• Title/Summary/Keyword: Co-contaminants

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Treatment Study on the Combustion Gas of Medical Waste (의료폐기물 소각가스 처리에 관한 연구)

  • Lee, Sung-Jin;Seo, Man-Chul
    • Journal of environmental and Sanitary engineering
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    • v.23 no.3
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    • pp.1-8
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    • 2008
  • Currently, medical waste stoker incinerator is widely used in the emission control technology of health-care risk waste and miscellaneous contaminated waste. In the past, wet type control technology was used to remove the major harmful gaseous contaminants of medical waste such as HCl, $NO_x,\;SO_2$, CO, DUST, Dioxin. However, the treatment cost for wastewater was high and it has a disadvantage for frozen system during winter season. Therefore, in order to obtain effective treatment, the dry type control technology was developed and widely used to remove the gaseous contaminants. In this study, pre-coated bag filter using hydrated lime, ($Ca(OH)_2$), was applied to the dry type control system and the optimum dose of hydrated lime was investigated. The treatment results showed that the dust collection rate was approximately 26.7%. Moreover, the HCl removal rate using pre-coated bag filter ($50mg/sm^3\;Ca(OH)_2$) was 13.52%, which was significantly higher than 3.26% obtained from conventional bag filter.

Effects of Humic Acids on Growth of Herbaceous Plants in Soil Contaminated with High Concentration of Petroleum Hydrocarbons and Heavy Metals (고농도 유류와 중금속으로 복합 오염된 토양에서 식물성장에 미치는 부식산의 영향)

  • Kim, Ki-Seob;Sung, Ki-June
    • Journal of Soil and Groundwater Environment
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    • v.16 no.1
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    • pp.51-61
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    • 2011
  • Germination tests were conducted to determine the practical concentration levels at which plants can reproduce naturally during the phytoremediation of soils contaminated with a high concentration of petroleum hydrocarbons and heavy metals. The effects of humic acids on plant growth and soil physicochemical properties were also investigated. The results show that phytoremediation can be applied in soils contaminated by multiple contaminants at the former soil contamination potential level of Korean soil quality standards considering successful natural reproduction. It was observed that germination rates of Helianthus annuus and Festuca arundinacea were high after all treatments, and transplantation was more appropriate for Phragmites communis in phytoremediation. Humic acids had a positive effect on the growth of both aboveground and belowground biomass of herbaceous plants. Growth inhibition by multiple contaminants is more severe in the case of aboveground biomass. Germination and growth tests suggest that Helianthus annuus is a suitable phytoremediation plant for soils contaminated with a high concentration of petroleum hydrocarbons and heavy metals. The addition of humic acids also caused changes in the physicochemical properties of contaminated soils. An increase in the carbon and nitrogen content due to the addition of humic acids and a correlation between cation exchange capacity(CEC) and the organic matter content were observed.

Numerical Investigation on Wall Flow Control for Preventing Contaminants Deposition inside a Duct (덕트 내 오염물질 퇴적 방지를 위한 벽면유동 제어에 관한 해석적 연구)

  • Lee, Banguk;Lee, Jeekeun
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.25 no.5
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    • pp.261-268
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    • 2013
  • Technologies for preventing contaminants deposition are a key issue in a modern duct system. When particulate matters deposit inside the exhaust pipes, which are widely used in the Urea-SCR system to reduce $NO_x$ emission from heavy duty diesel engines, many problems arise associated with increased flow resistance and corrosion. Therefore, the development of the urea deposition avoidance technologies is being treated as an important issue of the Urea-SCR system. An analytical study was carried out to investigate the effects of the wall flow around the mixer with the variation of the mixer housing surrounding and supporting the mixer, which is designed to increase the wall flow and then to reduce droplet deposition. The housing angles and the position of the mixer were changed:angles of $0^{\circ}$, $1^{\circ}$, $2^{\circ}$, and $3^{\circ}$, and mixer positions of 0 L, 0.5 L, and 1 L. The axial velocity distributions, maximum velocity, the half-width, and momentum distribution of the wall flow were investigated to examine the effect of the mixer-housing assembly geometry.

