• Korean Chemical Engineering Research
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• 제43권4호
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• pp.458-466
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• 2005

회분식 증류 공정을 모델링하기 위해서는 평형상수와 엔탈피값이 필요하며 이 값들은 열역학적인 계산 방법에 의해 계산된다. 석탄 유분인 coal tar의 경우에는 성분이 다양하고 coal tar내의 성분을 대부분 알 수 없으므로 가상성분으로 만들어 적절한 물성예측식을 사용하여 물성값을 계산해 주어야 한다. 본 연구에서는 기존의 물성예측식에 의해 계산된 값과 이미 알려진 coal tar 유분의 실제물성값의 차이를 기 개발된 물성예측식에 대해 비교하였고 물성예측식에 필요한 2개의 parameter(NBP, SG)대신 1개의 변수(NBP)를 사용하여 간단한 물성예측식을 도출하였다. 또한 이상 기체 열용량 예측식의 경우에도 같은 방법을 적용하였다. 개발된 물성 예측식 및 회분식 증류공정프로그램은 coal tar계에 적용하여 coal tar 중 유효성분 분리를 위해 효율적으로 적용할 수 있다 하겠다.

• Geomechanics and Engineering
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• 제16권1호
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• pp.85-95
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• 2018

Water affects the mechanical properties of coal and stress wave propagation. To comprehensively investigate the effect of water content on the properties of coal, laboratory tests including X-Ray Diffraction (XRD) analysis, P-wave test, S-wave test, static and dynamic compression test with different water contents were conducted. The compressive strength, elastic modulus and failure strain and their mechanism of coal specimen under coupled static-dynamic load with the increased water content were observed. Meanwhile, energy transmission and dissipation characteristics of a stress wave in coal specimens with different water contents under dynamic load and its relation with the failure features, such as fragmentation and fractal dimension, of coal was analyzed. Furthermore, the dynamic interpretation of water infusion to prevent coal burst based on water infusion model of coal seam roadway was provided.

• Asian Journal of Atmospheric Environment
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• 제4권2호
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• pp.80-88
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• 2010

In order to offer a better understanding of air pollution of China as well as East Asia we attempted to characterize the chemical properties of the raw coal materials mined in China and their combusted bottom ashes generated from coal fired power plant. To this end, we measured the chemical characteristics of individual bottom ashes and feed coal fragments collected at a coal fired power generator which was operated with the raw coal dug at a coal mine in China. The chemical properties of these two sample types were determined by a synchrotron radiation X-ray fluorescence (SR-XRF) microprobe method. Through an application of such technique, it was possible to draw the 2D elemental maps in and/or on raw coal fragments and fired bottom ashes. The pulverized fine pieces of feed coal mainly consisted of mineral components such as Fe, Ca, Ti, Ca, and Si, while Fe was detected as overwhelming majority. The elemental mass of combusted bottom ash shows strong enrichment of many elements that exist naturally in coal. There were significant variations in chemical properties of ash-to-ash and fragment-to-fragment. Although we were not able to clearly distinguish As and Pb peaks because of the folding in their X-ray energies, these two elements can be used as tracers of coal fire origin.

• Korean Chemical Engineering Research
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• 제45권6호
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• pp.596-603
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• 2007

실시간 온라인 석탄 성상분석은 효율적인 석탄 화력발전소 운영을 위해 반드시 필요한 기술이다. 온라인 석탄 성상분석 기술 개발을 위해 다변량 분석기법을 사용하여 확산 반사방식을 통해 얻은 석탄의 근적외선 스펙트럼과 석탄 성상(%)[수분, 회분, 휘발분, 고정탄소, 탄소, 수소, 질소, 산소, 황], 발열량(kcal/kg)간의 관계를 조사하였다. 현재 석탄 화력발전소에서 사용하는 40여종의 석탄에서 얻은 근적외선 스펙트럼을 전처리[2차 미분, MSC(multiplicative scatter correction)]를 통해 물리적 영향을 최소화하여 석탄 성상과의 관계를 PLS(partial least squares regression), PCA(principal component analysis)의 chemometrics 기법을 이용하여 정량 분석하였다. 분석 결과 본 기법을 통해 근적외선 스펙트럼으로 석탄 성상 중 회분, 질소 그리고 황을 제외한 나머지 성분에 대해 분석이 가능함을 확인할 수 있었다. 또한 PC(PLS component)의 값을 이용하여 석탄의 종류를 구별한 다음, 다변량 통계기법을 사용하여 정량 분석한 결과, 전체 석탄을 이용해서 정량 분석한 결과에 비해 비교적 좋은 결과를 얻었다. 수분, 발열량이 실시간으로 분석 가능하여 보다 효율적인 석탄 화력발전소 운영이 가능할 것으로 예상된다.

