• 제목/요약/키워드: Co-polymer

검색결과 1,924건 처리시간 0.024초

옥외용 고분자 애자의 기술 현황 (State-of-the-Art of Polymer Insulators)

  • 한기만;김동욱;권혁삼;오무원
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1992년도 하계학술대회 논문집 B
    • /
    • pp.886-890
    • /
    • 1992
  • Recent investigations have been made on polymer Insulators of various types. The findings are related to experience on operational lines in foreign countries, design concepts, materials and tests about outdoor properties. Over last decade improvements have been occured in the design and construction techniques of polymer insulators. For transmission and distribution lines, it may be advantageous or even necessary to replace, the conventional porcelain or tempered glass insulators by lighter polymer insulators which have better mechanical properties.

  • PDF

이산화탄소 포집용 폴리비닐아세테이트-이온성액체 막 (Poly (vinyl acetate)-Ionic Liquids Membranes for $CO_2$ Capture)

  • 이상진;최수현;백일현
    • 한국에너지공학회:학술대회논문집
    • /
    • 한국에너지공학회 2010년도 춘계학술 발표회
    • /
    • pp.199-199
    • /
    • 2010
  • Polymeric membranes have been widely used to separate gas mixtures, such as $O_2/N_2,\;CO_2/CH_4,\;CO_2/N_2$, and olefin/paraffin. The permeation selectivity is the ratio between composition ratio at the permeate side and composition ratio at the feed side. In addition, the permeation selectivity is a product of solubility selectivity and diffusivity selectivity. We present a novel idea and describe its experimental result, which was achieved by preparing polymer gel films that included a room temperature ionic liquid (RTIL) in a polymer matrix. It is known that $CO_2$ can dissolve easily in imidazolium-based RTILs. We prepared polymer-ionic liquid gel films using an ionic liquid, 1-ethyl-3-methylimidazolium acetate ([emim] acetate, C-tri) and a host polymer, poly (vinyl acetate) (PVAc, Aldrich).

  • PDF

Construction of a 2D Co(II) Coordination Polymer with (4,4)-Connected Topology: Synthesis, Crystal Structure, and Surface Photo-electric Property

  • Li, Jia-Ming
    • Bulletin of the Korean Chemical Society
    • /
    • 제35권4호
    • /
    • pp.1177-1181
    • /
    • 2014
  • A 2D grid-like (4, 4)-connected topology coordination polymer, $[Co(BTA)_2(H_2O)_2]_n$ (1), where HBTA = 2-(1H-benzotriazol-1-yl)acetic acid, has been synthesized by hydrothermal method and characterized by single crystal X-ray diffraction, IR spectroscopy, elemental analysis and surface photovoltage spectroscopy (SPS). X-ray diffraction analyses indicated that 1 displays octahedral metal centers with secondary building units (SBUs) [$Co(BTA)_2(H_2O)_2$] bridged by the $BTA^-$ ligands. In the crystal, the 2D supramolecular architecture is further supported by $O-H{\cdots}O$, $O-H{\cdots}N$, $C-H{\cdots}O$ hydrogen bonds and ${\pi}{\cdots}{\pi}$ stacking interactions. The SPS of polymer 1 indicates that there are positive response bands in the range of 300-600 nm showing photo-electric conversion properties. There are good relationships between SPS and UV-Vis spectra.

Chitosan/Poly(acrylic acid-co-crotonic acid) Semi-IPN의 합성, 분석 및 팽윤거동 (Synthesis, Characterization and Swelling Properties of Chitosan/Poly(acrylic acid-co-crotonic acid) Semi-Interpenetrating Polymer Networks)

  • Hosseinzadeh, Hossein;Alijani, Darioush
    • 폴리머
    • /
    • 제38권5호
    • /
    • pp.588-595
    • /
    • 2014
  • A semi-interpenetrating polymer network (semi-IPN) hydrogel composed of crosslinked chitosan and poly (acrylic acid-co-crotonic acid) was prepared in the presence of glutaraldehyde (GA) as a crosslinker. Fourier-transform infrared, thermogravimetric analysis and scanning electron microscopy were employed to confirm the structure of the semi-IPN hydrogel. The swelling capacity of hydrogel was shown to be affected by the monomers weight ratio, chitosan content, initiator and GA concentrations. The results also indicated that the semi-IPN hydrogel had different swelling capacity at various pHs. Additionally, the swelling behavior of the hydrogel was investigated in aqueous solutions of NaCl, $CaCl_2$, and $AlCl_3$.