Sorption of Pb and Cu on different types of microplastics

  • Ruri, Lee;Eun Hea, Jho;Jinsung, An
    • Membrane and Water Treatment
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    • v.14 no.1
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    • pp.19-25
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    • 2023
  • The studies on the effect of different plastic properties (e.g., types, shapes, presence of additivies) on the sorption of contaminants in the agricultural environment are limited. In this study, Cu and Pb, the commonly found heavy metals in the environment, were used to investigate the sorption capacities of microplastics (MPs). The Pb sorption capacity increased in the order of polystyrene (PS)<polyethylene (PE)<polyvinyl chloride (PVC). The estimated Cu sorption capacity was greater for the PE films than the PE fragments, while the sorption strength was greater for the PE fragments. This suggests that the shapes of MPs can affect the contaminant sorption capacities. With the PE fragments, the Pb sorption capacity was greater than the Cu sorption capacity by 10-12 times. Also, the Pb and Cu sorption capacities were greater for the PE fragments with additives than the PE fragment without additives. After the sorption of Pb or Cu on MPs, the toxic effects of the Pb or Cu solutions were decreased, suggesting that the toxic effects of contaminants can be affected by the co-presence of MPs in the environment. Overall, the results show that different types and shapes of MPs and the presence of additives can affect the heavy metal sorption capacities of MPs.

Effect of Soil Micro-environments on the Remediation Efficiency of Contaminated Soil and Groundwater: Review and Case Study (토양지하수 미세환경과 오염정화효율과의 상관성 고찰)

  • Shim, Moo Joon;Yang, Jung-Seok;Lee, Mi Jung;Lee, Giehyeon;Park, Jae Seon;Kim, Guk Jin;Min, Sang Yoon;Kim, Joo Young;Choi, Min Joo;Kim, Min Chan;Lim, Jong Hwan;Kwon, Man Jae
    • Journal of Soil and Groundwater Environment
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    • v.19 no.1
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    • pp.34-45
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    • 2014
  • A variety of physical, chemical, and microbiological techniques have been developed to deal with soil and groundwater contamination. However, in the presence of the large portion of soil micro-environments, contaminant rebound and/or tailing have been frequently reported. Case study of total petroleum hydrocarbons (TPH) removal by full-scale land farming showed that contaminant rebound and/or tailing occurred in 9 out of total 21 cases and subsequently resulted in problems of a long term operation to satisfy TPH guidelines of contaminated soil and groundwater. The main cause of contaminant rebound and tailing is considered to be the strong interactions between contaminants and micro-environments including micro-particles, micro-pores, and organic matter. Thus, this study reviewed the effects of soil micro-environments of soil and groundwater on the removal efficiency for both heavy metals and petroleum contaminants. In addition, the various methods of sampling, analysis, and assessment of soil micro-environments were evaluated. Thorough understanding of the effects of soil micro-environments on contaminant removal will be essential to achieve a cost-effective and efficient solution to contaminated sites.

Covalent Organic Framework Based Composite Separation Membrane: A Review (공유 유기 골격체 기반 복합 분리막 : 고찰)

  • Jeong Hwan Shim;Rajkumar Patel
    • Membrane Journal
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    • v.33 no.4
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    • pp.149-157
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    • 2023
  • Covalent organic frameworks (COFs) have shown promise in various applications, including molecular separation, dye separation, gas separation, filtration, and desalination. Integrating COFs into membranes enhances permeability, selectivity, and stability, improving separation processes. Combining COFs with single-walled carbon nanotubes (SWCNT) creates nanocomposite membranes with high permeability and stability, ideal for dye separation. Incorporating COFs into polyamide (PA) membranes improves permeability and selectivity through a synthetic interfacial strategy. Three-dimensional COF fillers in mixed-matrix membranes (MMMs) enhance CO2/CH4 separation, making them suitable for biogas upgrading. All-nanoporous composite (ANC) membranes, which combine COFs and metal-organic framework (MOF) membranes, overcome permeance-selectivity trade-offs, significantly improving gas permeance. Computational simulations using hypothetical COFs (hypoCOFs) demonstrate superior CO2 selectivity and working capacity relevant for CO2 separation and H2 purification. COFs integrated into thin-film composite (TFC) and polysulfonamide (PSA) membranes enhance rejection performance for organic contaminants, salt contaminants, and heavy metal ions, improving separation capabilities. TpPa-SO3H/PAN covalent organic framework membranes (COFMs) exhibited superior desalination performance compared to traditional polyamide membranes by utilizing charged groups to enable efficient desalination through electrostatic repulsion, suggesting their potential for ionic and molecular separations. These findings highlight COFs' potential in membrane technology for enhanced separation processes by improving permeability, selectivity, and stability. In this review, COF applied for the separation process is discussed.

