• Title/Summary/Keyword: Coal-derived synthetic gas

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NOx Formation Characteristics of the Coal-derived Synthetic Gas Containing $CH_4$ and $NH_3$ Components (메탄 및 암모니아를 포함하는 석탄 합성가스의 NOx 발생 특성)

  • Lee, Chan
    • Clean Technology
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    • v.14 no.2
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    • pp.117-122
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    • 2008
  • Theoretical analysis was conducted on the combustion and the NOx formation characteristics of the coal-derived synthetic gases with medium-BTU heating value. The synthetic gas was assumed to contain the major species of CO, $H_2,\;CO_2$, and $N_2$ and the minor species of $CH_4$ and $NH_3$. Through thermochemical analysis on the combustion of the synthetic gas, the flame temperature, major and minor species of exhaust gas, and thermal and fuel NOx emissions were computed. In addition, the effects of the $CH_4$ and the $NH_3$ components in syngas fuel on combustion and NOx emission were investigated. Based on the computed results on the synthetic gases, basic direction and guidelines were provided fur the low NOx design of gas turbine combustor.

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Analysis on the Combustion Characteristics of Low-Btu Synthetic Gases in Gas Engine (저발열량 합성가스의 가스엔진 내 연소 특성에 대한 해석)

  • Lee, Chan;Cho, Sang Mok
    • Clean Technology
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    • v.12 no.2
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    • pp.78-86
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    • 2006
  • Computational analyses are conducted on the combustion characteristics of the coal- and the biomass-derived synthetic gases with low-Btu heating value in gas engine. Using thermochemical analyses on the synthetic gases, combustion pressure, temperature, exhaust gas composition, NO emission and engine power are predicted and the predicted results are compared with small-scale pilot engine test results. In order to investigate the unsteady combustion phenomena in gas engine combustion chamber, CFD analyses are carried out on the coal and the biomass synthetic gases and their computed results are compared to provide the guidelines for the design modification and the tuning of the gas engine burning the synthetic gases as alternative fuels.

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Experimental Study on the NOx Emission Characteristics of Low Calorific Value(LCV) Gas Fuel at Premixed Combustion Condition (저 발열량 가스 연료의 예혼합 연소시 NOx 발생 특성에 관한 실험적 연구)

  • Kim, Yong-Chul;Lee, Chan;Yun, Yong-seung
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.11a
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    • pp.23-29
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    • 1999
  • Experimental studies are conducted to investigate the flame stability and the thermal/fuel NOx formation characteristics of the low calorific value (LCV) coal derived gas fuel. Synthetic LCV fuel gas is produced by mixing carbon monoxide, hydrogen, nitrogen and ammonia on the basis that the thermal input of the syngas fuel into a burner is identical to that of natural gas. The syngas mixture is fed to and burnt with air on flat flame burner. With the variation of the equivalence ratio for specific syngas fuel, flame behaviors are observed to identify the flame instability due to blow-off or flashback and to define stable combustion range. Measurements of NOx content in combustion gas are made for comparing thermal and fuel NOx from the LCV syngas combustion with those of the natural gas one. In addition, the nitrogen dilution of the LCV syngas is preliminarily attempted as a NOx reduction technique, and its effects on thermal and fuel NOx production are discussed.

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Development of Jet-Fuel Using Petroleum Displacement Resources (석유대체자원을 이용한 항공유제조기술)

  • Jeong, Soon-Yong;Kim, Chul-Ung;Jeong, Kwang-Eun;Koh, Jae-Cheon;Chae, Ho-Jeong;Kim, Tae-Wan;Park, Hyun-Joo;Lee, Sang-Bong;Han, Jeong-Sik;Jeong, Byung-Hun
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.307-310
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    • 2010
  • The research for production of jet fuel from petroleum displacement resources such as bio-mass, coal, natural gas mainly consists of three sub-research areas; the fisrt step is the pretreatment for producing a synthetic gas, and the next step is the Fischer-Trophsh reaction process for making hydrocarbons. The last is the upgrading technology for the hydrocarbons to fit a jet fuel specification via cracking and isomerization reactions. This talk presents reaserch trends and main technologies for production of jet fuel derived from petroleum displacement resources.

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Combustion Performance Test of Syngas Gas in a Model Gas Turbine Combustor - Part 2 : NOx/CO emission Characteristics, Temperature Characteristics and Flame Structures (모델 가스터빈 연소기에서 합성가스 연소성능시험 - Part 2 : NOx/CO 배출특성, 온도특성, 화염구조)

  • Lee, Min Chul;Yoon, Jisu;Joo, Seong Pil;Yoon, Youngbin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.8
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    • pp.639-648
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    • 2013
  • This paper describes on the NOx/CO emission characteristics, temperature characteristics and flame structures when firing coal derived synthetic gas especially for gases of Buggenum and Taean IGCC. These combustion characteristics were observed by conducting ambient-pressure elevated-temperature combustion tests in GE7EA model combustor when varying heat input and nitrogen dilution ratio. Nitrogen addition caused decrement in adiabatic flame temperature, thus resulting in the NOx reduction. At low heat input condition, nitrogen dilution raised the CO emission dramatically due to incomplete combustion. These NOx reduction and CO arising phenomena were observed at certain flame temperature of $1500^{\circ}C$ and $1250^{\circ}C$, respectively. As increasing nitrogen dilution, adiabatic flame temperature and combustor liner temperature were decreased and singular points were detected due to change in flame structure such as flame lifting. From the results, the effect of nitrogen dilution on the NOx/CO and flame structure was examined, and the test data will be utilized as a reference to achieve optimal operating condition of the Taean IGCC demonstration plant.

Combustion Performance Test of Syngas Gas in a Model Gas Turbine Combustor - Part 1 : Flame Stability (모델 가스터빈 연소기에서 합성가스 연소성능시험 - Part 1 : 화염안정성)

  • Lee, Min Chul;Joo, Seong Pil;Yoon, Jisu;Yoon, Youngbin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.8
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    • pp.632-638
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    • 2013
  • This paper describes on the flame stability and combustion instability of coal derived synthetic gas especially for gases of Buggenum IGCC in Netherlands and Taean IGCC in Korea. These combustion characteristics were observed by conducting ambient-pressure elevated-temperature combustion tests in GE7EA model combustor when varying heat input and nitrogen dilution ratio. Flame stability map is plotted according to the flame structure by dividing all regimes into six, and only regime I and II are identified to be stable. Both syngases of Taean and Buggenum with nitrogen integration corresponds to regime II in which syngas burnt stably and flame coupled with outer recirculation flow. Stable regime of Buggenum is larger than that of Taean when considering only $H_2$/CO ratio due to higher content of hydrogen. However, when considering nitrogen dilution, syngas of Taean is burnt more stably than that of Buggenum since more nitrogen in Buggenum has negative effect on the stability of flame.