charges are generated in the liquid by a triboelectric effect. Then randomly distributed ${\beta}$ phase PVDF film could be re-oriented by the electric field resulting from the accumulated electrical charges, and might be resulted in extremely one-directionally aligned ${\beta}$ phase PVDF film without additional electric field for poling. X-ray diffraction patterns were used to investigate crystal structure of the CNT/PVDF composite films. It was confirmed that they revealed extremely large portion of the ${\beta}$ phase PVDF crystalline in the film. Therefore we could obtain the poled CNT/PVDF piezoelectric composite films by the spray coating method without additional poling process.