• Title/Summary/Keyword: Co-presence

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Preparation of Sodiumisocyanate and its Analyzing Method in the Presence of Impurities $Na_2CO_3$, Urea, and Biuret (Sodium Isocyanate의 제법 및 $Na_2CO_3$, Urea, Biuret 혼재시 그의 정량분석법에 관한 연구)

  • 국채호
    • YAKHAK HOEJI
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    • v.7 no.2_3
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    • pp.67-71
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    • 1963
  • Studies the reaction mechanism and optimal reaction condition of the process of preparing sodium isocyanate, by means of heating of sodium carbonate and urea. Proposing, at the sametime, the quantitative analyzing method of sodium isocyanate in the presence of impurities of $Na_{2}CO_{3}$, urea and biuret. 1. Sodium isocyanate could be prepared by means of heating reaction of sodium carbonate and urea. 2. Adding urea into the heated sodium carbonate is reasonable. 3. Quantitative analysis of sodium isocyanate in the presence of impurities, $Na_{2}CO_{3}$, urea and biuret could be done by the following method:-adding nitrobarite solution into sample solution in order to remove $CO_{3}"$ and neutralize the solution, filtering off $BaCO_{3}$, and then precipitating isocyanate as a silver salt, filtering off AgNCO, and then, titrating remaining $AgNO_{3}$ with $NH_{4}SCN$, (indicator $FeNH_{4}(SO_{4})_{2})$/TEX>

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Investigation of Sweet and Sour Corrosion of Mild Steel in Oilfield Environment by Polarization, Impedance, XRD and SEM Studies

  • Paul, Subir;Kundu, Bikramjit
    • Corrosion Science and Technology
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    • v.17 no.5
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    • pp.249-256
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    • 2018
  • Metallic structures in the oil and gas production undergo severe degradation due to sweet and sour corrosion caused by the presence of $CO_2$ and $H_2S$ in the fluid environment. The corrosion behavior of 304 austenitic stainless was investigated in the presence of varying concentrations of $CO_2$ or $H_2S$ and $CO_2+H_2S$ to understand the effect of the parameters either individually or in combination. Potentiodynamic polarization study revealed that a small amount of $CO_2$ aided in the formation of calcareous deposit of protective layer on passive film of 304 steel, while increase in $CO_2$ concentration ruptured the layer resulting in sweet corrosion. The presence of $S^{2-}$ damaged the passive and protective layer of the steel and higher levels increased the degradation rate. Electrochemical impedance studies revealed lower polarization resistance and impedance at higher concentration of $CO_2$ or $H_2S$, supporting the outcomes of polarization study. XRD analysis revealed different types of iron carbides and iron sulphides corresponding to sweet and sour corrosion as the corrosion products, respectively. SEM analysis revealed the presence of uniform, localized and sulphide cracking in sour corrosion and general corrosion with protective carbide layer amid for sweet corrosion.

Film Formation in $CO_2$ Corrosion with the Presence of Acetic: An Initial Study

  • Ismail, Mokhtar Che;Mohd, Muhammad Azmi;Turgoose, Stephen
    • Corrosion Science and Technology
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    • v.7 no.1
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    • pp.22-26
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    • 2008
  • Formation of protective iron carbonate films in $CO_2$ corrosion can reduce corrosion rate substantially and the effects have been incorporated in various prediction models. The $CO_2$ corrosion with the presence of free acetic acid is known to increase corrosion rate below scaling temperature. The possible interaction between the formation of iron acetate and iron carbonate films can affect the protectiveness of the film. The study is done using 3% NaCl solution under stagnant $CO_2$ -saturated condition at the scaling temperatures at various pH values and HAC concentrations. The result show that the presence of HAc does not affect the formation of protective iron carbonate film but delays the attainment of protective iron carbonate due to a possibility of solubilising of ferrous ions and thinning of the films.

