• Title/Summary/Keyword: Coagulants

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Evaluation of Coagulation Characteristics of Fe(III) and Al(III) Coagulant using On-line Monitoring Technique (On-line 모니터링 기법을 이용한 Al염계와 Fe염계 응집제의 응집특성 평가)

  • Son, Hee-Jong;Yoom, Hoon-Sik;Kim, Sang-Goo;Seo, Chang-Dong;Hwang, Young-Do
    • Journal of Environmental Science International
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    • v.23 no.4
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    • pp.715-722
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    • 2014
  • Effects of coagulation types on flocculation were investigated by using a photometric dispersion analyzer (PDA) as an on-line monitoring technique in this study. Nakdong River water were used and alum and ferric chloride were used as coagulants. The aim of this study is to compare the coagulation characteristics of alum and ferric chloride by a photometric dispersion analyzer (PDA). Floc growing rates ($R_v$) in three different water temperatures ($4^{\circ}C$, $16^{\circ}C$ and $30^{\circ}C$) and coagulants doses (0.15 mM, 0.20 mM and 0.25 mM as Al, Fe) were measured. The floc growing rate ($R_v$) by alum was 1.8~2.8 times higher than that of ferric chloride during rapid mixing period, however, for 0.15 mM~0.25 mM coagulant doses the floc growing rate ($R_v$) by ferric chloride was 1.1~2.3 times higher than that of alum in the slow mixing period at $16^{\circ}C$ water temperature. Reasonable coagulant doses of alum and ferric chloride for turbidity removal were 0.1 mM (as Al) and 0.2 mM (as Fe), respectively, and the removal efficiency of those coagulant doses showed 94% for alum and 97% for ferric chloride. The appropriate coagulant dose of alum and ferric chloride for removing dissolved organic carbon (DOC) showed about 0.3 mM (as Al, Fe) and at this dosage, DOC removal efficiencies were 36% and 44%, and ferric chloride was superior to the alum for removal of the DOC in water.

Precipitaion of Acid Mine Drainage Using Coagulants and Flocculants (유기 및 무기응집제를 이용한 산성광산배수 침전 연구)

  • Oh, Taek-Geun;Hwang, Won-Jeong;Lee, Jong-Un;Cha, Jongmun
    • Resources Recycling
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    • v.25 no.3
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    • pp.3-10
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    • 2016
  • The passive treatment was required a large area for the treatment of acid mine drainage (AMD), and pollutants were discharged with mine drainage by the increased flow rate in summer. This study was performed to improve the turbidity and to precipitate the pollutants quickly using coagulants and flocculants in AMD of abandoned mine sites that were difficult to build the passive treatment system. The coagulant PAC (Poly aluminium chloride) and flocculant PAM (Polyacrylamide) were selected to improve turbidity in W mine waters. We also tested the particle size analysis, ICP-OES and/or SEM-EDS for water and sludge samples.

Flocculation Efficiency and Particle Distribution of Total Suspended Solids in the Effluent from Semi-recirculating Aquaculture Systems Treated with Polymers (고분자 응집제를 이용한 반순환여과양식시스템의 배출수 내 고형물 응집 효율 및 입도 분포)

  • Seo, Junhyuk;Woon, Sungchun;Kim, Jisoo;Park, Jeonghwan
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.55 no.1
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    • pp.10-16
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    • 2022
  • Interest in effluent treatment is currently increasing and the use of polymetric coagulants is considered as a pretreatment of physical filtration prior to effluent discharge to increase solids recovery. A jar test evaluated effluent treatment efficiency of polymeric coagulants for semi-recirculating aquaculture systems. The particle coagulation efficiency and distribution were evaluated at different polymer dosages in freshwater and seawater effluents. The polymer was added at 0.005-0.08 mL/g of total suspended solids (TSS) in the effluents. TSS in the supernatant after coagulation decreased with increasing polymer dose in the freshwater, while showing no corresponding changes with dose in the seawater. However, in all treatments for both effluents, the removal efficiency was above 90%, regardless of the dose in the tested range. Both the De Brouckere Mean Diameter (DBMD) and volumetric median diameter (VMD) were all above 100 ㎛ in the freshwater effluent. In the seawater effluent, the particle size appeared to be larger than that in freshwater, ranging from 400-1,000 ㎛ for both DBMD and VMD. Considering that the typical pore size of physical filtration in aquaculture is between 60 and 200 ㎛, the use of polymers is expected to improve the practicality of physical filtration for efficient treatment.

