• Korean Chemical Engineering Research
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• 제61권2호
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• pp.202-207
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• 2023

태양광과 풍력발전의 잉여전기를 공급받아 수전해를 구동하는 경우 날씨 변동에 따라 구동과 정지를 반복해야한다. 수전해를 구동하다 정지하면 잔류 수소와 산소에 의해 PEM 연료전지와 같은 상태가 되고, 구동 중 형성된 수전해의 높은 전위 때문에 전극과 고분자막이 정지 중에도 열화될 가능성이 높다. 본 연구에서는 PEM 수전해가 구동/정지 반복과정에서 전극과 고분자막의 열화가 얼마나 진행되는지 확인하고자, 144시간 동안에 구동/정지 횟수를 변화시키며 성능 감소를 측정하였다. 전극 촉매 활성면적 변화와 고분자막의 수소투과도와 불소유출속도 등을 분석해 전극과 고분자막의 특성 변화를 측정했다. 전체적으로 정지 횟수가 증가할수록 PEM 수전해 성능이 감소했다. 144시간동안에 5회 정지했을 때 IrO_x 촉매 활성이 30% 이상 감소하였고, 수소투과도는 80% 증가해서 전극과 고분자막이 모두 열화됨을 확인했다.

• 전력전자학회:학술대회논문집
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• 전력전자학회 2010년도 하계학술대회 논문집
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• pp.570-571
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• 2010

To reduce the problem of ecocide, the plating equipment, water treatment system, electrolysis facility in ship need high current high power rectifier. This paper shows entire constitution of the proposed high-current rectifier for electrolysis of seawater, describes a way to design controller and analyzes output characteristic of the rectifier.

• 전력전자학회:학술대회논문집
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• 전력전자학회 2010년도 하계학술대회 논문집
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• pp.196-197
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• 2010

This paper investigates a high performance converter topology for hydrogen gas generation electrolysis system. The proposed converter topology consists of full-bridge inverter, medium frequency transformer, and diode rectifier. Hydrogen gas generation electrolysis process considered in the paper is analyzed and characterized by its equivalent circuit. The electrolysis cell is modeled as effective resistance, capacitance, inductance, and internal emf voltage source. The proposed converter topology provides enhanced efficiency of hydrogen gas generation process under the operating condition of dc output voltage with high frequency ripple on it. The high performance operation of proposed converter is confirmed through the simulation with the electrolysis cell considered in the equivalent circuit model.

• 한국재료학회지
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• 제22권2호
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• pp.86-90
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• 2012

Insoluble catalytic electrodes were fabricated by RF magnetron sputtering of Pt on Ti substrates and the performance of seawater electrolysis was compared in these electrodes to that is DSA electrodes. The Pt-sputtered insoluble catalytic electrodes were nearly 150 nm-thick with a roughness of $0.18{\mu}m$, which is 1/660 and 1/12 of these values for the DSA (dimensionally stable anodes) electrodes. The seawater electrolysis performance levels were determined through measurements of the NaOCl concentration, which was the main reaction product after electrolysis using artificial seawater. The NaOCl concentration after 2 h of electrolysis with artificial seawater, which has 3.5% NaCl normally, at current densities of 50, 80 and 140 mA/$cm^2$ were 0.76%, 1.06%, and 2.03%, respectively. A higher current density applied through the electrodes led to higher electrolysis efficiency. The efficiency reached nearly 58% in the Pt-sputtered samples after 2 h of electrolysis. The reaction efficiency of DSA showed higher values than that of the Pt-sputtered insoluble catalytic electrodes. One plausible reason for this is the higher specific surface area of the DSA electrodes; the surface cracks of the DSAs resulted in a higher specific surface area and higher reaction sites. Upon the electrolysis process, some Mg- and Ca-hydroxides, which were minor components in the artificial seawater, were deposited onto the surface of the electrodes, resulting in an increase in the electrical resistances of the electrodes. However, the extent of the increase ranged from 4% to 7% within an electrolysis time of 720 h.

• 한국환경과학회지
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• 제8권4호
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• pp.539-545
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• 1999

Dye wastewater was treated by using an electrochemical oxidation process. Various combinations of electrodes such as carbon, Al and Fe were investigated. In this study, electrode material, electrolyte concentration, electrode distance, current density, and pH value were found to have significant effect on both pollutant removal efficiency and current efficiency in electrochemical oxidation process. After electrolysis for 40min with carbon/Al, it was observed that COD, $T-N, NH_{4}^{+}-N$ and color of treated wastwater were reduced from 580mg/$\ell$ to 145mg/$\ell$, 67.2mg/$\ell$ to 26.8mg/$\ell$, 46.8mg/$\ell$ to 1.4mg/$\ell$, and 4200 Pt-Co units to 336 Pt-Co units, respectively. The optimal conditions of the electrooxidation process to treat the wastewater for this study were found to be such : current density ; 16.67mA/$cm^2$, electrode distance ; 2.5cm, pH value ; 5.0 and carbon/Al electrode.