Influence of Thallium Carbonate on the Hydration of Tricalcium Silicate (Tricalcium silicate의 수화반응에 따른 $T1_2CO_3$의 영향)

  • Yim, Going
    • The Journal of Natural Sciences
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    • v.4
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    • pp.95-102
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    • 1991
  • The influences of various concentrations of thallium carbonate on the hydration of tricalcium silicate which is widely used to the inorganic materials have been studied using an isothermal microcalorime-ter. The experimental results indicate that the hydration of tricalcium silicate is accelerated in the presence of thallium carbonate, namely the concentration of thallium carbonate is increased, the rate of hydration is also increased. The x-ray diffraction analysis shows that the concentration of tricalcium silicate decreases rapidly in the presence of thallium carbonate. Differential thermal analysis of tricalcium silicate hydrated in the persence of thallium carbonate indicates the presence of calcium carbonate. The nonevaporable water content and the degree of hydration of tricalcium silicate show that the accelerating action of thallium carbonate is more pronounced only during the early period of hydration. Analytical results of the liquid phase in contact with the tricalcium silicate paste indicate that the concentrations of calcium and hydroxyl ions are changed considerably in the presence of thallium carbonate.

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Exploring the Effects of the Virtual Human with Physicality on Co-presence and Emotional Response

  • Shin, Kwang-Seong;Jo, Dongsik
    • Journal of the Korea Society of Computer and Information
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    • v.24 no.1
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    • pp.67-71
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    • 2019
  • With continued technology innovation in the fields of computer graphics (CG) and virtual reality (VR), digital animated avatars (or virtual humans) are evolving into ones that are more interactive at a suitable location such as museum, airport, and shopping mall. Specially, the form of the avatar (or the virtual human) realistically need to be expressed in a way that matches the users' physical space. In recent many researches, the form of virtual human has been expressed as mixed-reality human (MRH)-the virtual human combines with the physicality as the real part. In this paper, we propose to carry out a study comparing various MRH on co-presence and emotional response in two-typed virtual humans depending on how many actual parts are included: (1) (Level 1) small parts in the virtual human combined virtual components (e.g., the head only) and (2) (Level 2) large parts in the virtual human with the physicality as the real part such as head, arms, and upper body). We report on the implemented results of our virtual humans and experimental results on co-presence and emotional response.

SIP based IP Multimedia Network (SIP기반의 IP Multimedia Network 구축)

  • Jung Jung-Moon
    • 한국정보통신설비학회:학술대회논문집
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    • 2003.08a
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    • pp.223-225
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    • 2003
  • Session Initiation Protocol(이하 SIP)은 H.323 network에서 제기된 문제점을 해결하고 다양한 multimedia service를 제공하기위해 IETF에서 정의된 protocol로서, 3GPP의 IP Multimedia Subsystem(이하 IMS)의 기반 protocol로 채택되었다. IMS는 multimedia service를 제공하기 위한 infrastructure로서 CSCF, HSS, MRF, MGCF, IM-GW등 기능적으로 분리된 여러 entity로 구성되며, 향후 추가될 다양한 부가 service에 유연하게 대처할 수 있는 Application Server(이하 AS) mechanism을 포함하고 있다. 현재 AS mechanism을 이용하여 3GPP규격 상에 정의된 대표적 서비스는 presence service이며, presence service network은 presence server, presence agent, presence proxy, watcher등으로 구성된다. 마지막으로 상기에 언급한 규격을 바탕으로 실제 구축된 Instant messaging/presence service network을 제시한다. (본문 참조)

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Preparation and Characterization of Proton Conducting Crosslinked P(VDF-co-CTFE)-MAA/SEMA membranes (수소이온 전도성 가교된 P(VDF-co-CTFE)-MAA/SEMA 막 제조 및 분석)

  • Patel, Rajkumar;Lei, Zeng Xiao;Heo, Sung Yeon;Kim, Jong Hak
    • Membrane Journal
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    • v.23 no.4
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    • pp.290-296
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    • 2013
  • Poly(vinylidenefluoride-co-chlorotrifluoroethylene) P(VDF-co-CTFE) polymer was attached to methacrylic acid (MAA) in the presence of 1,8-diazabicyclo[5,4,0]undec-7-ene(DBU) catalyst to prepare P(VDF-co-CTFE)-MAA copolymer. The modified P(VDF-co-CTFE)-MAA was polymerized with 2-sulfoethyl methacrylate (SEMA) monomer in the presence of 4',4'-azobis(4-cyanovaleric acid(ACVA) initiator by free radical polymerization to form the proton conducting membrane. The ratio of the SEMA was increased in the membrane to increase the presence of the acidic group. The maximum IEC value that was observed at 50% SEMA was around 0.82 meq/g, which is consistent with the water uptake value. The highest proton conductivity achieved by P(VDF-co-CTFE)-MAA/SEMA membrane with 50% SEMA was approximately 0.041 S/cm. This indicates that the available ionic group for the proton conduction increases with the increase in the SEMA in the membrane.