The Quality Characteristics of Kanghwang(Curcuma aromatica Salab.) Tofu Prepared with Various Coagulants (응고제에 따른 강황 두부의 품질 특성)

  • Park, Geum-Soon;Lee, Shin-Ho;Park, Kyoung-Nam
    • Journal of the East Asian Society of Dietary Life
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    • v.17 no.4
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    • pp.547-553
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    • 2007
  • The physicochemical and functional properties of tofu prepared with kanghwang(Curcuma aromatica Salab.) were investigated, in order to study the effects of six different commercial coagulants. The coagulant concentrations were determined as 0.3% GDL, 0.3% $MgCl_2$, 1.0% $CaCl_2$, 1.5% $CaSO_4$, 0.45% mixed coagulant, and 1.5% Milky-Mg by pre-experiments. Also, the optimum concentration for the added kanghwang(Curcuma aromatica Salab.) was chosen as 0.01%. The yields of the kanghwang tofu prepared with Milky-Mg, mixed, and GDL coagulants were higher than those prepared with $MgCl_2$, $CaCl_2$, and $CaSO_4$. The pH of the kanghwang tofu prepared with the $MgCl_2$ coagulant was higher than when made with the other coagulants. The turbidity of the kanghwang tofu was highest when it was coagulated with GDL, and moisture content was highest or the of kanghwang tofu coagulated with $CaCl_2$. In the color analysis of the kanghwang tofu, the $L^{***}$ value was highest with the Milky-Mg coagulant, while the $a^{***}$ value was highest and the b value lowest with the GDL coagulant. For the textural properties, the hardness results were in the order of $CaSO_4$ > $CaCl_2$ > $MgCl_2$ > mixed > GDL > Milky-Mg, springiness, gumminess, and brittleness were highest in the tofu coagulated with Milky-Mg. For the overall acceptability of the sensory properties, the Kanghwang tofu that was made using the mixed coagulant had the highest score.

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Membrane contactor and Carbon Dioxide Separation

  • 이규호
    • Proceedings of the Membrane Society of Korea Conference
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    • 2002.07a
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    • pp.59-101
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    • 2002
  • PVDF is good material for a hollow fiber membrane with high porosity and excellent hydrophobicity. Asymmetric PVDF hollow fiber membranes were prepared by the Loeb-Sourirajan phase inversion method. Asymmetric PVDF hollow fiber membranes could be controlled in pore size and porosity using various additives(LiCl, ZnCl$_2$) and internal coagulants (water, EtOH/water, and DMAc/water mixture). $CO_2$removal efficiency of asymmetric PVDF hollow fiber membranes was 1.2 times high than that of commercialized PP hollow fiber membranes at MEA 5wt% solution. $CO_2$flux of asymmetric PVDF hollow fiber membranes was 2.5 times higher than that of commercialized PP hollow fiber membranes. $CO_2$removal efficiency and absorption rate of asymmetric PVDF hollow fiber membranes were 30 times higher than those of packed column at absorbent $H_2O$. $CO_2$flux of asymmetric PVDF hollow fiber membranes at MEA 5wt% solution was 48 times higher than that of pure water. In the case of MEA 5wt% solution used as an absorbent, the $CO_2$absorption rate and removal efficiency of PVDF hollow fiber membrane were 2.3 times higher than that of a packed column.

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Studies on the Wastewater Treatment and Wastewater Characteristics from Acetaldehyde (아세트 알데히드 공장 폐수의 특성 및 화학적 처리)

  • 강선태;서승교;김정호
    • Journal of Environmental Health Sciences
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    • v.17 no.2
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    • pp.17-21
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    • 1991
  • As a research for treatment of wastewater from acetaldehyde plant by biological method, we investigated general characteristics of the wastewater as well as the effect of coagulants. COD and BOD of the wastewater were 5260 ppm and 6452 ppm, respectively, and pH was 1.86. COD and BOD of the wastewater were 214, 000ppm and 15190ppm, respectively, and pH was 2.4. And the main organic componnt in wastewater were acetic acid were contained 6.76 % and 14.5 %, respectively. FeSO$_{4}$ as the coagulated was the most effective. The COD removal rate was reached to maximum state by supplementing 1200 ppm FeSO$_{4}$ and pH 9.5.

