• Applied Chemistry for Engineering
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• v.35 no.2
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• pp.107-114
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• 2024

In order to produce high-yield pitch-based activated carbon, pitch was synthesized by blending pyrolysis fuel oil (PFO) and coal-tar. Pitch was synthesized by varying the amount of coal-tar from 0~20% compared to PFO and reacting at 380~420 ℃ for 3 h. The synthesized pitch had a softening point between 80 and 260 ℃, and yields ranged from 10 to 40%. At all synthesis temperatures, as the coal-tar blending ratio increased, the yield increased and the softening point decreased. After considering the selected pitches (softening points: 230~260 ℃), pitches containing coal-tar were more volatile at a low boiling point and had a higher residual carbon content. This is a difference in the composition of coal-tar and PFO, and it was con- firmed that coal-tar has a lot of aromatics and PFO has a lot of aliphatics. The selected pitch was heated to 950 ℃ in a tubular reactor and physically activated with steam for 1 hour. Activated carbon containing coal-tar showed higher yield and microporosity compared to only PFO. In this study, the effect of increasing activated carbon yield by blending pitch raw materials was confirmed, and the physical activation characteristics according to the coal-tar mixing ratio were examined.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.2
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• pp.218-224
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• 2008

Coal-, coconut- and wood-based activated carbons and anthracite were tested to evaluate adsorption and biodegradation performances of chloral hydrate. In the early stage of the operation, the adsorption was the main mechanism for the removal of chloral hydrate, however as increasing populations of attached bacteria, the bacteria played a major role in removing chloral hydrate in the activated carbon and anthracite biofilter. It was also investigated that chloral hydrate was readily subjected to biodegrade. The coal- and coconut-based activated carbons were found to be most effective adsorbents in adsorption of chloral hydrate. Highest populations and activity of attached bacteria were shown in the coal-based activated carbon. The populations and activity of attached bacteria decreased in the order: coconut-based activated carbon > wood-based activated carbon > anthracite. The attached bacteria was inhibited in the removal of chloral hydrate at temperatures below 10$^{\circ}C$. It was more active at higher water temperatures(20$^{\circ}C$ <) but less active at lower water temperature(10$^{\circ}C$>). The removal efficiencies of chloral hydrate obtained by using four different adsorbents were directly related to the water temperatures. Water temperature was the most important factor for removal of chloral hydrate in the anthracite biofilter because the removal of chloral hydrate depended mainly on biodegradation. Therefore, the main removal mechanism of chloral hydrate by applying activated carbon was both adsorption and biodegradation by the attached bacteria. The observation suggests that the application of coalbased activated carbon to the water treatment should be the best for the removal of chloral hydrate.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.4
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• pp.404-411
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• 2007

Adsorption performance of odorous compounds such as geosmin and 2-MIB on granular activated carbon were evaluated in this study. The coal-based activated carbon was found more effective than other carbons in adsorption of geosmin and 2-MIB. The wood-based virgin activated carbon was less effective than coconut- and coal-based carbon in adsorption nevertheless having larger pore volume and specific surface area than others carbons. The maximum adsorption capacity(X/M) of coal-based activated carbon for geosmin and 2-MIB was $1.2\sim1.9$ and $2.1\sim2.6$ times larger than coconut- and wood-based virgin activated carbon, respectively. Carbon usage rate (CUR) of coal-, coconut- and wood-based virgin activated carbons for geosmin and 2-MIB were 1.72 and 1.44 g/day, 1.72 and 2.05 g/day and 2.12 and 1.90 g/day, respectively. In the evaluation of adsorption isotherm of geosmin and 2-MIB for coal-, coconut- and wood-based virgin activated carbons, k value of 2-MIB was lower than geosmin, It menas 2-MIB is more difficult to remove by activated carbon adsorption than geosmin. The relationship of max. adsorption versus total pore volume of coconut- and wood-based virgin and used activated carbon for geosmin and 2-MIB were $y=264,459\times-79,047(R^2=0.95)$, $y=319,650\times-101,762(R^2=0.93)$.

• Journal of Environmental Science International
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• v.22 no.2
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• pp.205-213
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• 2013

This is made of domestic and foreign coal activated carbon of five species, physicochemical adsorption efficient about sterilize products and micro harmful substances and is a result of the economic evaluation. The most well-developed micropores bed volume 123,409 of AC-1 activate carbon appeared to be the best next AC-2, AC-3, AC-4, AC-5 followed by activated carbon was investigated. PFOA and PFOS in the BV 96,000 when evaluating foreign types of adsorption activated carbon adsorption capacity was greater when more than PFOA, PFOS showed that the adsorption well. The economic evaluation of activated carbon usage in chloroform (CUR) was most excellent as a AC-1 4.3 g/day, the next AC-2, AC-3, AC-4, AC-5 there are two types of foreign economic order appears to have appeared, but the current domestic market when applying the price AC-1, AC-3, AC-2, AC-4, AC-5 order was investigated.

• Journal of Environmental Science International
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• v.24 no.9
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• pp.1123-1129
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• 2015

This research was performed by means of several different virgin granular activated carbons (GAC) made of each coal, coconut and wood, and the GACs were investigated for an adsorption performance of iodine-131 in a continuous adsorption column. Breakthrough behavior was investigated that the breakthrough points of the virgin two coals-, coconut- and wood-based GACs were observed as bed volume (BV) 7080, BV 5640, BV 5064 and BV 3192, respectively. The experimental results of adsorption capacity (X/M) for iodine-127 showed that two coal- based GACs were highest (208.6 and $139.1{\mu}g/g$), the coconut-based GAC was intermediate ($86.5{\mu}g/g$) and the wood-based GAC was lowest ($54.5{\mu}g/g$). The X/M of the coal-based GACs was 2~4 times higher than the X/M of the coconut-based and wood-based GACs.