• 한국표면공학회지
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• 제29권6호
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• pp.728-734
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• 1996

To obtain the relation in the electrochemical reduction of $CO_2$ in aqueous $KHCO_3$ colution between an activity for the product and the nature of Cu electrode, the electrode surface was characterized by using two methods: X-ray photoelectron spectroscopy (XPS) and photoelectron emission (PE) measurement. Electrolyses were performed with Cu electrodes pretreated in several ways. The distribution of the products changed drastically with electrolysis time and the pretreatment method. The features in XPS spectra were closely connected with the product distribution. The oxide film at the electrode surface was gradually reduced to bare Cu metal with electrolysis time, resulting in a variation of the product distribution. PE was measured by verying the wavelength of incident light at several temperatures. The dependence of PE on the measurement temperature changed greatly before and after electrolysis.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2017년도 춘계학술대회 논문집
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• pp.168.1-168.1
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• 2017

화석연료를 대체하기 위한 에너지원으로서 수소에너지에 대한 연구가 활발히 진행되고 있다. 수전해는 무한 청정한 물을 전기분해하여 수소를 생산하는 기술로써 대표적으로 알칼리 수전해(alkaline water electrolysis, AWE)와 고분자 전해질막 수전해(polymer electrolyte membrane water electrolysis, PEMWE)가 있다. 그 중, AWE는 알칼리 분위기에서 물분해 반응이 진행되어 촉매의 부식 위험성이 비교적 낮기 때문에 상대적으로 저렴한 비귀금속 산화물 촉매를 사용할 수 있다는 장점이 있다. 본 연구에서는 비귀금속인 Cu, Co를 이용하여 $CuCoO_4$를 합성한 후 산소 발생 촉매 물질로 활용하여 산소 발생 반응(Oxygen Evolution Reaction, OER)특성을 고찰하였다.

• KEPCO Journal on Electric Power and Energy
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• 제2권1호
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• pp.109-113
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• 2016

Techno-economic evaluation of Non-Capture $CO_2$ Utilization (NCCU) technology for the production of high-value-added products using greenhouse gas ($CO_2$) was performed. The general scheme of NCCU process is composed of $CO_2$ carbonation and brine electrolysis process. Through a carbonation reaction with sodium hydroxide that is generated from brine electrolysis and $CO_2$ of the flue gas, it is possible to get high-value-added products such as sodium bicarbonate, sodium hydroxide, hydrogen & chloride and also to reduce the $CO_2$ emission simultaneously. For the techno-economic study on NCCU technology, continuous operation of bench-scale facility which could treat $2kgCO_2/day$ was performed. and based on the key performance data evaluated, the economic evaluation analysis targeted on the commercial chemical plant, which could treat 6 tons $CO_2$ per day, was performed using the net present value (NPV) metrics. The results showed that the net profit obtained during the whole plant operation was about 7,890 mKRW (million Korean Won) on NPV metrics and annual $CO_2$ reduction was estimated as about $2,000tCO_2$. Also it was found that the energy consumption of brine electrolysis is one of the key factors which affect the plant operation cost (ex. electricity consumption) and the net profit of the plant. Based on these results, it could be deduced that NCCU technology of this study could be one of the cost-effective $CO_2$ utilization technology options.

• 한국수소및신에너지학회논문집
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• 제23권5호
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• pp.538-544
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• 2012

The bubbles made of hydrogen and oxygen gases producted by electrolysis disturb the electrolysis, but the behavior of these bubbles in the electrolysis stack isn't clearly defined. In order to study on the behavior of bubbles in the flow pattern of the meshes type separator, the flow visualization experiment was performed by using of a visible alkaline electrolysis stack and a stereoscopic microscope. As the results, a fine size bubbles adhered to the separator's surface in the electrolyte solution have grown large sized bubbles until each bubble's buoyance is lager than the sum of surface adhesion force and weight. And then the large bubbles flow into the upper area of the separator. Also, as wide area of the separator have been occupied by various sized bubbles, the electrolysis efficiency is declined.

• 상하수도학회지
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• 제30권6호
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• pp.745-753
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• 2016

The objective of this study was to investigate design factors of the electrolysis reactor through the CFD(computational fluid dynamics) simulation technique. Analyses of velocity vector, streamline, chloride ion concentration distribution showed differences in flow characteristics between the plate type electrode and the porous plate type electrode. In case of the porous plate type electrode, chlorine gas bubbles generated from the anode made upward density flow with relatively constant velocity vectors. Electrolysis effect was more expected with the porous plate type electrode from the distribution of chloride ion concentration. The upper part of the electrolysis reactor with the porous plate type electrode had comparatively low chloride concentration because chloride was converted to the chlorine gas formation. Decreasing the size and increasing total area of rectifying holes in the upper part of cathodes, and widening the area of the rectifying holes in the lower part of cathodes could improve the circulation flow and the efficiency of electrolysis reactor.