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Effects of dissolved oxygen and coagulants on algal autoflotation (응집제종류 및 용존산소농도에 따른 조류의 Autoflotation효과)

  • 권오상;박혜경
    • Journal of environmental and Sanitary engineering
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    • v.15 no.1
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    • pp.7-13
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    • 2000
  • To develop the removal technique of algal bloom the efficiencies of algal flocculation/ autoflotation by the kinds of coagulant and oversaturated oxygen concentration were investigated. The summarized results are as follow. 1. In the algae flocculation test with alum[$Al_2(SO_4)_3{\cdot}18H_2O$], optimum pH was 5.5 and, with chitosan optimum pH was 7.0. 2. Chitosan which was natural polymer showed the 5~10 times higher algal biomass flocculation efficiency than alum in the condition of same algal concentration. 3. For the each coagulant, the higher ${\Delta}DO$(oversaturated dissolved oxygen concentration - saturated dissolved oxygen) was, the faster the rising velocity of the algal floc was. 4. In the condition of about 4mg/L ${\Delta}DO$, the rising velocity of chitosan is about 2 times higher than that of alum, and chitosan formed the stronger algal floc.

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Effect of Anionic Polymer on Particle Size Distribution in PAC Coagulation Process for Phosphorus Removal (PAC를 이용한 인제거 공정에서 음이온계 고분자 첨가가 입도 분포에 미치는 영향)

  • Kim, Sunghong;Lee, Dongwoo;Kim, Donghan;Kim, Dooil
    • Journal of Korean Society on Water Environment
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    • v.29 no.2
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    • pp.170-175
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    • 2013
  • Achieving very low phosphorus levels in treated wastewater will require the installation of additional treatment. Phosphorus removal experiments by chemical coagulation were carried out for the effluent of wastewater treatment plant in this study. TP (total phosphorus) or phosphate were highly related to the addition of PAC (poly aluminium chloride) which is one of the inorganic coagulants. But, organic polymer did not significantly affect the phosphorus removal efficiency. Polymer affected the flocculation of particle especially particle matter less than 10 micrometer so, the number of micro particles was decreased by polymer dose. Chlorination would not affect on chemical coagulation process and TP and turbidity could be effectively removed by the co-addition of PAC and polymer.

Screening Test of Selaginella tarmariscina for Liver Protective Effects in Primary Cultured Hepatocytes (일차 배양한 간세포에서의 권백의 간보호효과의 Screening Test)

  • Yoon, Soo-Hong;Lee, Ju-Young;Ha, Hun
    • Environmental Analysis Health and Toxicology
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    • v.11 no.3_4
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    • pp.65-68
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    • 1996
  • Selaginellae Herba has been used as folk medicine for antineoplastics, coagulants, antidotes and invigorants. To find an in vitro screening method for liver protective effect of Selaginellae Herba in benzo(a)pyrene intoxicated injury were examined in primary cultured rat hepatocytes. Using MTT assay, herba concentration showed dose dependently viability. The lowest concentration of benzo(a)pyrene giving cytotoxicity revealed around 50gM. The hepatoprotective effect of Selaginellae Herba in both water and chloroform extracts was also increased dose dependently.

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A perspective of chemical treatment for cyanobacteria control toward sustainable freshwater development

  • Huh, Jae-Hoon;Ahn, Ji-Whan
    • Environmental Engineering Research
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    • v.22 no.1
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    • pp.1-11
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    • 2017
  • One of the most threatening consequences of eutrophic freshwater reservoirs is algal blooming which typically occur after the long a mega drought or/and irregular rainfall under influence of climate change. The long-term experiences of chemical treatment are known as a most practical effort to reduce health concerns from human exposure of harmful cyanobacteria as well as to preserve ultimate freshwater resources. Even though these conventional chemical treatment methods do not completely solve the algal residue problem in water treatment plant or directly in the water bodies, they still have big advantages as fast and efficient removal process of cyanobacteria due to cheaper, easier to manage. This review summarizes their chemical treatment scenarios of the representative coagulants, pre-oxidants and algaecides composed to chemical compounds which immediately may help to manage severe cyanobacteria blooms in the summer seasons.