• Carbon letters
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• v.9 no.2
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• pp.137-144
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• 2008

The commercial activated carbons are typically prepared by activation from coconut shell char or coal char containing lots of inorganic impurities. They also have pore structure and pore size distribution depending on nanostructure of precursor materials. In this study, two types of commercial activated carbons were applied for EDLC electrode by removing impurities with acid treatments, and controlling pore size distribution and contents of functional group with heat treatment. The effect of the surface functional groups on electrochemical performance of the activated carbon electrodes was investigated. The initial gravimetric and volumetric capacitance of coconut based activated carbon electrode which was acid treated by $HNO_3$ and then heat treated at $800^{\circ}C$ were 90 F/g and 42 F/cc respectively showing 94% of charge-discharge efficiency. Such a good electrochemical performance can be possibly applied to the medium capacitance of EDLC.

• Carbon letters
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• v.22
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• pp.96-100
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• 2017

• Journal of Korean Society of Environmental Engineers
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• v.27 no.7
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• pp.762-770
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• 2005

Adsorption and biodegradation performance of chlorinated by-products such as trihalomethanes(THMs) and haloacetic acids(HAA5) on granular activated carbon were evaluated in this study. The coconut-based activated carbon was found more effective than others in adsorption of THMs due to larger pore volume of less than $20{\AA}$. The wood-based activated carbon was less effective than coconut- and coal-based activated carbon in adsorption nevertheless having larger pore volume and specific surface area than others. The maximum adsorption capacity(X/M) of coconut-based carbon for THMS was 1.1-1.5 times larger than coal based carbon and 14.1-31.4 times larger than wood based activated carbons. Activated carbon usage rate(CUR) of coconut-, coal- and wood-based activated carbons for chloroform were 9.4, 11.2 and 38 g/day respectively. In the evaluation of adsorption isotherm of THM species for coconut-, coal- and wood-based activated carbons, k value of chloroform was the lowest in the THM species, It menas that chloroform is difficult to remove by activated carbon adsorption. and BDCM, CDBM, bromoform are in the succeeding order of adsorption. In the evaluation of biodegradation rate, mean biodegradation rate was chloroform 7%, BDCM 5%, CDBM 4% and bromoform 3%, respectively THMs are difficult materials to be biodegraded. In the evaluation of characteristics of adsorption and biodegradation for HAA5 species, HAA5 species appear to be removed effectively by activated carbon. Most of the HAA5 are adsorbed at the beginning of operation periods and HAA5 except TCAA were almost biodegraded from bed volume of 2,000 and more than 90 percent of biodegradation of TCAA was started from bed volume around 4,000 and after that biodegradation rate was increased with increasing bed volume.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.2
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• pp.184-191
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• 2007

Coal-, coconut- and wood-based activated carbons and anthracite were tested for an adsorption and biodegradation performances of nitrogenous chlorinated by-products such as chloropicrin, DCAN, DBAN and TCAN. In early stage of operations, an adsorption performance was a main mechanism for removal of nitrogenous chlorinated by-products, however as increasing populations of attached bacteria, the bacteria played a major role in removing nitrogenous chlorinated by-products in the activated carbon and anthracite biofilter. It was also investigated that the compounds were readily subjected to biodegrade. Whilst the coal- and coconut-based activated carbons were found most effective in adsorption of the compounds, the anthracite was worst in adsorption of the compounds. Highest populations and activity of attached bacteria were shown in the coal-based activated carbon. The populations and activity of attached bacteria decreased in the order: coconut-based activated carbon > wood-based activated carbon > anthracite. The attached bacteria were inhibited for removal of the compounds at temperatures below $10^{\circ}C$. The attached bacteria were more active at higher water temperatures$(20^{\circ}C\;<)$ but less active at love. water temperature$(10^{\circ}C\;>)$. The removal efficiencies of the compounds obtained using coal-, coconut- and wood-based activated carbons and anthracite were directly related to the water temperatures. In particular, water temperature was the most important factor for removal of the compounds in the anthracite biofilter because the removal of the compounds depended mainly on biodegradation. Therefore, the main removal mechanism of the compounds the main mechanism on the removal of the compounds using activated carbon was both adsorption and biodegradation by the attached bacteria. The observation suggests that using coal-based activated carbon is the best for removal of nitrogenous chlorinated by-products in the water treatment.

• Journal of the Korean Institute of Gas
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• v.27 no.3
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• pp.134-140
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• 2023

Activated carbon is a carbonaceous material mainly used as a gaseous or liquid adsorbent. As fire-related accidents occur consistently due to the accumulation of heat of adsorption and oxidation of volatile organic compounds, the explosive characteristics and thermal stability of powdered and granular activated carbon made from coal and coconut shells were evaluated. As a result of the particle size analysis, the powdered activated carbon was in the particle size range (0.4~3) ㎛, and thermal properties such as exothermic onset temperature and decomposition behavior were analyzed using a differential scanning calorimetry and a thermogravimetric analysis. As a result of the evaluation of the explosion hazards for dust, both coal-based and coconut-based powdered activated carbon are classified as St1 class with weak explosion, but this is a relative and does not mean that the explosion hazards is absolutely low. Therefore, it is necessary to establish countermeasures for reducing the damage.