Organic co-solvents mediated variation in anion-water hydrogen bonding in [Bmim][BF4] ionic liquid through FTIR spectroscopy

  • Manna, Arpan;Lim, Manho
    • Rapid Communication in Photoscience
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    • v.4 no.3
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    • pp.67-69
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    • 2015
  • FTIR spectroscopy has been employed to investigate the variation of anion-water hydrogen bonding in 1-butyl 3-methyl imidazolium tetrafluoroborate ([Bmim][$BF_4$]) ionic liquid caused by addition of organic co-solvents with various polarities. The variation was estimated by probing band shape and intensity of the OH stretching vibration of trace water present in ionic liquid at $3400-3800cm^{-1}$. The presence of polar aprotic co-solvent in ionic liquid dramatically reduces the absorptivity of the OH stretch band, indicating that the co-solvent changes the nature of anion-water hydrogen bond drastically, which might be responsible for the reduction of the viscosity of ionic liquid in the presence of the co-solvent.

Molecular detection of bat coronaviruses in three bat species in Indonesia

  • Dharmayanti, Ni Luh Putu Indi;Nurjanah, Diana;Nuradji, Harimurti;Maryanto, Ibnu;Exploitasia, Indra;Indriani, Risa
    • Journal of Veterinary Science
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    • v.22 no.6
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    • pp.70.1-70.12
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    • 2021
  • Bats are an important reservoir of several zoonotic diseases. However, the circulation of bat coronaviruses (BatCoV) in live animal markets in Indonesia has not been reported. Genetic characterization of BatCoV was performed by sequencing partial RdRp genes. Real-time polymerase chain reaction based on nucleocapsid protein (N) gene and Enzyme-linked immunosorbent assay against the N protein were conducted to detect the presence of severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) viral RNA and antibody, respectively. We identified the presence of BatCoV on Cynopterus brachyotis, Macroglossus minimus, and Rousettus amplexicaudatus. The results showed that the BatCoV included in this study are from an unclassified coronavirus group. Notably, SARS-CoV-2 viral RNA and antibodies were not detected in the sampled bats.

Properties of Acetyl-CoA Synthetase from Pseudomonas fluorescens

  • Kim, Yu-Sam;An, Jae-Hyung;Yang, Bu-Hyun;Kim, Kyu-Wan
    • BMB Reports
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    • v.29 no.4
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    • pp.277-285
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    • 1996
  • In Pseudomonas fluorescens grown on malonate as sole carbon source, acetyl-CoA synthetase was induced, suggesting that malonate is metabolized through acetate and then acetyl-CoA. Acetyl-CoA synthetase was purified 18.6-fold in 4 steps to apparent homogeneity. The native molecular mass of the enzyme estimated by a native acrylamide gel electrophoresis was 130 kDa. The enzyme was composed of two identical subunits with a molecular mass of 67 kDa. Optimum pH was 70. The acetyl-CoA synthetase showed typical Michaelis-Menten kinetics for the substrates, acetate, ATP and CoA, whose $K_m$ values were calculated to be 33.4, 74.8, and 40.7 mM respectively. Propionate. butyrate and pentanoate were also used as substrates by the enzyme, but the rate of the formation of the CoA derivatives was decreased in the order of the increase in carbon number. The enzyme was inhibited by the group-specific reagents diethylpyro-carbonate, 2,3-butanedione, pyridoxal-5'-phosphate and N-bromosuccinimide. In the presence of substrates the inactivation rate of the enzyme, by all of the group-specific reagents mentioned above decreased, indicating the presence of catalytically essential histidine, arginine, lysine and tryptophan residues at or near the active site. Preincubation of the enzyme with ATP, $Mg^{2+}$ resulted in the increase of its susceptibility to diethylpyrocarbonate, suggesting that ATP, $Mg^{2+}$ may induce a conformational change in the active site exposing the essential histidine residue to diethylpyrocarbonate. The enzyme was acetylated in the presence of acetyl-CoA, indicating that this is one of acyl-enzyme.

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