Comparative Molecular Field Analysis of Dioxins and Dioxin-like Compounds

  • Ashek, Ali;Cho, Seung-Joo
    • Molecular & Cellular Toxicology
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    • v.1 no.3
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    • pp.157-163
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    • 2005
  • Because of their widespread occurrence and substantial biological activity, halogenated aromatic hydrocarbons are one of the important classes of contaminants in the environment. We have performed comparative molecular field analysis (CoMFA) on structurally diverse ligands of Ah (dioxin) receptor to explore the physico-chemical requirements for binding. All CoMFA models have given $q^{2}$ value of more than 0.5 and $r^{2}$ value of more than 0.83. The predictive ability of the models was validated by an external test set, which gave satisfactory predictive $r^{2}$ values. Best predictions were obtained with CoMFA model of combined modified training set ($q^{2}=0.631,\;r^{2}=0.900$), giving predictive residual value = 0.002 log unit for the test compound. We have suggested a model comprises of four structurally different compounds, which offers a good predictability for various ligands. Our QSAR model is consistent with all previously established QSAR models with less structurally diverse ligands. The implications of the CoMFA/QSAR model presented herein are explored with respect to quantitative hazard identification of potential toxicants.

Exposure Assessments of Chemical Risk Factors to Airborne Contaminants in Foundry Process (주물사업장 내 공기중 화학적 유해인자 노출 평가)

  • Bae, Hye-Jeong;Nam, Mi-Ran;Lee, Sang-Man;Jung, Yu-Jin;Shon, Byung-Hyun;Phee, Young-Gyu;Jung, Jong-Hyeon
    • Journal of Environmental Science International
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    • v.24 no.5
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    • pp.699-708
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    • 2015
  • This study was performed to identify the state of the exposure and characteristics of pollutants by each process at 4 casting sites located in Gyeongsang-do from April to November 2013. The concentrations of methanol, crystallized silica glass, formaldehyde and phenol were analyzed by different process - casting process, molding process, core process, and shakeout & finishing process. The highest concentration of methanol was found in casting and molding process, whereas the highest concentration of crystalline quartz(Silica) was observed in core process. The most oxidized steel dusts and the highest concentration of fume were found in shakeout & finishing process. As a result of this study, those labors working at the casting site were found to be constantly exposed to various forms of hazardous chemicals; therefore, it is considered that this is the time to manage and plan how to reduce them. In addition, it is required to thoroughly manage the local exhauster, and improve the process and working environment to reduce various forms of hazardous chemicals.

A Study of Full Scale PUV/US Hybrid System for Contaminant Treatment in Groundwater (지하수 오염물질 처리를 위한 Full Scale PUV/US Hybrid System 연구)

  • Han, Jonghun;Park, Wonseok;Lee, Jongyeol;Heo, Jiyong;Her, Namguk
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.10
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    • pp.575-580
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    • 2017
  • Chlorinated hydrocarbons (TCE and PCE), petroleum hydrocarbons (BTEX, PAHs, and TPH), and explosive compounds (TNT, RDX, and HMX) have been detected in underground water countrywide. The overall objective of this study is to evaluate sono-catalytic degradation coupled with the use of PUV in order to understand the fate and transport of a representative selection of non-biodegradable contaminants (i.e., TCE, PCE, BTEX, PAHs, TPH, TNT, RDX, and HMX) in groundwater. Both ultraviolet (UV) and ultrasound (US) systems are used in degrading of organic contaminants and they can thus be applicable simultaneously as an UV/US hybrid system in attempts further to increase the degradation efficiency. Results indicate that synergistic effect of UV/US hybrid system is closely correlated to the enhancement of sono-chemical reactivity with the UV-US interaction of increasing the formation rate of OH by providing additional $H_2O_2$ production through the pyrolysis of water molecules during UV/US hybrid irradiation.

Present Deterioration Situation and Study on the Conservation Treatment of the Seven-story Stone Pagoda of Jeongamsa Temple (정선 정암사 수마노탑의 손상현황과 보존처리연구)

  • Hwang, Jeong Eun;Kim, Sa-Dug;Jung, Hee Soo
    • 보존과학연구
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    • s.34
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    • pp.110-122
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    • 2013
  • The Seven-story Stone Pagoda of Jeongamsa Temple consists of dolomitic limestone. The surface of the stone stupa is efflorescene. There are spaces between parts in the stereobate and part of roof at the fifth story and above. The space between parts is colonized by biological contaminants. There are breakaway parts in the third, fifth, sixth, seventh story. The dry and wet cleaning of all the biological contaminants, efflorescene. The steam cleaning of rest of efflorescene. The use of poultice with oxalic acid, were done to remove the rust. Breakaway parts are inosculated by L30 and Por-rok. Spaces between parts are waterproofing by Porrok. After treatment, the efflorescene of part of waterproofing are comparatively scarce. So waterproofing is effective at reduced efflorescene and waterproof.

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