Electrochemical Properties of Cross-linked Polyurethane Acrylate-Based Gel Polymer Electrolyte

  • Kim, Hyun-Soo;Kim, Sung-Il;Choi, Gwan-Young;Moon, Seong-In;Kim, Sang-Pil
    • 전기화학회지
    • /
    • 제5권4호
    • /
    • pp.197-201
    • /
    • 2002
  • In this study, a gel polymer electrolyte was prepared from urethane acrylate and its electrochemical performances were evaluated. And, $LiCoO_2/GPE/graphite$ cells were prepared and their performances depending on discharge currents and temperatures were evaluated. The precursor containing $5 vol\%$ curable mixture had a low viscosity relatively. Ionic conductivity of the gel polymer electrolyte at room temperature and $-20^{\circ}C$ was ca. $5.9\times10^{-3}S{\cdot}cm^{-1}\;and\;1.7\times10^{-3}S{\cdot}cm^{-1}$, respectively. GPE showed electrochemical stability up to potential of 4.5V vs. $Li/Li^+.LiCoO_2/GPE/graphite$ cell showed a good high-rate and a low-temperature performance.

Flexural Behavior of Polymer Mortar Permanent Forms Using Methyl Methacrylate Solution of Waste Expanded Polystyrene

  • Bhutta, M. Aamer Rafique;Tsuruta, Ken;Ohama, Yoshihiko
    • International Journal of Concrete Structures and Materials
    • /
    • 제2권1호
    • /
    • pp.35-39
    • /
    • 2008
  • This experimental study examines the applicability of polymer mortar permanent forms using a methyl methacrylate (MMA) solution of waste expanded polystyrene (EPS) to develop effective recycling processes for the EPS, referring to the flexural behavior of a polymer-impregnated mortar permanent form with almost the same performance as commercial products. An MMA solution of EPS is prepared by dissolving EPS in MMA, and unreinforced and steel fiber-reinforced polymer mortars are mixed using the EPS-MMA-based solution as a liquid resin or binder. Polymer mortar permanent forms (PMPFs) using the EPS-MMA-based polymer mortars without and with steel fiber and crimped wire cloth reinforcements and steel fiber-reinforced polymer-impregnated mortar permanent form (PIMPF) are prepared on trial, and tested for flexural behavior under four-point (third-point) loading. The EPS-MMAbased PMPFs are more ductile than the PIMPF, and have a high load-bearing capacity. Consequently, they can replace PIMPF in practical applications.

Study on the Cycling Performances of Lithium-Ion Polymer Cells Containing Polymerizable Additives

  • Kim, Dong-Won
    • Bulletin of the Korean Chemical Society
    • /
    • 제30권2호
    • /
    • pp.319-322
    • /
    • 2009
  • Gel polymer electrolytes were prepared by immersing a porous poly(vinylidene fluoride-co-hexafluoropropylene) membrane in an electrolyte solution containing small amounts of polymerizable additive (3,4-ethylenedioxythiophene, thiophene, biphenyl). The organic additives were electrochemically oxidized to form conductive polymer films on the electrode at high potential. With the gel polymer electrolytes containing different organic additive, lithium-ion polymer cells composed of carbon anode and LiCo$O_2$ cathode were assembled and their cycling performances were evaluated. Adding small amounts of thiophene or 3,4-ethylenedioxythiophene to the gel polymer electrolyte was found to reduce the charge transfer resistance in the cell and it thus exhibited less capacity fading and better high rate performance.