• Plant Journal
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• v.16 no.1
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• pp.38-43
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• 2020

In this study, Seochon Thermal Power Plant No.1 for anthracite coal was tested to find the proper operation range of limestone slurry pH in the absorber tower which can be operated continuously in compliance with the Air Quality Preservation Act and Seocheon Thermal Power Division's internal regulation, sulfur dioxide average emission regulation. When operating the sulfur dioxide concentration [ppm] in the combustion gas flowing into the desulfurization absorption tower at 370, 400, 460 and 550 ppm while the main operating elements such as the flow rate of the combustion gas were fixed, the proper slurry pH Were 4.4, 4.5, 4.8 and 5.1, respectively. Therefore, it is recommended to operate with the correlation equation, R_pH=0.004×C_in+2.93 derived using sulfur dioxide and the appropriate slurry pH.

• The Korean Journal of Rheology
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• v.9 no.1
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• pp.1-5
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• 1997

새로이 합성한 계면확성제와 대표적 분산용 계면활성제의 분산효과를 상호 비교해 보기 위하여 고농도 석탄-물 슬러리계에 대한 유변학ㅈ거 성질을 측정하였다. 0~$25^{\circ}C$ 온도 범위에서 얻어진 유동곡선으로부터 여러 가지 유동 파라미터를 구한 결과, PS가 상대적으로 structure factor, C2와 shear modulus, $\chi$2/$\alpha$2 값에 있어서 큰 감소를 보여 주엇으며 특히 shear modulus는 계면활성제의 종류에 따라 큰차이를 보여주었다. 이러한 현상을 PS가 다 가음이곤 고분자 전해질과 유사한 구조를 갖고있어서 석탄 입자에 흡착시 입자간 정전기적 반발과 입체장애를 초래하여 슬러리의 유동성을 향상시킨데 따른 결과로 해석된다.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1993.11a
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• pp.31-36
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• 1993

Three different methods were employed to measure the degree of aerial oxidation in coal and the resulting oxidation/weathering indices were applied to obtain kinetic parameters of aerial oxidation processes, The index (i.e., slurry pH, Free Swelling Index, weight gain) values were subjected to kinetic analysis based on power-law Arrhenius type reaction model. The results show that activation energy of the aerial oxidation in 20-29$0^{\circ}C$ is in the range of 12-16 ㎉/㏖ and the agreement among three techniques is remarkable. The first order kinetic model is suitable in describing low temperature aerial oxidation process, except in the FSI case where the zero order expression is the best one.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.8
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• pp.1068-1076
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• 1997

Emission control of acid exhaust gases from coal-fired power plants and waste incinerators has become an increasing concern of both industries and regulators. Among those gaseous emissions, SO$_{2}$ has been eliminated by a Spray Drying Absorber (SDA) system, where the exhaust gas is mixed with atomized limestone-water slurry droplets and then the chemical reaction of SO$_{2}$ with alkaline components of the liquid feed forms sulfates. Liquid atomization is necessary because it maximizes the reaction efficiency by increasing the total surface area of the alkaline components. An experimental study was performed with a laboratory scale SDA to investigate whether the scrubbing efficiency for SO$_{2}$ reduction increased or not with the application of a DC electric field to the limestone-water slurry. For a selected experimental condition SO$_{2}$ concentrations exited from the reactor were measured with various applied voltages and liquid flow rates. The applied voltage varied from -10 to 10 kV by 1 kV, and the volume flow rate of slurry was set to 15, 25, 35 ml/min which were within the range of emission mode. Consequently, the SO$_{2}$ scrubbing efficiency increased with increasing the applied voltage but was independent of the polarity of the applied voltage. For the electrical and flow conditions considered a theoretical study of estimating average size and charge of the atomized droplets was carried out based on the measured current-voltage characteristics. The droplet charge to mass ratio increased and the droplet diameter decreased as the strength of the applied voltage increased.

• New & Renewable Energy
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• v.9 no.3
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• pp.20-28
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• 2013

The gasification process has developed to convert coal into the more useful energy and material since decades. Despite the numberous design of ones, entrained flow gasifier of the major companies has had an advantage on the market. Because it has a merit of full-scale and high performance plant. In this paper, the gasification technologies of GE energy, Phillips, Siemens and Shell have been reviewed to compare their characteristics and a high performance gasification process was suggested. And the simulation model of gasifiers using Aspen Plus offered the quantitative comparison data for difference designs. The simulation results revealed the poor performance of the slurry feed than dry design. The corresponding cold gas efficiency of 77% is much lower than the 80.3% for the dry feed cases. The exergy analysis of the difference syngas quenching system showed that chemical quenching is superior to another. The results of analysis recommend the two stage gasifier with dry multi-feeder as the energy effective design.