• 한국재료학회지
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• 제23권5호
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• pp.276-280
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• 2013

Coal tar is the primary feedstock of premium graphitizable carbon precursor. Coal tars are residues formed as byproducts of thermal treatments of coal. Coal tar pitches were prepared through two different heat treatment schedules and their properties were characterized. One was prepared with argon and oxidation treatment with oxygen; the other was prepared with oxygen treatment at low temperature and then argon treatment at high temperature; both used coal tar to prepare coal tar pitches. To modulate the properties, different heat treatment temperatures ($300{\sim}400^{\circ}C$) were used for the coal tar pitches. The prepared coal tar pitches were investigated to determine several properties, such as softening point, C/H ratio, coke yield, and aromaticity index. The coal tar pitches were subject to considerable changes in chemical composition that arose due to polymerization after heat treatment. Coal tar pitch showed considerable increases in softening point, C/H ratio, coke yields, and aromaticity index compared to those characteristics for coal tar. The contents of gamma resin, which consists of low molecular weight compounds in the pitches and is insoluble in toluene, showed that the degree of polymerization in the pitches was proportional to C/H ratio. Using an oxidizing atmosphere like air to prepare the pitches from coal tar was an effective way to increase the aromaticity index at relatively low temperature.

• 자원환경지질
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• 제28권4호
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• pp.381-388
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• 1995

The petrographic, geochemical, and physical properties of the Jangseong and Chinese coals were investigated. The most common mineral matters of Jangseong coal are kaolinite, muscovite, sericite, illite, quartz and pyrophyllite. Mineral matters in Chinese coal are mainly composed of quartz, calcite, dolomite and kaolinite. Jangseong coal ash has higher content of $Al_2O_3$, $K_2O$, $TiO_2$, As, Rb and V, and lower content of CaO, MgO, $Na_2O$, $Fe_2O_3$ and $P_2O_5$ than those of Chinese coal ash. The liquid limit and the plasticity index of Jangseong coal were compared with those of Chinese coal. The result shows that the briquetting ability of Jangseong coal is a little bit better than that of Chinese coal. The briquetting ability is found to be principally dependent on the type and the content of mineral matter in coal, especially clay mineral.

• 대한기계학회논문집B
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• 제33권10호
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• pp.737-747
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• 2009

This study is to investigate the effect of the moisture, volatile matter and particle size in the coal on the pulverized coal combustion characteristics using CFD. The results show that as the moisture content in coal increases, flame temperature decreases because of heat loss driven from latent heat of vaporization and reduction of heating value. As the volatile matter content in the coal increases, the temperature in the region near the burner increases, while the temperature in rear region of boiler decreases. The solution to keep the temperature in the rear region of boiler is suggested that particle size is needed to be larger. As the particle size increases, the temperature in the rear region of boiler show tendency to increase, for combustion burning time of coal could be extended.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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• pp.7-10
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• 2003

The amount of coal ash has been increasing and development of effective use is urgently needed. Various by-products and waste are expected to be used as resources from the point of reduction in environmental load. This is an experimental study to compare the properties of high volume coal ash concrete using the reclaimed coal ash. For this purpose, the mix proportion of concrete according to the content ratio of below 5mm reclaimed coal ash (0.65, 0.70, 0.75 and 0.80). And then air content, slump, compressive strength test were performed. According to test results, it was found that the compressive strength of reclaimed coal ash concrete was similar to the content ratio of below 5mm reclaimed coal ash. And the slump of reclaimed coal ash concrete decreased as the content ratio of below 5mm.

• Steel and Composite Structures
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• 제38권1호
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• pp.79-86
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• 2021

Due to the complex geological conditions, a large number of high quality coal seams was buried in the western of China which cannot be mining in open-pit methods. The dynamic properties of that coal cannot be studied easily in real site for the complex working condition. The compound coal blocks made on the basis of the real situation were studied in the laboratory. The physical and mechanical properties of the compound coal blocks and the raw coal were contrasted by using the UCS tests. The results show that the compound coal blocks made by mixing coal powder, cement and water in proportion of 2.5:2:1 are the closest to that of standard raw coal. Then the propagation of strain waves and crushing effects on the coal were studied in the compound coal blocks by using the super dynamic strain test system and the numerical calculated method of ANSYS/LS-DYNA. The results show that the diameter of the crushing zone in the compound coal blocks was similar to that in the numerical results. The fractures distribution in laboratory tests also has a similar trend to the calculation results. The measured strain waves at the distance of 50 cm, 100 cm, and 150 cm from the center of the charge are mainly concerned at -1.0×104 με and have a similar trend as that in the numerical simulation.

• 자원환경지질
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• 제21권1호
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• pp.97-106
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• 1988

The purpose of this study is to collect basic data which are prerequisite for quantitative analysis of coal logging data. The study involves laboratory measurements of physical properties such as seismic velocities (P,S-waves), resitivity and density of domestic and imported foreign coals. The relationships between these properties were analyzed by using cross-plots. Correlation between the physical properties of coal and the results of chemical analysis (calorie, fixed carbon, ash, moisture, volatile matter and sulfur contents) was also studied to obtain ideas about coal quality analysis using logging data. Summarized results are as follows: 1. $V_P$ is exponentialy related to $V_S$. And the average value of $V_P$ is about l.8 times as large as $V_S$. 2. Since coal has very low density compared with surrounding sedimentary rocks, density logging is appeared to be the best method for identifying coal seams and evaluating their qualities. 3. For the case of domestic coals, the ash contents and calorie show a perfect inverse relationship. Since the density increases as increase of ash content with a well-defined functional form, the ash content of domestic coals can be estimated by density measurements. 4. Because of low ash content, low density and high resistivity, foreign coals and domestic lignites are easily distinguished from domestic coals.