• Journal of the Korean earth science society
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• v.28 no.1
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• pp.112-122
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• 2007

It is known that coal-derived fly ashes have the unique chemical composition and mineralogical characteristics. Since iron oxides in coal fly ash are enriched with heavy metals, the subsurface media including soils, underground water, and sea water are highly likely contaminated with heavy metals when the heavy metals are leached from fly ashes by water-fly ash interactions. The purpose of this study was to investigate how indigenous bacteria affect heavy metal leaching and mineralogy in fly ash slurry during the fly ash-seawater interactions in the ash pond located in Dangjin seashore, Korea. The average pH of ash pond seawater was 8.97 in nature. Geochemical data showed that microbial activity sharply increased after the 7th day of the 60-day course batch experiments. Compared with other samples including autoclaved and natural samples, ${SO_4}^{2-}$ was likely to decrease considerably in the fly ash slurry samples when glucose was added to stimulate the microbial activity. Geochemical data including Eh/pH, alkalinity, and major and trace elements showed that the bacteria not only immobilize metals from the ash pond by facilitating the chemical reaction with Mn, Fe, and Zn but may also be able to play an important role in sequestration of carbon dioxide by carbonate mineral precipitation.

• Journal of the Korea Concrete Institute
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• v.21 no.1
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• pp.3-11
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• 2009

The increased demand and consumption of coal has intensified problems associated with disposal of solid waste generated in utilization of coal. Major utilization of coal by-products has been in construction-related applications. Since fly ash accounts for the part of the production of utility waste, the majority of scientific investigations have focused on its utilization in a multitude of use, while little attention has been directed to the use of bottom ash. As a consequence of this neglect, a large amount of bottom ash has been stockpiled. However, the need to obtain safe and economical solution for its proper utilization has been more urgent. The study presented herein is designed to ascertain the performance characteristics of bottom ash, as autoclaved lightweight foamed concrete product. The laboratory test results indicated that tobermorite was generated when bottom ash was used as materials for hydro-thermal reaction. According to the analysis of variance, at the fresh state, water ratio affects on flow and slurry density of autoclaved lightweight foamed concrete, but foam ratio influences on slurry density, while, at the hardened state, foam ratio affects on the density of dry and the compressive strength but doesn't affect on flexural and tensile strength. In the results of response surface analysis, to obtain target performance, the most suitable mix condition for lightweight foamed concrete using bottom ash was water ratio of 70$\sim$80% and foaming ratio of 90$\sim$100%.

• Journal of the Korean GEO-environmental Society
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• v.12 no.10
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• pp.73-82
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• 2011

Coal ash of industial by-products was not recycled about 30% in total emissions. Moreover, it caused environmental pollution as well as wasted unnecessary expenses and time. Currently, fly ash(FA) is recycled as construction material however ponded ash(PA) is mostly buried. Lightweight foamed Controlled Low-Strength Materials(CLSM) evaluated in this study reduces unit weight by mixing foam in the traditional Controlled Low-Strength Material and has lightweight and flowability to be available for backfill materials in construction. Flow test, unconfined compressive strength test, and foamed-slurry unit weight test were performed in this study and the applicability of lightweight foamed CLSM for construction materials was evaluated. The results indicate that the mixture ratio(PA:FA) ranging from 70:30 to 50:50, cement of 7%, foam of 2~3%, and water content of 26.5~29.5% were required to satisfy the following standards such as flow value(i.e., 20cm), unconfined compressive strength(i.e., 0.8~1.2MPa), and foamed-slurry unit weight(i.e., $12{\sim}15kN/m^3$).

• Plant Journal
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• v.15 no.4
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• pp.30-35
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• 2019

To meet both increasing social demand for reduction of fine dust and the strengthened air pollutant emission standards, this paper indicated performance enhancement of FGD with structural constraints in 500 MW coal fired thermal power plant's. Through modifying internal facilities for flue gases to make swirl in the absorption tower, it made turbulence and increased the efficiency of material transfer, the reaction area and time with the limestone slurry. Therefore, it could reduce dust and enhance the performance of collecting the SO₂. As a result, desulfurization efficiency was improved from 91.61% to 98.43% and dust removal efficiency was improved from 77.4% to 87.08%. Emission density is 7.85 ppm of SO₂ and 4.67 mg/㎥ of dust. This is a level that satisfies emission limit of 25 ppm of SO₂ and 5 mg/㎥ of dust which are the air pollutant emission standards of 2023. The performance enhancement method of this study is expected to be effectively applied to other coal-fired power plants with similar constraints.

• KEPCO Journal on Electric Power and Energy
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• v.3 no.1
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• pp.29-34
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• 2017

Leaching kinetics for extracting yttrium from the coal fly ash was investigated in the presence of sulfuric acid during extraction. The leaching kinetics of yttrium were conducted at reactant densities of 5~1,000 g coal fly ash per L of $1.0{\sim}10.0N\;H_2SO_4$, agitation speed of 250 rpm and temperature ranging from 30 to $90^{\circ}C$. As a result, the leaching kinetic model was determined in a two-step model based on the shrinking core model with spherical particles. The first step was proceeded by chemical reaction at ash surface, and the second step was proceeded by ash layer diffusion because the leaching conversion of yttrium by the first chemical reaction increases with increased the time irrelevant to the temperature whereas it increases with increased the leaching temperature. The activation energy of the first chemical leaching step was determined to be $1.163kJmol^{-1}$. After the first chemical reaction, the activation energy of ash layer diffusion leaching was derived to be $41.540kJmol^{-1}$. The optimum conditions for leaching the yttrium metal of 60 % were found to be the slurry density of 250 g fly ash per L of $H_2SO_4$, solvent concentration of $2.0N\;H_2SO_4$, second step leaching of temperatures of $30^{\circ}C$ for 3 hours and then $90^{\circ}C$ for 3 hours at agitation rate of 250 rpm.